SONG Di, XU Chang, YAO Suping, TENGER Boltsjin. Influence of graptolite debris on shale gas generation and accumulation[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2019, 41(4): 540-547. doi: 10.11781/sysydz201904540
Citation: SONG Di, XU Chang, YAO Suping, TENGER Boltsjin. Influence of graptolite debris on shale gas generation and accumulation[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2019, 41(4): 540-547. doi: 10.11781/sysydz201904540

Influence of graptolite debris on shale gas generation and accumulation

doi: 10.11781/sysydz201904540
  • Received Date: 2018-12-11
  • Rev Recd Date: 2019-05-23
  • Publish Date: 2019-07-28
  • As one of the standard fossils of the Ordovician and Silurian, graptolites are widely distributed in the Upper Ordovician Wufeng Formation to the Lower Silurian Longmaxi Formation in the Lower Paleozoic of South China. This stratum shows a good potential for shale gas exploration; however, there is a disagreement about the contribution of graptolite debris to the generation and storage of shale gas. Acid treatment was carried out on shale samples from the Wufeng-Longmaxi formations in well Weiye 1 in the Weiyuan and Changning areas of the Sichuan Basin. Graptolite debris was collected and analyzed with Microscopic Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy and Transmission Electron Microscopy. The composition and pore development characteristics of the organic matter in graptolites were examined, and the contribution of graptolite bodies to shale reservoir capacity was discussed. The graptolite bodies were mainly composed of organic matter of collagen, which shows a poor gas potential. However, the inner fetal tube of the graptolite body is hollow, and strawberry-like pyrite is developed in the body cavity, which is favorable for the storage of shale gas. The graptolite bodies are superposed on each other to form a multi-layer structure, and the vertical and horizontal stripes and the nano-mineral partitions in the graptolite skin form gaps between the stacked graptolite skins, thereby improving shale gas storage. Therefore, it is believed that the large number of graptolites in the Wufeng-Longmaxi formation shale is one of the important reasons that affect the shale gas enrichment in this segment.

     

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  • [1]
    王传尚,汪啸风.早-中奥陶世之交笔石动物群全球分布及其控制作用[J].地质科技情报,2011,30(2):41-44.

    WANG Chuanshang,WANG Xiaofeng.Global distribution of graptolite fauna and its controlling factor during the Lower-Middle Ordovician transitional period[J].Geological Science and Technology Information,2011,30(2):41-44.
    [2]
    陈旭,樊隽轩,张元动,等.五峰组及龙马溪组黑色页岩在扬子覆盖区内的划分与圈定[J].地层学杂志,2015,39(4):351-358.

    CHEN Xu,FAN Junxuan,ZHANG Yuandong,et al.Subdivision and delineation of the Wufeng and Lungmachi black shales in the subsurface areas of the Yangtze Platform[J].Journal of Stratigraphy,2015,39(4):351-358.
    [3]
    RIEDIGER C,GOODARZI F,MACQUEEN R W.Graptolites as indicators of regional maturity in Lower Paleozoic sediments,Selwyn Basin,Yukon and Northwest Territories,Canada[J].Canadian Journal of Earth Sciences,1989,26(10):2003-2015.
    [4]
    邝国敦.广西常见化石图鉴[M].武汉:中国地质大学出版社,2014. KUANG Guodun.The index fossil atlas of Guangxi[M].Wuhan:China University of Geosciences Press,2014.
    [5]
    穆恩之.正笔石及正笔石式树形笔石的演化、分类和分布[J].中国科学,1974(2):174-183. MU Enzhi.Evolution,classification and distribution of graptoloidea and graptodendroids[J].Scientia Sinica,1974,15(2):227-238.
    [6]
    樊隽轩,MELCHIN M J,陈旭,等.华南奥陶-志留系龙马溪组黑色笔石页岩的生物地层学[J].中国科学:地球科学,2012,42(1):130-139.

    FAN Junxuan,MELCHIN M J,CHEN Xu,et al.Biostratigraphy and geography of the Ordovician-Silurian Lungmachi black shales in South China[J].Science China Earth Sciences,2011,54(12):1854-1863.
    [7]
    聂海宽,金之钧,马鑫,等.四川盆地及邻区上奥陶统五峰组-下志留统龙马溪组底部笔石带及沉积特征[J].石油学报,2017,38(2):160-174.

    NIE Haikuan,JIN Zhijun,MA Xin,et al.Graptolites zone and sedimentary characteristics of Upper Ordovician Wufeng Formation-Lower Silurian Longmaxi Formation in Sichuan Basin and its adjacent areas[J].Acta Petrolei Sinica,2017,38(2):160-174.
    [8]
    聂海宽,唐玄,边瑞康.页岩气成藏控制因素及中国南方页岩气发育有利区预测[J].石油学报,2009,30(4):484-491.

    NIE Haikuan,TANG Xuan,BIAN Ruikang.Controlling factors for shale gas accumulation and prediction of potential development area in shale gas reservoir of South China[J].Acta Petrolei Sinica,2009,30(4):484-491.
    [9]
    腾格尔,申宝剑,俞凌杰,等.四川盆地五峰组-龙马溪组页岩气形成与聚集机理[J].石油勘探与开发,2017,44(1):69-78.

    TENGER B,SHEN Baojian,YU Lingjie,et al.Mechanisms of shale gas generation and accumulation in the Ordovician Wufeng-Longmaxi formation,Sichuan Basin,SW China[J].Petroleum Exploration and Development,2017,44(1):69-78.
    [10]
    刘大锰,侯孝强,蒋金鹏.笔石组成与结构的微区分析[J].矿物学报,1996,16(1):53-57.

    LIU Dameng,HOU Xiaoqiang,JIANG Jinpeng.The composition and structure of graptolite:a micro-area analysis[J].Acta Mineralogica Sinica,1996,16(1):53-57.
    [11]
    DOYLE B B,BENDIT E G,BLOUT E R.Infrared spectroscopy of collagen and collagen-like polypeptides[J].Biopolymers,1975,14(5):937-957.
    [12]
    DURAND B.Kerogen:insoluble organic matter from sedimentary rock[M].Paris:Editions Technip,1980:55-112.
    [13]
    TOWE K M,URBANEK A.Collagen-like structures in Ordovician graptolite periderm[J].Nature,1972,237(5356):443-445.
    [14]
    CROWTHER P R.The fine structure of the graptolite periderm[R].Special Papers in Palaeontology.London:[s.n],1981:1-119.
    [15]
    BUSTIN R M,LINK C,GOODARZI F.Optical properties and chemistry of graptolite periderm following laboratory simulated maturation[J].Organic Geochemistry,1989,14(4):355-364.
    [16]
    王勤,钱门辉,蒋启贵,等.中国南方海相烃源岩中笔石生烃能力研究[J].岩矿测试,2017,36(3):258-264.

    WANG Qin,QIAN Menhui,JIANG Qigui,et al.A study on hydrocarbon generation capacity of graptolite in marine hydrocarbon source rocks in southern China[J].Rock and Mineral Analysis,2017,36(3):258-264.
    [17]
    TEGELAAR E W,DE LEEUW J W,DERENNE S,et al.A reappraisal of kerogen formation[J].Geochimica et Cosmochimica Acta,1989,53(11):3103-3106.
    [18]
    周圆圆,吉珍娃,申宝剑,等.成烃生物对页岩含气性影响控制因素研究进展[J].矿物岩石地球化学通报,2017,36(2):332-338.

    ZHOU Yuanyuan,JI Zhenwa,SHEN Baojian,et al.Research progress on main controlling factor of hydrocarbon-forming organisms in gas-bearing property[J].Bulletin of Mineralogy,Petrology and Geochemistry,2017,36(2):332-338.
    [19]
    马施民,邹晓艳,朱炎铭,等.川南龙马溪组笔石类生物与页岩气成因相关性研究[J].煤炭科学技术,2015,43(4):106-109.

    MA Shimin,ZOU Xiaoyan,ZHU Yanming,et al.Study on relationship between graptolite and shale gas origin of Longmaxi Formation in southern Sichuan[J].Coal Science and Techno-logy,2015,43(4):106-109.
    [20]
    杨永军.贵州遵义松林地区寒武系牛蹄塘组下部烃源岩评价[D].成都:成都理工大学,2010. YANG Yongjun.The evaluate of the source rocks of Cambrian Niutitang Formation in Songlin,Zunyi area of Guizhou Province[D].Chengdu:Chengdu University of Technology,2010.
    [21]
    陶树,汤达祯,伍大茂,等.中、上扬子区下组合烃源岩有机岩石学特征[J].中国矿业大学学报,2010,39(4):575-581.

    TAO Shu,TANG Dazhen,WU Damao,et al.Organic petrology characteristics of lower assemblage source rocks in Upper and Middle Yangtze region[J].Journal of China University of Mining & Technology,2010,39(4):575-581.
    [22]
    赵陵.滇黔桂地区海相生油岩有机质类型的恢复[J].贵州地质,2000,17(2):86-91.

    ZHAO Ling.Restitution of organic matter type in marine-facing oil source rock in Guizhou-Yunnan-Guangxi area[J].Guizhou Geology,2000,17(2):86-91.
    [23]
    胡明霞,曹寅.下古生界烃源岩有机显微组分分类与应用[J].石油实验地质,2007,29(4):432-435.

    HU Mingxia,CAO Yin.Classification and application of organic macerals in the Lower Paleozoic hydrocarbon source rock[J].Petroleum Geology & Experiment,2007,29(4):432-435.
    [24]
    穆恩之.中国笔石[M].北京:科学出版社,2002. MU Enzhi.Chinese graptolite[M].Beijing:Science Press,2002.
    [25]
    张元动,陈旭.华南早-中奥陶世笔石动物的辐射演化[M]//戎嘉余,方宗杰,周忠和,等.生物的起源、辐射与多样性演变:华夏化石记录的启示.北京:科学出版社,2006:285-316. ZHANG Yuandong,CHEN Xu.Radiation evolution of Early-Middle Ordovician graptolite animals in South China[M]//RONG Jiayu,FANG Zongjie,ZHOU Zhonghe,et al.Originations,radiations and biodiversity changes:evidences from the Chinese fossil record.Beijing:Science Press,2006:285-316.
    [26]
    BULMAN O M B.Some species of Bryograptus and Pseudobryograptus from northwest Europe[J].Geological Magazine,1971,108(5):361-371.
    [27]
    URBANEK A,TOWE K M.Ultrastructural studies on graptolites,1:the periderm and its derivatives in the dendroidea and in mastigograptus[J].Smithsonian Contributions to Paleobiology,1974,20:1-48.
    [28]
    贝思D E B,柯克N H,赵宇虹,等.利用扫描电子显微镜对笔石超微构造的研究[J].古生物学报,1988,27(5):527-535.

    BETH D E B,KIRK N H,ZHAO Yuhong,et al.Ultrastructure of graptolites by scanning electron microscope[J].Acta Palaeontologica Sinica,1988,27(5):527-535.
    [29]
    MELCHIN M J,ANDERSON A J.Infrared video microscopy for the study of graptolites and other organic-walled fossils[J].Journal of Paleontology,1998,72(2):397-400.
    [30]
    魏志红.富有机质页岩有机质孔发育差异性探讨:以四川盆地五峰组-龙马溪组笔石页岩为例[J].成都理工大学学报(自然科学版),2015,42(3):361-365. WEI Zhihong.Difference of organic pores in organic matter:a case from graptolite shales of Wufeng Formation-Longmaxi Formation in Sichuan Basin,China[J].Journal of Chengdu University of Technology(Science & Technology Edition),2015,42(3):361-365.
    [31]
    胥畅,王文卉,姚素平.聚焦离子束扫描电镜研究微体化石的微观孔隙结构[J].高校地质学报,2016,22(1):207-212.

    XU Chang,WANG Wenhui,YAO Suping.A study into the microscopic pore structure of microfossils with Focused Ion Beam Scanning Electron Microscopy (FIB-SEM)[J].Geological Journal of China Universities,2016,22(1):207-212.
    [32]
    邓昆,周文,周立发,等.鄂尔多斯盆地奥陶系平凉组笔石页岩微孔隙特征及其影响因素[J].石油勘探与开发,2016,43(3):378-385.

    DENG Kun,ZHOU Wen,ZHOU Lifa,et al.Influencing factors of micropores in the graptolite shale of Ordovician Pingliang Formation in Ordos Basin,China[J].Petroleum Exploration and Development,2016,43(3):378-385.
    [33]
    戴娜,钟宁宁,张瑜,等.氩离子抛光/扫描电镜分析方法在笔石有机质研究中的应用[J].电子显微学报,2015,34(5):416-420.

    DAI Na,ZHONG Ningning,ZHANG Yu,et al.Ar ion milling/SEM analysis on graptolitinite macerals[J].Journal of Chinese Electron Microscopy Society,2015,34(5):416-420.
    [34]
    MA Yong,ZHONG Ningning,CHENG Lijun,et al.Pore structure of the graptolite-derived OM in the Longmaxi shale,southeastern Upper Yangtze region,China[J].Marine and Petroleum Geology,2016,72:1-11.
    [35]
    ZHANG Han,ZHU Yanming,WANG Yang,et al.Comparison of organic matter occurrence and organic nanopore structure within marine and terrestrial shale[J].Journal of Natural Gas Science and Engineering,2016,32:356-363.
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