Jiang Qigui, Shen Baojian, Yang Yunfeng, Li Zhiming, Ma Yuanyuan, Qian Menhui. Kinetic analysis of hydrocarbon generation components in shales from the Bonan sub-Sag and its significance for hydrocarbon exploration[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2016, 38(2): 231-239. doi: 10.11781/sysydz201602231
Citation: Jiang Qigui, Shen Baojian, Yang Yunfeng, Li Zhiming, Ma Yuanyuan, Qian Menhui. Kinetic analysis of hydrocarbon generation components in shales from the Bonan sub-Sag and its significance for hydrocarbon exploration[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2016, 38(2): 231-239. doi: 10.11781/sysydz201602231

Kinetic analysis of hydrocarbon generation components in shales from the Bonan sub-Sag and its significance for hydrocarbon exploration

doi: 10.11781/sysydz201602231
  • Received Date: 2015-03-21
  • Rev Recd Date: 2016-01-18
  • Publish Date: 2016-03-28
  • The Paleogene shales in the East China contain Type I organic matter comprised mainly of planktonic algae. A kinetic analysis of the hydrocarbon generation of this source rock was made using a pyrolysis-gas chromatograph. The hydrocarbon generation potential, composition and oil saturation of shales in the Bonan sub-Sag were studied in the context of the thermal history of the Shahejie Formation. The hydrocarbon conversion rates of light and heavy hydrocarbons in source rocks in the middle section of the third member of Shahejie Formation (Es3) are 31.1% and 43.8%, respectively, indicating the oil generation period. The oil saturation index might reach 273.24 mg/g, showing some shale oil potential. However, the oil is too heavy for exploitation. The lower section of Es3 (and the upper section of Es4) has a high oil saturation up to 571.17 mg/g and a high elastic force with coexisting oil and gas, and hence is an excellent target for shale oil exploitation. The middle and lower sections of Es4 arrived at the peak of methane generation. Any residual oil would have been cracked. Shale gas should be the main exploration focus unless an overpressure system developed.

     

  • loading
  • [1]
    Mullen J,Lowry J C,Nwabuoku K C.Lessons learned developing the Eagle Ford shale[C]//Proceedings of Tight Gas Completions Conference.San Antonio,Texas,USA:Society of Petroleum Engineers,2010.
    [2]
    邹才能,朱如凯,吴松涛,等.常规与非常规油气聚集类型、特征、机理及展望:以中国致密油和致密气为例[J].石油学报,2012,33(2):173-187. Zou Caineng,Zhu Rukai,Wu Songtao,et al.Types,characteristics,genesis and prospects of conventional and unconventional hydrocarbon accumulations:Taking tight oil and tight gas in China as an instance[J].Acta Petrolei Sinica,2012,33(2):173-187.
    [3]
    Sonnenberg S A,Pramudito A.Petroleum geology of the giant Elm Coulee field,Williston Basin[J].AAPG Bulletin,2009,93(9):1127-1153.
    [4]
    Gibson R I.Basement tectonics and hydrocarbon production in the Williston Basin:An interpretive overview[C]//7th International Williston Basin Symposium:1995 Guidebook.Mertztown,PA,USA:Montana Geological Society,1995:3-11.
    [5]
    Passey Q R,Moretti F J,Kulla J B,et al.A practical model for organic richness from porosity and resistivity logs[J].AAPG Bulletin,1990,74(12):1777-1794.
    [6]
    张金川,林腊梅,李玉喜,等.页岩油分类与评价[J].地学前缘,2012,19(5):322-331. Zhang Jinchuan,Lin Lamei,Li Yuxi,et al.Classification and evaluation of shale oil[J].Earth Science Frontiers,2012,19(5):322-331.
    [7]
    Lafollette R,Holcomb W D,Aragon J.Impact of completion system,staging,and hydraulic fracturing trends in the Bakken Formation of the Eastern Williston Basin[C]//SPE Hydraulic Fracturing Technology Conference.The Woodlands,Texas,USA:Society of Petroleum Engineers,2012.
    [8]
    Rasdi M F,Chu L.Diagnosing fracture network pattern and flow regime aids production performance analysis in unconventional oil reservoirs[C]//SPE/EAGE European Unconventional Resources Conference and Exhibition.Vienna,Austria:Society of Petroleum Engineers,2012.
    [9]
    Centurion S M,Cade R,Luo X L.Eagle ford shale:Hydraulic fracturing,completion,and production trends:Part II[C]//SPE Annual Technical Conference and Exhibition.San Antonio,Texas,USA:Society of Petroleum Engineers,2012.
    [10]
    Orangi A,Nagarajan N R,Honarpour M M,et al.Unconventional shale oil and gas-condensate reservoir production,impact of rock,fluid and hydraulic fractures[C]//SPE Hydraulic Frac-turing Technology Conference.The Woodlands,Texas,USA:Society of Petroleum Engineers,2011.
    [11]
    Gonzales V M,Barham M R,Lawless P,et al.Understanding production drivers and challenges in converting a vertical to horizontal oil play utilizing single well modeling[C]//SPE Canadian Unconventional Resources Conference.Calgary,Alberta,Canada:Society of Petroleum Engineers,2012.
    [12]
    秦长文,秦璇.美国鹰滩和尼奥泊拉拉页岩油富集主控因素[J].特种油气藏,2015,22(3):34-37. Qin Changwen,Qin Xuan.Major controlling factors for shale oil enrichment in Eagle Ford and Niobrara Plays[J].Special Oil & Gas Reservoirs,2015,22(3):34-37.
    [13]
    李建青,高玉巧,花彩霞,等.北美页岩气勘探经验对建立中国南方海相页岩气选区评价体系的启示[J].油气地质与采收率,2014,21(4):23-27,32. Li Jianqing,Gao Yuqiao,Hua Caixia,et al.Marine shale gas evaluation system of regional selection in South China:enlightenment from North American exploration experience[J].Petroleum Geology and Recovery Efficiency,2014,21(4):23-27,32.
    [14]
    Montgomery S L,Jarvie D M,Bowker K A,et al.Mississippian Barnett Shale,Fort Worth Basin,north-central Texas:Gas-shale play with multi-trillion cubic foot potential[J].AAPG Bulletin,2005,89(2):155-175.
    [15]
    Singh P.Lithofacies and sequence stratigraphic framework of the Barnett Shale,Northeast Texas[D].Oklahoma:The University of Oklahoma,2008:1-230.
    [16]
    Rickman R,Mullen M J,Petre J E,et al.A practical use of shale petrophysics for stimulation design optimization:All shale plays are not clones of the Barnett Shale[C]//SPE Annual Technical Conference and Exhibition.Denver,Colorado,USA:Society of Petroleum Engineers,2008.
    [17]
    Schepers K C,Nuttal B C,Oudinot A Y,et al.Reservoir modeling and simulation of the Devonian gas shale of eastern Kentucky for enhanced gas recovery and CO2 storage[C]//SPE International Conference on CO2 Capture,Storage,and Utilization.San Diego,California,USA:Society of Petroleum Engineers,2009.
    [18]
    张林晔,李政,朱日房,等.济阳坳陷古近系存在页岩气资源的可能性[J].天然气工业,2008,28(12):26-29. Zhang Linye,Li Zheng,Zhu Rifang,et al.Resource potential of shale gas in Paleogene in Jiyang Depression[J].Natural Gas Industry,2008,28(12):26-29.
    [19]
    丁敏,姚志刚,张狄杰.鄂尔多斯盆地延长组长7页岩油存在的可能性分析[J].石油化工应用,2011,30(12):59-63. Ding Min,Yao Zhigang,Zhang Dijie.Analysis of the existing possibility of shale oil in the Chang 7 of Erdos Basin[J].Petrochemical Industry Application,2011,30(12):59-63.
    [20]
    陈祥,王敏,严永新,等.泌阳凹陷陆相页岩油气成藏条件[J].石油与天然气地质,2011,32(4):568-576. Chen Xiang,Wang Min,Yan Yongxin,et al.Accumulation conditions for continental shale oil and gas in the Biyang Depression[J].Oil & Gas Geology,2011,32(4):568-576.
    [21]
    宁方兴.济阳坳陷页岩油富集机理[J].特种油气藏,2015,22(3):27-30. Ning Fangxing.Mechanism of shale oil enrichment in Jiyang Depression[J].Special Oil & Gas Reservoirs,2015,22(3):27-30.
    [22]
    宁方兴.济阳坳陷不同类型页岩油差异性分析[J].油气地质与采收率,2014,21(6):6-9. Ning Fangxing.Difference analysis on different types of shale oils in Jiyang depression[J].Petroleum Geology and Recovery Efficiency,2014,21(6):6-9.
    [23]
    王勇,宋国奇,刘惠民,等.济阳坳陷页岩油富集主控因素[J].油气地质与采收率,2015,22(4):20-25. Wang Yong,Song Guoqi,Liu Huimin,et al.Main control factors of enrichment characteristics of shale oil in Jiyang depression[J].Petroleum Geology and Recovery Efficiency,2015,22(4):20-25.
    [24]
    章新文,李吉君,朱景修,等.泌阳凹陷页岩油富集段资源评价及有利区预测[J].断块油气田,2014,21(3):301-304. Zhang Xinwen,Li Jijun,Zhu Jingxiu,et al.Resource evaluation and favorable area prediction on rich section of shale oil in Bi-yang Depression[J].Fault-Block Oil and Gas Field,2014,21(3):301-304.
    [25]
    胡望水,张骜,王长江,等.长岭坳陷地区嫩江组一段页岩油资源评价[J].特种油气藏,2014,21(1):46-49. Hu Wangshui,Zhang Ao,Wang Changjiang,et al.Evaluation of the Nunjiang Formation member I shale oil resources in the Changling depression[J].Special Oil & Gas Reservoirs,2014,21(1):46-49.
    [26]
    张善文,王永诗,张林晔,等.济阳坳陷渤南洼陷页岩油气形成条件研究[J].中国工程科学,2012,14(6):49-55,63. Zhang Shanwen,Wang Yongshi,Zhang Linye,et al.Formation conditions of shale oil and gas in Bonan sub-Sag,Jiyang Depression[J].Engineering Science,2012,14(6):49-55,63.
    [27]
    张大伟.加快中国页岩气勘探开发和利用的主要路径[J].天然气工业,2011,31(5):1-5. Zhang Dawei.Main solution ways to speed up shale gas exploration and development in China[J].Natural Gas Industry,2011,31(5):1-5.
    [28]
    张林晔,李政,李钜源,等.东营凹陷古近系泥页岩中存在可供开采的油气资源[J].天然气地球科学,2012,23(1):1-13. Zhang Linye,Li Zheng,Li Juyuan,et al.Feasibility analysis of existing recoverable oil and gas resource in the Palaeogene shale of Dongying Depression[J].Natural Gas Geoscience,2012,23(1):1-13.
    [29]
    王永诗,李政,巩建强,等.济阳坳陷页岩油气评价方法:以沾化凹陷罗家地区为例[J].石油学报,2013,34(1):83-91. Wang Yongshi,Li Zheng,Gong Jianqiang,et al.Discussion on an evaluation method of shale oil and gas in Jiyang Depression:a case study on Luojia area in Zhanhua Sag[J].Acta Petrolei Sinica,2013,34(1):83-91.
    [30]
    王永诗,王伟庆,郝运轻.济阳坳陷沾化凹陷罗家地区古近系沙河街组页岩储集特征分析[J].古地理学报,2013,15(5):657-662. Wang Yongshi,Wang Weiqing,Hao Yunqing.Shale reservoir characteristics analysis of the Paleogene Shahejie Formation in Luojia area of Zhanhua Sag,Jiyang Depression[J].Journal of Palaeogeography,2013,15(5):657-662.
    [31]
    武晓玲,高波,叶欣,等.中国东部断陷盆地页岩油成藏条件与勘探潜力[J].石油与天然气地质,2013,34(4):455-462. Wu Xiaoling,Gao Bo,Ye Xin,et al.Shale oil accumulation conditions and exploration potential of faulted basins in the east of China[J].Oil & Gas Geology,2013,34(4):455-462.
    [32]
    盛湘,陈祥,章新文,等.中国陆相页岩油开发前景与挑战[J].石油实验地质,2015,37(3):267-271. Sheng Xiang,Chen Xiang,Zhang Xinwen,et al.Prospects and challenges of continental shale oil development in China[J].Petroleum Geology & Experiment,2015,37(3):267-271.
    [33]
    朱德顺,王勇,朱德燕,等.渤南洼陷沙一段夹层型页岩油界定标准及富集主控因素[J].油气地质与采收率,2015,22(5):15-20. Zhu Deshun,Wang Yong,Zhu Deyan,et al.Analysis on recognition criteria and enrichment factors of interlayer shale oil of Es1 in Bonan subsag[J].Petroleum Geology and Recovery Efficiency,2015,22(5):15-20.
    [34]
    高平,张放东,尚雅珍.濮卫次洼沙三段页岩油藏勘探潜力与实践[J].断块油气田,2014,21(1):39-42. Gao Ping,Zhang Fangdong,Shang Yazhen.Exploration potential and practice of Es3 shale reservoir in Puwei Sag[J].Fault-Block Oil and Gas Field,2014,21(1):39-42.
    [35]
    陈永昌,张金川,苏惠,等.东濮凹陷北部沙三段页岩油成藏地质条件分析[J].特种油气藏,2014,21(3):62-65. Chen Yongchang,Zhang Jinchuan,Su Hui,et al.Analysis of geologic conditions for Es3 shale oil accumulation in the northern Dongpu sag[J].Special Oil & Gas Reservoirs,2014,21(3):62-65.
    [36]
    张馨,邹艳荣,蔡玉兰,等.原油族组分在煤中留存能力的研究[J].地球化学,2008,37(3):233-238. Zhang Xin,Zou Yanrong,Cai Yulan,et al.Retention potential of oil group-type in coals[J].Geochimica,2008,37(3):233-238.
    [37]
    Horsfield B,Muscio G P,Grice K,et al.Gas generation and retention in the Bakken Shale,Williston Basin[C]//AAPG Annual Convention.San Antonio,TX:AAPG,2008.
    [38]
    Jarvie D M.Unconventional oil petroleum systems:shales and shale hybrids[C]//AAPG International Conference and Exhibition.Calgary,Alberta,Canada:AAPG,2010.
    [39]
    蒋启贵,马媛媛,李欣.单冷阱热解色谱仪在烃源岩评价中的应用[J].石油实验地质,2011,33(5):546-551. Jiang Qigui,Ma Yuanyuan,Li Xin.Application of single cold trap pyrolysis chromatography in source rock evaluation[J].Petroleum Geology & Experiment,2011,33(5):546-551.
    [40]
    郭瑞超,李延钧,王廷栋,等.胜利油田渤南洼陷古近系油气源与成藏特征[J].新疆石油地质,2009,30(6):674-676. Guo Ruichao,Li Yanjun,Wang Tingdong,et al.Oil-gas source and accumulation characteristics of Palaeogene in Bonan sub-sag in Shengli oil field[J].Xinjiang Petroleum Geology,2009,30(6):674-676.
    [41]
    秦延才,徐福刚,赵翠霞,等.渤南油田沙三段含油体系研究[J].油气地质与采收率,2002,9(3):59-62. Qin Yancai,Xu Fugang,Zhao Cuixia,et al.Research on Es3 oil bearing system in Bonan oilfield[J].Petroleum Geology and Recovery Efficiency,2002,9(3):59-62.
    [42]
    张枝焕,曾艳涛,张学军,等.渤海湾盆地沾化凹陷渤南洼陷原油地球化学特征及成藏期分析[J].石油实验地质,2006,28(1):54-58. Zhang Zhihuan,Zeng Yantao,Zhang Xuejun,et al.The geochemistry characteristics and accumulation history of crude oil in the Bonan sub-sag of the Zhanhua Sag,the Bohaiwan Basin[J].Petroleum Geology & Experiment,2006,28(1):54-58.
    [43]
    杨绪充.济阳坳陷中新生代古地温分析[J].石油大学学报,1988,12(3):23-33. Yang Xuchong.Paleogeothermal analyses of the Mesozoic and the Cenozoic in Jiyang Depression[J].Journal of the University of Petroleum,China,1988,12(3):23-33.
    [44]
    邱楠生,李善鹏,曾溅辉.渤海湾盆地济阳坳陷热历史及构造-热演化特征[J].地质学报,2004,78(2):263-269. Qiu Nansheng,Li Shanpeng,Zeng Jianhui.Thermal history and tectonic-thermal evolution of the Jiyang Depression in the Bohai Bay Basin,East China[J].Acta Geologica Sinica,2004,78(2):263-269.
    [45]
    卢双舫,黄文彪,陈方文,等.页岩油气资源分级评价标准探讨[J].石油勘探与开发,2012,39(2):249-256. Lu Shuangfang,Huang Wenbiao,Chen Fangwen,et al.Classification and evaluation criteria of shale oil and gas resources:Discussion and application[J].Petroleum Exploration and Development,2012,39(2):249-256.
    [46]
    张林晔,李钜源,李政,等.陆相盆地页岩油勘探开发关键地质问题研究:以东营凹陷为例[C]//页岩油资源与勘探开发技术国际研讨会.无锡:[s.n.],2012. Zhang Linye,Li Juyuan,Li Zheng,et al.Geologic analysis of the key factors for shale oil exploration in continental basins:A case study of the Dongying Sag[C]//International Conference of Shale Oil Resources and Exploration.Wuxi:[s.n.],2012.
    [47]
    秦建中,郑伦举,腾格尔.海相高演化烃源岩总有机碳恢复系数研究[J].地球科学:中国地质大学学报,2007,32(6):853-860. Qin Jianzhong,Zheng Lunju,Tenger.Study on the restitution coefficient of original total organic carbon for high mature marine hydrocarbon source rocks[J].Earth Science:Journal of China University of Geosciences,2007,32(6):853-860.
    [48]
    梁狄刚,张水昌,张宝民,等.从塔里木盆地看中国海相生油问题[J].地学前缘,2000,7(4):534-547. Liang Digang,Zhang Shuichang,Zhang Baomin,et al.Understanding on marine oil generation in China based on Tarim Basin[J].Earth Science Frontiers,2000,7(4):534-547.
    [49]
    张水昌,梁狄刚,张大江.关于古生界烃源岩有机质丰度的评价标准[J].石油勘探与开发,2002,29(2):8-12. Zhang Shuichang,Liang Digang,Zhang Dajiang.Evaluation criteria for Paleozoic effective hydrocarbon source rocks[J].Petroleum Exploration and Development,2002,29(2):8-12.
    [50]
    周总瑛.烃源岩演化中有机碳质量与含量变化定量分析[J].石油勘探与开发,2009,36(4):463-468. Zhou Zongying.Quantitative analysis of variation of organic carbon mass and content in source rock during evolution process[J].Petroleum Exploration and Development,2009,36(4):463-468.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (1133) PDF downloads(1326) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return