GEOCHEMICAL ANALYSES ON THE HYDROCARBON COMPOSITION CHANGES AND POOL-FORMING MECHANISMS OF SHUANGNAN OILFIELD IN THE WEST LIAOHE SAG
-
摘要: 双南地区以产正常原油为主,并伴有少量的凝析油.观察发现,凝析油和正常油的总体特征(密度、粘度、含蜡量和凝固点)和某些生物标志化合物的含量变化较大.详细的地化分析表明,它们的成熟度相当.用多种分子标志物进行成熟度评估,可知液态烃的成熟度相当于Ro为0.7%~0.8%.这些原油有相同的生源构成,并形成于相似的沉积环境之中.原油总体组成和分子组成的变化归因于运移分馏过程,在该过程中气凝析油从与之相关的原油中分离出来,并运移到较浅的储层中聚集.认识运移分馏的过程和理解它在石油组分上的作用十分重要,因为许多用于油油、油源对比以及原油蚀变、油源类型和热成熟度等方面的地球化学指标都可能受到运移分馏作用的影响.Abstract: Shuangnan area produces mainly normal crude oil along with small amounts of condensate.It is discovered by observation that the total properties of condensate and normal oil(including density,viscosity,wax content,solidifying point,etc.)and the content of some biomarkers change greatly.Detail geochemical analyses reveal that they are well-matched in maturity.Many kinds of biomarkers are used to make maturity evaluation.The matutity of liquid hydrocarbon Ro is equal to 0.7%-0.8%.These crude oils have the same biological source composition,and are formed in the similar sedimentary environments.The total and molecular composition changes of crude oil are attributed to migration-fractionation process.In this process,gas-condensate is partitioned from the related crude oil,and then migrates to shallower reservoirs and accumulates there.It is very important to recognize the migration-fractionation process and understand its effects on petroleum components,because many geochemical bimarkers applied in oil-oil and oil-source correlation as well as crude oil alteration,oil source types,thermal maturity,etc.may be influenced by the migration-fractionation process.
-
Key words:
- condensate /
- biomarker /
- crude oil composition /
- maturity /
- migration-fractionation process /
- Shuangnan oilfield
-
[1] Tissot B P,Welte D H.Petroleum Formation and Occurrence-A New Approach to Oil and Gas Exploration[M].Berlin:Springer,1984. [2] Snowdon L R,Powell T G.Immature oil and condensate-modification of hydrocarbon generation model for terrestrial organic matter[J].AAPG Bulletin,1982,66:775-788. [3] 卢松年,张刚.一种新的凝析油形成模式[J].中国科学(B辑),1994,24(1). [4] Gussow W C.Differential entrapment of oil and gas-a fundamental principle[J].AAPG Bulletin,1954,38:816-853. [5] Silverman S R.Migration and segregation of oil and gas[A].Yong A,Galley G E.Fluids in Subsurface Environments[C].AAPG Memoir,1965,4:53-65. [6] Thompson K F M.Fractionated aromatic petroleum and the ge-neration of gas-condensates[J].Org Geochem,1987,11(6):573-590. [7] Thompson K F M.Gas-condensate migration and oil fractionation in deltaic system[J].Mar Petrol Geol,1988,5:237-246. [8] Curiale J A,Bromley B W.Migration induced compositional change in oils and condensates of a single field[J].Org Geochem,1996,24(12):1 097-1 113. [9] Napitulu H,Ellis L,Mitterer R M.Post-generative alteration efforts on petroleum in the onshore Northwest Java Basin,Indonesia[J].Org Geochem,2000,31:295-315. [10] Dzou L I P,Hughes W B.Geochemistry of oils and condensates,K Field,offshore Taiwan:a case study in migration fractionation[J].Org Geochem,1993,20(4):437-462. [11] Khavari-Khorasani G,Dolson J C,Michlsen J K.The factors controlling the abundance and migration of heavy versus light oils,as constrained by data from the Gulf of Suez(Part I:the effect of expelled petroleum composition,PVT properties and petroleum system geometry)[J].Org Geochem,1998,29(1-3):255-282. [12] 葛泰生,陈义贤.中国石油地质志(卷三),辽河油田[M].北京:石油工业出版社,1993. [13] 张水昌.运移分馏作用:凝析油和蜡质油形成的一种重要机制.科学通报.2000,5(6):667-670. [14] Radke M.Application of aromatic compounds as maturity indicators in source rocks and crude oils[J].Mar Petrol Geol,1988,5:224-236. [15] Mello M R,Maxwell J R.Organic geochemical and biological marker characterization of source rocks and oils from lacustrine environments in the Brazilian Continental Margin[A].Katz B J.Lacustrine Basin Exploration[C].AAPG Memoir,1990,50:77-97. [16] Hughes W B,Holba A G,Dzou L I P.The ratios of dibenzo-thiophene to phenanthrene and pristane to phytane as indicators of depositional environment and lithology of petroleum source rocks[J].Geochimica et Cosmochimica Acta,1995,59:3 581-3 598.
点击查看大图
计量
- 文章访问数: 588
- HTML全文浏览量: 25
- PDF下载量: 327
- 被引次数: 0