渤海湾盆地东营凹陷烃源岩生烃动力学研究

王建宝; 肖贤明; 郭汝泰; 鹿洪友; 高喜龙

doi:10.11781/sysydz200304403

渤海湾盆地东营凹陷烃源岩生烃动力学研究

doi: 10.11781/sysydz200304403

中国科学院, 广州地球化学研究所, 有机地球化学国家重点实验室, 广东, 广州, 510640

基金项目: 国家自然科学基金资助(40072043).

详细信息

作者简介:
王建宝(1963- ),男(汉族),山东东营人,高级工程师、博士生,主要从事油气地质研究工作.

中图分类号: TE122.1
计量
- 文章访问数: 702
- HTML全文浏览量: 49
- PDF下载量: 364
- 被引次数: 0
出版历程
- 收稿日期: 2002-10-10
- 修回日期: 2003-05-20
- 刊出日期: 2003-07-25

STUDY ON THE HYDROCARBON GENERATION KINETICS OF SOURCE ROCKS FROM THE DONGYING DEPRESSION, THE BOHAIWAN BASIN

titute of Geochemistry, Chinese Academy of Sciences, Guangzhou, Guangdong 510640, China

摘要

摘要: 大量研究已经证明,将干酪根生烃热模拟实验结果直接应用于含油气盆地烃源岩评价存在很大风险性。生烃动力学方法可将实验生烃数据外推地质过程,因而具有较高的应用价值。本研究采用金管高压釜封闭体系对渤海湾盆地东营凹陷1块Es⁴⁽²⁾褐色页岩进行了生烃动力学研究,对热模拟产物4种组成C₁、C_1-5、C_6-12及C₁₃⁺生成动力学参数,采用Kinetics动力学软件进行计算,并模拟了具体地质条件下的成烃规律。将本研究结果与早期研究结果以及实际地质资料进行了对比,结果表明,烃源岩生烃动力学模型可较好吻合地质条件下生烃过程,在油气勘探中具有广泛应用前景。
- 生烃动力学 /
- 封闭体系 /
- 烃源岩 /
- 东营凹陷
Abstract: Lot of research work has shown that great risk will be introduced by a direct use of thermal simulation of petroleum generation pattern of a source rock. Kinetics method of hydrocarbon generation can be used to exptrapolation of the kinetics of oil and gas formation from laboratory experiments to sedimentary basins. Thus, the data obtained by this method are greater valuable for source rock evaluation. In this paper, the petroleum generation pattern of kerogen of the Lower Tertiary brown black shale from the Dong-ying Depression was studied using a golden tube-high pressure stove, and the petroleum generation kine-tics parameters of the kerogen for the four group compositions of C₁,C_1-5,C_6-12 and C₁₃⁺ were deduced by a patented software Kinetics. A comparison was made between this result and the geological data, showing that petroleum generation model obtained by this method can match with petroleum generation pattern of the source rocks in geological conditions. The kinetics method of petroleum generation will have wide application in source rock evaluation.
- petroleum generation /
- kinetics /
- closed system /
- source rock

HTML全文

参考文献(20)

[1]	Behar F, Tang T Liu. Comparison of rate constant for some molecular trances generated during artificial maturation of ke-rogens: influence of keroenn type[J]. Org Geochem, 1997, 26: 281-287.
[2]	黄第藩,等. 陆相有机质演化和成烃机理[M]. 北京: 石油工业出版社,1984. 151-187.
[3]	王会祥,黄第藩,李晋超. 陆相干酪跟降解动力学研究——有机地球化学与陆相生油[M]. 北京: 石油工业出版社,1986. 245-256.
[4]	杨国华,吴肇亮,刘庆豪,等. 不同类型干酪跟热解生烃动力学研究[J]. 石油大学学报,1990, 14(1): 72-78.
[5]	杨天宇,王涵云. 褐煤干酪根煤化作用成气的模拟实验及其地质意义[J]. 石油勘探与开发,1983, 6: 29-36.
[6]	张大江,黄第藩,李晋超. 油页岩干酪根热解的动力学性质及其地球化学意义[J]. 石油与天然气地质,1983, 14(4): 383-394.
[7]	林玉祥. 论低熟油烃产率模型[J]. 石油实验地质,2001, 23(1):87.
[8]	Braum R. Oil and gas evolution kinetics for oil shale and petroleum source rock determined from pyrolysis-TQMS data at two heating rates[J]. Energy and Fuel, 1992, (6): 468-474.
[9]	Pepper A S, Corvit P J. Simple kinetic models of petroleum formation[J]. Marine and Petroleum Geology, 1995, 12(30): 291-319.
[10]	Reynolds J C, Burnham A K. Comparison of kinetic analysis of source rocks and kerogen concentrates[J]. Org Geochem, 1995, 23 (1): 11-19.
[11]	Schenk H J, Horsfield B. Kinetics of petroleum generation by programmed-temperature closed-verus open system pyrolysis[J]. Geochimica et Cosmochimica Acta, 1993, 57: 623-630.
[12]	Tang Y, Stauffer M. Multiple cold trap pyrolysis gas chrmatography: a new technique for modeling hydrocarbon generation[J]. Org Geochem, 1993, 22 (3-5).
[13]	Tang Y, Perry J, Jenden P D, et al. Mathematical modeling of stable carbon isotope ratios in natural gases[J]. Geochimica et Cosmochimica Acta, 2000, 64 (15): 2673-2687.
[14]	Ungger P, Pelet R. Exptrapolation of the kinetics of oil and gas formation from laboratory experiments to sedimentary basins[J]. Nature, 1987, 327:52-54.
[15]	Ungerer P. State of the art of research in kinetics modeling of oil formation and expulsion[J]. Org Geochem, 1990, 16 (1-3): 1-25.
[16]	刘金钟,唐永春. 用干酪根生烃动力学方法预测甲烷生成量[J]. 科学通报,1998, 43(11): 1187-1991.
[17]	张林晔,张春荣. 低熟油生成机理及成油体系[M]. 北京: 地质出版社,1999. 1-130.
[18]	李理. 惠民-东营凹陷孔店组-沙四段构造对油气的控制作用[J]. 石油实验地质,1999, 21(增):10.
[19]	中国石油地质志编委会. 中国石油地质志(卷2)——胜利油田[M]. 北京: 石油工业出版社,1993. 78-99.
[20]	郭汝泰. 东营北带复合型含油气系统研究[D]. 中国科学院广州地球化学研究所, 2002.