前处理方法对原油中金刚烷化合物定量的影响

李二庭; 向宝力; 马万云; 熊永强; 王明; 米巨磊

doi:10.11781/sysydz201906916

前处理方法对原油中金刚烷化合物定量的影响

doi: 10.11781/sysydz201906916

李二庭^1,2,
向宝力^1,2,
马万云^1,2,
熊永强³,
王明^1,2,
米巨磊^1,2

1. 中国石油新疆油田分公司新疆砾岩油藏实验室, 新疆克拉玛依;
2. 中国石油新疆油田分公司实验检测研究院, 新疆克拉玛依 834000;
3. 中国科学院广州地球化学研究所有机地球化学国家重点实验室, 广州 510640

基金项目:

国家科技重大专项（2011ZX05008-002-50）和国家自然科学基金（41372136）资助。

详细信息

作者简介:
李二庭(1988-),男,高级工程师,从事油气地球化学研究。E-mail:lierting@petrochina.com.cn。

中图分类号: TE135
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出版历程
- 收稿日期: 2019-05-07
- 修回日期: 2019-08-19
- 刊出日期: 2019-11-28

Effect of pretreatment methods on determination of diamondoids in crude oils

1. Xinjiang Laboratory of Petroleum Reserve in Conglomerate, Xinjiang Oilfield Company, PetroChina, Karamay, Xinjiang 834000, China;
2. Research Institute of Experiment and Testing, Xinjiang Oilfield Company, PetroChina, Karamay, Xinjiang 834000, China;
3. State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, Guangdong 510640, China

摘要

摘要: 利用色谱/质谱/质谱方法分析了准噶尔盆地不同密度原油中金刚烷化合物的含量，探讨了族组分分离法和直接进样法2种前处理方法对金刚烷化合物测定的影响。族组分分离法会造成原油中金刚烷类化合物含量损失，特别是密度相对小的单金刚烷类损失更大，但族组分分离方法有利于低熟原油中低含量、受挥发作用影响较小的双金刚烷类化合物的富集，更有利于仪器检出。族组分分离法对金刚烷异构化指标影响较小，对应用更为重要的浓度指标影响较大，因此在进行金刚烷类化合物分析时应尽量避免复杂的前处理，减少金刚烷类化合物的损失。选择直接进样法是测定正常油、轻质油和凝析油中金刚烷类化合物的最佳前处理方法，对于部分低熟原油样品可考虑使用族组分分离法进行处理。
- 前处理 /
- 族组分分离 /
- 直接进样 /
- 金刚烷 /
- 原油 /
- 准噶尔盆地
Abstract: The content of diamondoids in crude oils of different density from the Junggar Basin was analyzed by gaschromatography-mass spectrometry-mass spectrometry to investigate the effect of group component separation and direct injection on the determination of diamondoids in crude oils. The group component separation method will result in the loss of adamantane from crude oils, especially a large loss of single adamantanes with relatively lower density. However, the group component separation method is conducive to the enrichment of low-mass adamantane compounds in low-maturity crude oils, especially the diadamantane compounds which are less affected by volatilization, and thus more favorable for detection. The group component separation process has little effect on the isomerization index of adamantane, but has a great influence on the concentration index. Therefore, in order to reduce the loss of diamondoids during preparation, complex pretreatment should be avoided as much as possible. The direct injection method is the best pretreatment method for the determination of adamantane compounds in normal oils, light oils and condensates. For some low-maturity crude oil samples, the group component separation method can be considered.
- pretreatment method /
- group component separation method /
- direct injection method /
- diamondoid /
- crude oil /
- Junggar Basin

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参考文献(17)

[1]	曾凡刚,程克明.利用双金刚烷指标研究下古生界海相碳酸盐岩的热成熟度[J].地质地球化学,1998,26(3):16-20. ZENG Fangang,CHENG Keming.Thermal maturity of Lower Palaeozoic marine carbonate rocks:a double adamantane index study[J].Geology-Geochemistry,1998,26(3):16-20.
[2]	STOUT S A,DOUGLAS G S.Diamondoid hydrocarbons:application in the chemical fingerprinting of natural gas condensate and gasoline[J].Environmental Forensics,2004,5(4):225-235.
[3]	DAHL J E,MOLDOWAN J M,PETERS K E,et al.Diamondoid hydrocarbons as indicators of natural oil cracking[J].Nature,1999,399(6731):54-57.
[4]	GRICE K,ALEXANDER R,KAGI R I.Diamondoid hydrocarbon ratios as indicators of biodegradation in Australian crude oils[J].Organic Geochemistry,2000,31(1):67-73.
[5]	任康绪,黄光辉,肖中尧,等.大宛齐原油金刚烷类化合物及其在油气运移中的应用[J].中国石油勘探,2012(2):27-31. REN Kangxu,HUANG Guanghui,XIAO Zhongyao,et al.Application of diamondoids to hydrocarbon migration in Dawanqi oilfield,Tarim Basin[J].China Petroleum Exploration,2012(2):27-31.
[6]	Wingert W S.G.C.-M.S. analysis of diamondoid hydrocarbons in Smackover petroleums[J].Fuel,1992,71(1):37-43.
[7]	WEI Zhibin,MOLDOWAN J M,PETERS K E,et al.The abundance and distribution of diamondoids in biodegraded oils from the San Joaquin Valley:implications for biodegradation of diamondoids in petroleum reservoirs[J].Organic Geochemistry,2007,38(11):1910-1926.
[8]	CHEN Junhong,FU Jiamo,SHENG Guoying,et al.Diamondoid hydrocarbon ratios:novel maturity indices for highly mature crude oils[J].Organic Geochemistry,1996,25(3/4):179-190.
[9]	SCHULZ L K,WILHELMS A,REIN E,et al.Application of diamondoids to distinguish source rock facies[J].Organic Geochemistry,2001,32(3):365-375.
[10]	ZHANG Shuichang,HUANG Haiping,XIAO Zhongyao,et al.Geochemistry of Palaeozoic marine petroleum from the Tarim Basin,NW China.Part 2:maturity assessment[J].Organic Geochemistry,2005,36(8):1215-1225.
[11]	张万峰,童婷,李东浩,等.原油中金刚烷化合物的高效分析方法[J].石油实验地质,2015,37(6):796-801. ZHANG Wanfeng,TONG Ting,LI Donghao,et al.A novel method for the determination of diamondoids in crude oils[J].Petro-leum Geology & Experiment,2015,37(6):796-801.
[12]	张魁英,杨佰娟,郑立,等.基于原油中金刚烷指纹半定量分析进行原油鉴别[J].分析化学,2011,39(4):496-500. ZHANG Kuiying,YANG Baijuan,ZHENG Li,et al.Crude oil identification based on diamondoid fingerprinting concentrations by semiquantitative method[J].Chinese Journal of Analytical Che-mistry,2011,39(4):496-500.
[13]	LIANG Qianyong,XIONG Yongqiang,FANG Chenchen,et al.Quantitative analysis of diamondoids in crude oils using Gas Chromatography-Triple Quadrupole Mass Spectrometry[J].Organic Geochemistry,2012,43:83-91.
[14]	梁前勇,熊永强,房忱琛,等.两种测定原油中金刚烷类化合物方法的对比研究[J].地球化学,2012,41(5):433-441. LIANG Qianyong,XIONG Yongqiang,FANG Chenchen,et al.Comparison of two methods for the determination of diamondoids in crude oils[J].Geochimica,2012,41(5):433-441.
[15]	陈致林,刘旋,金洪蕊,等.利用双金刚烷指标研究济阳坳陷凝析油的成熟度和类型[J].沉积学报,2008,26(4):705-708. CHEN Zhilin,LIU Xuan,JIN Hongrui,et al.Study on condensate maturity and type using methyl diamantane parameter[J].Acta Sedimentologica Sinica,2008,26(4):705-708.
[16]	郭小文,何生,陈红汉.甲基双金刚烷成熟度指标讨论与应用[J].地质科技情报,2007,26(1):71-76. GUO Xiaowen,HE Sheng,CHEN Honghan.Discussion and application of the maturity indicators of methyl double diamantane hydrocarbons[J].Geological Science and Technology Information,2007,26(1):71-76.
[17]	马安来.金刚烷类化合物在有机地球化学中的应用进展[J].天然气地球科学,2016,27(5):851-860. MA Anlai.New advancement in application of diamondoids on organic geochemistry[J].Natural Gas Geoscience,2016,27(5):851-860.