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页岩油气储层压裂返排液中卤代烃的吹扫捕集-气相色谱/质谱法检测

郭威 黄春华 赵雄虎 张小涛 沈斌 汪双清 孙玮琳

郭威, 黄春华, 赵雄虎, 张小涛, 沈斌, 汪双清, 孙玮琳. 页岩油气储层压裂返排液中卤代烃的吹扫捕集-气相色谱/质谱法检测[J]. 石油实验地质, 2017, 39(6): 865-872. doi: 10.11781/sysydz201706865
引用本文: 郭威, 黄春华, 赵雄虎, 张小涛, 沈斌, 汪双清, 孙玮琳. 页岩油气储层压裂返排液中卤代烃的吹扫捕集-气相色谱/质谱法检测[J]. 石油实验地质, 2017, 39(6): 865-872. doi: 10.11781/sysydz201706865
Guo Wei, Huang Chunhua, Zhao Xionghu, Zhang Xiaotao, Shen Bin, Wang Shuangqing, Sun Weilin. Determination of halogenated hydrocarbons in outlet fluid for shale oil and gas reservoir fracturing by purge-and-trap and GC-MS[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2017, 39(6): 865-872. doi: 10.11781/sysydz201706865
Citation: Guo Wei, Huang Chunhua, Zhao Xionghu, Zhang Xiaotao, Shen Bin, Wang Shuangqing, Sun Weilin. Determination of halogenated hydrocarbons in outlet fluid for shale oil and gas reservoir fracturing by purge-and-trap and GC-MS[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2017, 39(6): 865-872. doi: 10.11781/sysydz201706865

页岩油气储层压裂返排液中卤代烃的吹扫捕集-气相色谱/质谱法检测

doi: 10.11781/sysydz201706865
基金项目: 国家重大科技专项(2016ZX05034-003)和中国地质调查项目(DD20160184)资助。
详细信息
    作者简介:

    郭威(1991-),男,硕士研究生,从事油田示踪剂研究。E-mail:ym125668@163.com。

    通讯作者:

    孙玮琳(1967-),女,高级工程师,从事油气地球化学分析及研究。E-mail:sunweilin2003@163.com。

  • 中图分类号: TE357.1+2

Determination of halogenated hydrocarbons in outlet fluid for shale oil and gas reservoir fracturing by purge-and-trap and GC-MS

  • 摘要: 在页岩油气开采中,化学示踪技术可以有效应用于评价储层压裂改造效果。化学示踪剂技术推广应用的先决条件在于其相应的分析检测方法。通过研究筛选出了21种化学性质稳定、地层背景值低的卤代烃作为示踪剂,建立了基于吹扫捕集气相色谱-质谱联用(GC-MS)的高灵敏度检测方法。对吹扫捕集、气相色谱-质谱条件进行了优化并获得了最佳条件。结果表明:方法的检出限为0.027~0.162 μg/L,基体加标回收率在74.16%~121.9%之间,精密度(相对标准偏差RSDn=7)小于12.79%。该方法简单、快捷,适用于页岩油气储层压裂液中所述卤代烃示踪剂的检测。

     

  • [1] Catlett R D,Spencer J D,Lolon E,et al.Evaluation of two horizontal wells in the eagle ford using oil-based chemical tracer technology to optimize stimulation design[C]//SPE Hydraulic Fracturing Technology Conference.Texas,USA:Society of Petro-leum Engineers,2013.
    [2] Zhang K S,Tang M R,Yong S S,et al.Evaluation of stage contribution and interwell connectivity during initial flowback and oil production in a tight oil horizontal stimulation using tracer technology[C]//SPE Asia Pacific Hydraulic Fracturing Conference.Beijing,China:Society of Petroleum Engineers,2016.
    [3] 刘同敬,姜宝益,刘睿,等.多孔介质中示踪剂微观可视化实验研究[J].断块油气田,2013,20(4):530-534. Liu Tongjing,Jiang Baoyi,Liu Rui,et al.Experimental study on microcosmic visualization of tracer in porous medium[J].Fault-Block Oil and Gas Field,2013,20(4):530-534.
    [4] 翟亮.基于流线的示踪剂技术研究薄层底水油藏开发规律[J].特种油气藏,2011,18(1):79-82. Zhai Liang.Study on the development rule of thin reservoirs with bottom water by stream line-based tracer technology[J].Special Oil & Gas Reservoirs, 2011,18(1):79-82.
    [5] 巫波,刘遥,荣元帅,等.碳酸盐岩油藏缝洞差异连通及水淹特征研究[J].特种油气藏,2015,22(1):131-133. Wu Bo,Liu Yao,Rong Yuanshuai,et al.Fracture-cavern different connections and water-out in carbonate reservoir[J].Special Oil & Gas Reservoirs,2015,22(1):131-133.
    [6] 于瑞香,张泰山,周伟生.油田示踪剂技术[J].工业水处理,2007,27(8):12-15. Yu Ruixiang,Zhang Taishan,Zhou Weisheng.Technique in oil field tracer[J].Industrial Water Treatment,2007,27(8):12-15.
    [7] Williams R L,McCarthy J T.Using multiple radioactive tracers to optimize stimulation designs[C]//SPE California Regional Meeting.Ventura:Society of Petroleum Engineers,1987.
    [8] 刘佳文,陈学元,李武胜.同位素示踪剂井间监测技术在狮子沟油田N1油藏的应用[J].同位素,2008,21(1):54-57. Liu Jiawen,Chen Xueyuan,Li Wusheng.Application of isotope tracer interwell monitoring technique in N1 of Shizigou oilfield[J].Journal of Isotopes,2008,21(1):54-57.
    [9] 马云,池晓明,黄东安.用于多段压裂的微量物质示踪剂与压裂液的配伍性研究[J].精细石油化工,2016,33(2):50-53. Ma Yun,Chi Xiaoming,Huang Dong'an.Compatibility for trace substances of multi-stage fracturing and fracturing fluid[J].Speciality Petrochemicals,2016,33(2):50-53.
    [10] 易飞,江涛,陈维余,等.一种油田用速溶型微量元素示踪剂及制备方法:CN102296947A[P].2011-05-30. Yi Fei,Jiang Tao,Chen Weiyu,et al.A instant rare earth element tracer in oilfield and its preparation method:CN102296947A[P].2011-05-30.
    [11] Kuchuk F J,Lenn C,Hook P,et al.Performance evaluation of horizontal wells[C]//SPE Asia Pacific Conference on Integrated Modelling for Asset Management.Kuala Lumpur,Malaysia:Society of Petroleum Engineers,1998.
    [12] Hewitt P,Spencer J D,Croud V B.Method of tracing flow of hydrocarbon from a subterranean reservoir:US Patent 8640773[P].2016-03-15.
    [13] 黄毅,李国傲,饶竹,等.城市环境地下水调查样品中挥发性有机物测定[J].质谱学报,2012,33(5):301-307. Huang Yi,Li Guoao,Rao Zhu,et al.Determination of volatile organic compounds in city groundwater by GC/MS with purge and trap sampling[J].Journal of Chinese Mass Spectrometry Society,2012,33(5):301-307.
    [14] 贾静,刘艳.吹扫捕集气相色谱-质谱法测定土壤中54种挥发性有机物[J].分析试验室,2011,30(10):92-97. Jia Jing,Liu Yan.Analysis of 54 volatile organic compounds in soil by using purge and trap-gas chromatography/mass spectrometry[J].Chinese Journal of Analysis Laboratory,2011,30(10):92-97.
    [15] No C C A S.Method 5030C Purge and trap for aqueous samples.Cincinnati,Ohio:U.S. Envnmental Protection Agency,2003.
    [16] Techniquea A P.Method 8260B Volatile organic compounds by gas chromatography/mass spectrometry(GC/MS)[R].Cincinnati,Ohio:U.S. Envnmental Protection Agency,1996.
    [17] Eichelberger J W,Budde-Revision W L,Munch J W,et al.Method 524.2 measurement of purgeable organic compounds in water by capillary column gas chromatography/mass spectrometry[R].Cincinnati,Ohio:Environmental monitoring systems laboratory office of research and development,US EPA,1989.
    [18] 苟德国,束华勇.吹扫捕集-气相色谱同步测定苯系物和卤代烃[J].广州化工,2016,44(7):134-136. Gou Deguo,Shu Huayong.Simultaneous determination of BTEX and VHH by purge-and-trap gas chromatoraphy[J].Guangzhou Chemical Industry and Technology,2016,44(7):134-136.
    [19] 卢明伟.吹扫捕集气相色谱法测定水中苯系物[J].化学分析计量,2008,17(2):25-27. Lu Mingwei.Determination of benzene series in water by purge and trap with gas chromatography[J].Chemical Analysis and Meterage,2008,17(2):25-27.
    [20] 张艳萍,肖兵,丁国清,等.吹扫捕集气相色谱法测定饮用水中15种挥发性卤代烃的方法研究[J].中国卫生检验杂志,2010,20(9):2187-2188. Zhang Yanping,Xiao Bing,Ding Guoqing,et al.Determination of 15 volatile halogenated hydrocarbons in drinking water by purge-and-trap gas chromatography[J].Chinses Journal of Health Laboratory Technology,2010,20(9):2187-2188.
    [21] 刘盛田.吹扫捕集气相色谱法测定饮用水中多种卤代烃[J].中国卫生检验杂志,2010,20(10):2450-2452. Liu Shengtian.Determination of variety of halogenated hydrocarbons in drinking water by purge and trap gas chromatography[J].Chinese Journal of Health Laboratory Technology,2010,20(10):2450-2452.
    [22] Eichelberger J W,Behymer T D,Budde W L.Determination of organic compounds in Drinking water by liquid-solid extraction and capillary column gas chromatography/mass spectrometry[R]. Cincinnati,Ohio:Environmental Monitoring Systems Laboratory, US EPA,1988.
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出版历程
  • 收稿日期:  2017-08-07
  • 修回日期:  2017-09-14
  • 刊出日期:  2017-11-28

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