应用含氮化合物探讨油气运移和注入方向

李贤庆; 侯读杰; 肖贤明; 阳开林; 唐友军; 包建平; 马安来; 熊波

doi:10.11781/sysydz200402200

应用含氮化合物探讨油气运移和注入方向

doi: 10.11781/sysydz200402200

1.
长江大学, 分析测试研究中心, 湖北, 荆州, 434023
2. 中国科学院, 广州地球化学研究所有机地球化学国家重点实验室, 广东, 广州, 510640
3. 中国地质大学, 能源地质系, 北京, 100083
4. 中国海洋石油公司, 天津分公司, 勘探开发部, 天津, 塘沽, 300452

基金项目: 国家自然科学基金(49672128、40072043);中国科学院知识创新工程重要方向性项目(KZCX2-110);中国博士后科学基金(2002031282).

详细信息

作者简介:
李贤庆(1967- ),男(汉族),浙江富阳人,教授,博士,主要从事油气地球化学、成藏动力学与有机岩石学方面的科研和教学工作.

中图分类号: TE122.1
计量
- 文章访问数: 513
- HTML全文浏览量: 24
- PDF下载量: 539
- 被引次数: 0
出版历程
- 收稿日期: 2003-05-06
- 修回日期: 2004-02-07
- 刊出日期: 2004-03-25

STUDY OF OIL MIGRATION AND INJECTION DIRECTIONS BY NITROGEN COMPOUNDS

1.
Center of Test and Research, Yangtze University, Jingzhou, Hubei 434023
2. State Key Laboratory of Organic Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, Guangdong 510640, China
3. Department of Energy Geology, China University of Geosciences, Beijing 100083, China
4. Department of Exploration & Development, Tianjin Petroleum Branch Company, CNOOC, Tanggu, Tianjin 300452, China

摘要

摘要: 利用原油中含氮化合物组成和绝对浓度的变化,结合烃类生物标志物指标研究,该文探讨了我国渤海海域曹妃甸及临近地区的油气运移特征和注入方向.结果表明,原油中含氮化合物的分布和组成特征较好地指示了该区的油气运移效应.随着运移作用的加强,含氮化合物绝对浓度下降,"屏蔽"型与"暴露"型或"半屏蔽"型化合物的比值增加.沙垒田凸起油气运移方向是自东向西,注入点在凸起东侧.沙东南构造带油气存在2个运移和注入方向,即北东方向和西南方向.石臼坨凸起及倾没端油气是从西北方向运移和注入的.这与烃类生物标志物成熟度参数变化所揭示的油气运移和注入方向相一致,也与该区油气分布和勘探实践相吻合.
- 含氮化合物 /
- 油气运移 /
- 油藏 /
- 分馏效应 /
- 渤海海域 /
- 分子地球化学
Abstract: Based on the composition and concentration changes of nitrogen compounds in the study oil samples as well as the maturity indexes of saturated and aromatic biomarkers,this paper investigated the oil migration and injection direction of Caofeidian and nearby areas in the offshore part of the Bohai Bay Basin.The results showed that the distribution and composition characteristics can indicate oil fractionation effects.With the increasing of oil migration effects,the concentration of nitrogen compounds decreased whereas the ratios of shielded nitrogen compounds to exposed or semi-shielded ones increased.The oil migration and injection direction of the Shaleitian Uplift was from east to west,with the main charging point in the east.Two oil migration and injection directions (i.e.,eastnorth and southwest) were found in the Shadongnan tectonic zone.Oil in the Shijiutuo Uplift and the inclined end migrated from northwest.This is consistent with oil migration directions deduced from the gradient changes of hydrocarbon biomarkers.All these conclusions are also accorded with the regional oil occurrences and exploration facts.
- nitrogen compound oil migration oil pool fractionation effect offshore part of the Bohai Bay Basin molecular geochemistry /

HTML全文

参考文献(10)

[1]	Li M,Larter S R,Stoddart D,et al.Fractionation of pyrrolic nitrogen compounds in petroleum during migration-derived of migration related geochemical parameters [A].Cubitt J M,England W A.The Geochemistry of Reservoirs [C].Geological Society Special Publication,1995,86:103-123.
[2]	Yamamoto M.Fractionation of azarenes during oil migration [J].Organic Geochemistry,1992,19:389-402.
[3]	Larter S R,Bowler B,Li M,et al.Benzocarbazoles as molecular indicators of secondary oil migration distance[J].Nature,1996,383:593-597.
[4]	朱扬明,傅家谟,盛国英,等.塔里木盆地不同成因原油吡咯类氮化合物的地球化学意义[J].科学通报,1997,42(23):2 528-2 531.
[5]	黎茂稳.油气二次运移研究的基本思路和几个应用实例[J].石油勘探与开发,2000,27(4):11-19.
[6]	王传刚.应用吡略类氮化合物探讨彩南油田油气运移——以彩南油田东块侏罗系西山窑组油藏为例[J].石油实验地质,2003,25(6):740-745.
[7]	石油地质志编写组.沿海大陆架及毗临海域油气区[M].北京:石油工业出版社,1990,1-65.
[8]	黄正吉,李友川.渤海湾盆地渤中坳陷东营组烃源岩的烃源前景[J].中国海上油气(地质),2002,16(2):118-124.
[9]	包建平,马安来.原油中烷基苯酚和中性含氮化合物的快速分离与分析[A].见:王培荣.非烃地球化学和应用[M].北京:石油工业出版社,2001,109-114.
[10]	Larter S R,Aplin A C.Reservoir geochemistry:methods,applications and opportunities[A].Cubitt J M,England W A.The Geochemistry of Reservoirs[M].London:The Geological Society Press,1995,5-32.