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沥青质轻度化学氧化降解产物中正庚烷可溶组分的特征

廖泽文 耿安松

廖泽文, 耿安松. 沥青质轻度化学氧化降解产物中正庚烷可溶组分的特征[J]. 石油实验地质, 2003, 25(1): 45-52. doi: 10.11781/sysydz200301045
引用本文: 廖泽文, 耿安松. 沥青质轻度化学氧化降解产物中正庚烷可溶组分的特征[J]. 石油实验地质, 2003, 25(1): 45-52. doi: 10.11781/sysydz200301045
LIAO Ze-wen, GENG An-song. CHARACTERISTICS OF N-HEPTANE-SOLUBLE COMPONENTS IN THE MILD CHEMICAL OXIDATION DEGRADED PRODUCTS OF ASPHALTENE[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2003, 25(1): 45-52. doi: 10.11781/sysydz200301045
Citation: LIAO Ze-wen, GENG An-song. CHARACTERISTICS OF N-HEPTANE-SOLUBLE COMPONENTS IN THE MILD CHEMICAL OXIDATION DEGRADED PRODUCTS OF ASPHALTENE[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2003, 25(1): 45-52. doi: 10.11781/sysydz200301045

沥青质轻度化学氧化降解产物中正庚烷可溶组分的特征

doi: 10.11781/sysydz200301045
基金项目: 中国科学院"九五"重点项目(KZ952-S1-436).
详细信息
    作者简介:

    廖泽文(1969-),男(汉族),四川自贡人,博士,主要从事油气地球化学研究.

  • 中图分类号: TE122.1

CHARACTERISTICS OF N-HEPTANE-SOLUBLE COMPONENTS IN THE MILD CHEMICAL OXIDATION DEGRADED PRODUCTS OF ASPHALTENE

  • 摘要: 沥青质分子骨架中吸附、包裹了一些烃类组分,这些组分较少受到油藏后期演化的改造,被认为具有原生性,包含有重要的有机地球化学信息.实验结果表明,通过轻度化学氧化降解处理可以合理释放出沥青质分子骨架中这些具有原生性的组分,在油/油对比、油/源对比、油藏有机质沉积环境以及油藏的次生改造等研究方面可获得较好应用;特别是针对一些遭受后期严重降解的油藏而言,在恢复原始有机地球化学信息研究方面更具有重要意义.

     

  • [1] Speight J G.Asphaltenes in crude oil and bitumen:structure and dispersion[J].Adv Chem Ser,1996,251(Suspensions:Fundamentals and Applications in the Petroleum Industry):377-401.
    [2] Mansoori G A.Modeling of asphaltene and other heavy organic depositions[J].Journal of Petroleum Science and Engineering,1997,17:101-111.
    [3] Strausz O P,Mojelsky T W,Faraji F,et al.Additional structural details on Athabasca asphaltene and their ramifications[J].Energy &Fuels.1999,13(a):207-227.
    [4] Strausz O P,Mojelsky T W,Lown E M,et al.Structural features of Boscan and Duri asphaltene[J].Energy &Fuels,1999,13(b):228-247.
    [5] Bergmann U,Mullins O,Cramer S P.X-ray Raman spectroscopy of carbon in asphaltene:light element characterization with bulk sensitivity[J].Anal Chem,2000,72(11):2609-2612.
    [6] Calemma V,Rausa R,D'Antona P.et al.Characterization of asphaltenes molecular structure[J].Energy &Fuels,1998,12:422-428.
    [7] Acevedo S,Escobar G,Ranaudo M N,et al.Observations about the structure and dispersion of petroleum asphaltenes aggregates obtained from dialysis fractionation and characterization[J].Energy &Fuels,1997,11:774-778.
    [8] Mujica V,Nieto P,Puerta L,et al.Caging of molecules by asphaltenes:a model for free radical preservation in crude oils[J].Energy &Fuel,2000,14(3),632-639.
    [9] Murgich J,Abanero J A,Strausz O P.Molecular recognition in aggregates formed by asphaltene and resin molecules from the Athabasca oil sand[J].Energy &Fuel,1999,13(2):278-286.
    [10] Schabron J F,Speight J G.The solubility and three-dimensional structure of asphaltenes[J].Petroleum Science and Technology,1998,16(3-4):361-375.
    [11] Behar F,Pelet R,Roucache J.Geochemistry of asphaltenes[J].Org Geochem,1984,16:587-595.
    [12] Ekweozor C M.Tricyclic terpenoid derivatives from chemical degradation reactions of asphaltenes[J].Org Geochem,1984,6:51-61.
    [13] Ekweozor C M.Characterisation of the non-asphaltene pro-ducts of mild chemical degradation of asphaltenes[J].Org Geochem,1986,10:1053-1058.
    [14] Rubinstein I'Strausz O P.Thermal treatment of the Athabasca oil sand bitumen and its component parts[J].Geochimica et Cosmochimica Acta,1979,43:1887-1893.
    [15] Wilhelms A,Larter S R.Characterization of asphaltenes by pyrolysis-field ionization mass spectrometry-some observations[J].Org Geochem,1993,20(7):1049-1062.
    [16] Rubinstein I,Spyckerelle C,Strausz O P.Pyrolysis of asphaltenes:a source of geochemical information[J].Geochi-mica et Cosmochimica Acta,1979,43:1-6.
    [17] Magnier C,Huc A Y.Pyrolysis of asphaltenes as a tool for reservoir geochemistry[J].Org Geochem,1995,23:963-967.
    [18] Jones D M,Douglas A G,Connan J.Hydrous pyrolysis of asphaltenes and polar fractions of biodegraded oils[J].Org Geochem,1988,13:981-993.
    [19] Liao Zewen,Geng Ansong.Study of pyrolysis kinetics of asphaltenes in Silurian oilsands in the Tarim basin [J].Acta Geological Sinica,2000,74(3):680-684.
    [20] 熊永强,耿安松.辽河油田生物降解原油沥青质热解产物中单体化合物碳同位素组成[J].地球化学,1998,27(6):532-536.
    [21] Geng Ansong,Liao Zewen.Kinetic studies on the pyrolysis of asphaltenes from different types of kerogens [J].Chinese Science Bulletin,2000,45(Supplement):53-59.
    [22] Anonymous.Stabilization oils to minimize asphaltene deposition[J].Research Disclosure,2000,43272:686-689.
    [23] Laux H,Rahimian I,Butz T.Theoretical and practical approach to the selection of asphaltene dispersing agents[J].Fuel Processing Technology,2000,67:79-89.
    [24] Pan H,Firoozabadi A.Thermodynamic micellization model for asphaltene precipitation inhibition[J].AIChE,2000,46(2):416-426.
    [25] Peters K E,Moldowan J M.The Biomarker Guide:Interpreting Molecular Fossils in Petroleum and Ancient Sediments[M].Pretice Hall Inc,1993.79-188.
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出版历程
  • 收稿日期:  2001-09-17
  • 修回日期:  2002-10-17
  • 刊出日期:  2003-01-25

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