留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

天然气中伴生氢气的资源意义及其分布

孟庆强 金之钧 刘文汇 胡文瑄 张刘平 朱东亚

孟庆强, 金之钧, 刘文汇, 胡文瑄, 张刘平, 朱东亚. 天然气中伴生氢气的资源意义及其分布[J]. 石油实验地质, 2014, 36(6): 712-717. doi: 10.11781/sysydz201406712
引用本文: 孟庆强, 金之钧, 刘文汇, 胡文瑄, 张刘平, 朱东亚. 天然气中伴生氢气的资源意义及其分布[J]. 石油实验地质, 2014, 36(6): 712-717. doi: 10.11781/sysydz201406712
Meng Qingqiang, Jin Zhijun, Liu Wenhui, Hu Wenxuan, Zhang Liuping, Zhu Dongya. Distribution and genesis of hydrogen gas in natural gas[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2014, 36(6): 712-717. doi: 10.11781/sysydz201406712
Citation: Meng Qingqiang, Jin Zhijun, Liu Wenhui, Hu Wenxuan, Zhang Liuping, Zhu Dongya. Distribution and genesis of hydrogen gas in natural gas[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2014, 36(6): 712-717. doi: 10.11781/sysydz201406712

天然气中伴生氢气的资源意义及其分布

doi: 10.11781/sysydz201406712
基金项目: 国家自然科学基金项目(41102075,41230312)和山东省沉积成矿作用与沉积矿产重点实验室开放基金(DMSM201004)联合资助。
详细信息
    作者简介:

    孟庆强(1978-),男,博士,高级工程师,从事油气成藏机理研究。E-mail:mengqq.syky@sinopec.com。

  • 中图分类号: TE132.3

Distribution and genesis of hydrogen gas in natural gas

  • 摘要: 在系统调研氢气的分布及成因研究现状的基础上,对济阳坳陷部分油气井中天然气中的氢气含量进行了研究,并对其成因进行了初步划分。济阳坳陷天然气中氢气的含量普遍较低,在有R/Ra测试值的井中,氢气的H2/3He值普遍低于20×106,具有明显的幔源特征。因此,在这些井中,幔源氢气伴随深部流体活动混入了天然气中。

     

  • [1] Jin Zhijun,Zhang Liuping,Yang Lei,et al.A preliminary study of mantle-derived fluids and their effects on oil/gas generation in sedimentary basins[J].Journal of Petroleum Science and Engineering,2004,41(1/3):45-55.
    [2] 金之钧,杨雷,曾溅辉,等.东营凹陷深部流体活动及其生烃效应初探[J].石油勘探与开发,2002,29(2):42-44. Jin Zhijun,Yang Lei,Zeng Jianhui,et al.A primary study of deep-derived fluid activity and their effect on hydrocarbon generation[J].Petroleum Exploration and Development,2002,29(2):42-44.
    [3] 金之钧,张刘平,曾溅辉,等.东营凹陷与幔源富CO2流体有关的复合成因烷烃[J].科学通报,2002,47(16):1276-1280. Jin Zhijun,Zhang Liuping,Zeng Jianhui,et al.The compounded origin of methane related to CO2-riched mantle-derived fluid in Dongying Depression[J].Chinese Science Bulletin,2002,47(16):1276-1280.
    [4] 金之钧,张刘平,杨雷,等.沉积盆地深部流体的地球化学特征及油气成藏效应初探[J].地球科学,2002,27(6):659-665. Jin Zhijun,Zhang Liuping,Yang Lei,et al.The primary discussion on the relationship between geochemical characters and hydrocarbon accumulation for the deep-derived fluid in sedimentary basin[J].Earth Science,2002,27(6):659-665.
    [5] 孟庆强.幔源流体活动区氢气的同位素特征及其地质意义.北京:中国石油大学(北京),2008. Meng Qingqiang.Hydrogen isotopic character and its geological significance for mantle-derived fluid.Beijing:China Petroleum University,2008.
    [6] Rand D A J,Del R M.Hydrogen energy:challenges and prospects[M].Cambridge:Royal Society of Chemistry Publishing,2008:5-35.
    [7] Breakthrough Technologies Institute.Worldwide Hydrogen Fueling Stations..http://www.fuelcells.org/info/charts/h2fuelingstations.pdf.
    [8] International Energy Agency.World Energy Outlook-2009..http://www.worldenergyoutlook.org/media/weowebsite/2010/weo2010-london-nov9.pdf.
    [9] 韩崇仁.加氢裂化工艺与工程[M].北京:中国石化出版社,2001:224-226. Han Chongren.Hydrocracking technology and engineering[M].Beijing:Sinopec Press,2001:224-226.
    [10] Woolnough W G.Natural gas in Australia and New Guinea[J].AAPG Bulletin,1934,18(2):226-242.
    [11] Bohdanowic C.Natrual gas occurrence in Russia(U.S.S.R.)[J].AAPG Bulletin,1934,18(6):746-759.
    [12] Newcombe R B.Natural gas fields of Michigan//Ley H A.Geology of Natural Gas.AAPG,1935:787-812.
    [13] Depowski S.Wodowwgazachziemnych Nizu Polskiego w swietleogolnychwarunkowwystepowaniawolnegewodoru:Kwartalnik[J].Geologiczny,1966,10:194-202.
    [14] Meincke W.Zur Herkunft des Wasserstoffs in Tiefenproben[J].Zeitschrift fur Angewandte Geologie,1967,13(7):346-347.
    [15] Newell K D,Doveton J H,Merriam D F,et al.H2-rich and hydrocarbon gas recovered in a deep Precambrian well in northeastern Kansas[J].Natural Resources Research,2007,16(3):277-292.
    [16] Shuai Yanhua,Zhang Shuichang,Su Aiguo,et al.Geochemical evidence for strong ongoing methanogenesis in Sanhu region of Qaidam Basin[J].Science China Earth Sciences,2010,53(1):84-90.
    [17] 郭占谦.从全球油气田分布看我国东南沿海火山岩覆盖区的含油气前景[J].石油实验地质,2001,23(2):122-132. Guo Zhanqian.Hydrocarbon-bearing prospects of volcanic rock covered regions in the southeastern coastal waters of China judged by the distribution of global oil and gas fields[J].Petroleum Geology & Experiment,2001,23(2):122-132.
    [18] Hawkes H E.Geothermal hydrogen[J].Mining Engineering,1980,1(6):671-675.
    [19] Thayer T P.Serpentinization considered as a constant-volume metasomatic process[J].American Mineralogist,1966,51:685-710.
    [20] Abrajano T A,Sturchio N C,Bohlke J K,et al.Methane-hydrogen gas seeps,Zambalesophiolite,Philippines:Deep or shallow origin?[J].Chemical Geology,1988,71(1/3):211-222.
    [21] Neal C,Stanger G.Hydrogen generation from mantle source rocks in Oman[J].Earth and Planetary Science Letters,1983,66:315-320.
    [22] Jeffrey A W A,Kaplan I R.Hydrocarbons and inorganic gases in the Gravberg-1 wells,SiljanRing,Sweden[J].Chemical Geology,1988,71(1/3):237-255.
    [23] 戴金星.云南省腾冲县硫磺塘天然气的碳同位素组成特征及成因[J].科学通报,1988,33(15):1168-1170. Dai Jinxing.Characters and genesis for natural gas carbon isotopic composition in Liuhuangtang,Tengchong,Yunnan Province[J].Chinese Science Bulletin,1988,33(15):1168-1170.
    [24] Shang guan Zhi guan,Huo Weiguo.δD values of escaped H2 from hot springs at the Tengchong Rehai geothermal area and its origin[J].Chinese Science Bulletin,2002,47(2):148-150.
    [25] 高清武.长白山天池火山水热活动及气体释放特征[J].地球学报,2004,25(3):345-350. Gao Qingwu.Volcanic hydrothermal activities and gas-releasing characters of the Tianchi Lake region,Changbai Mountains[J].ActaGeoscienticaSinica,2004,25(3):345-350.
    [26] Zhang Mingjie,Hu Peiqing,Wang Xianbin,et al.The fluid compositions of lherzolite xenoliths in Eastern China and Western American[J].Geochimica et Cosmochimica Acta,2005,69:146.
    [27] 杨晓勇,刘德良,陶士振.中国东部典型地幔岩中包裹体成分研究及意义[J].石油学报,1999,20(1):19-23. Yang Xiaoyong,Liu Deliang,Tao Shizhen.Study on the composition and its significance of inclusion in typical mantle rock,East China[J].ActaPetrolei Sinica,1999,20(1):19-23.
    [28] 张铭杰,王先彬,李立武,等.幔源矿物中H2赋存状态的初步研究[J].地质学报,2002,76(1):39-44. Zhang Mingjie,Wang Xianbin,Li Liwu,et al.Mode of occurrence of H2 in mantle-derived minerals[J].Acta Geologica Sinica,2002,76(1):39-44.
    [29] 曹学伟,胡文瑄,金之钧,等.临盘油田夏38井区辉绿岩热效应对成烃作用的影响[J].石油与天然气地质,2005,26(3):317-322. Cao Xuewei,Hu Wenxuan,Jin Zhijun,et al.Influences of thermal effect of diabase intrusion on hydrocarbon generation in Xia 38 well block,Linpan Oilfield[J].Oil & Gas Geology,2005,26(3):317-322.
    [30] Goebel E D,Coveney R M Jr,Angino E E,et al.Naturally occurring hydrogen gas from a borehole on the western flank if Nemaha anticline in Kansas[J].AAPG Bulletin,1983,67-68(8):1324.
    [31] Coveney R M,Goebel E D,Zeller E J,et al.Serpentinization and the origin of Hydrogen Gas in Kansa[J].AAPG Bulletin,1987,71(1):39-48.
    [32] Marty B,Gunnlaugsson E,Jambon A,et al.Gas geochemistry of geothermal fluids,the Hengill area,southwest rift zone of Iceland[J].Chemical Geology,1991,91(3):207-225.
    [33] 吴振明,刘和甫,汤良杰,等.中国东部中、新生代主要裂谷盆地的演化及评论[J].石油实验地质,1985,7(1):60-69. Wu Zhenming,Liu Hepu,Tang Liangjie,et al.Revolution and review of the Mesozoic and Cenozoic rift basin in Eastern China[J].Petroleum Geology & Experiment,1985,7(1):60-69.
    [34] Kita I,Matsuo S,Wakita H,et al.D/H ratios of H2 in soil gases and an indicator of fault movements[J].Geochemical Journal,1980,14(6):317-320.
    [35] 杜乐天.地球的5个气圈与中地壳天然气开发[J].天然气地球科学,2006,17(1):25-35. Du Letian.The five gas cycles and natural gas development in middle crust of Earth[J].Natural Geochemistry,2006,17(1):25-35.
    [36] 陈丰.氢:地球深部流体的重要源泉[J].地学前缘,1996,3(3/4):72-79. Chen Feng.Hydrogen:the important origin of deep fluid in Earth[J].Earth Science Frontiers,1996,3(3/4):72-79.
    [37] Zhang Chi,Duan Zhenhao.A model for C-O-H fluid in the Earth's mantle[J].Geochimica et Cosmochimica Acta,2009,73(7):2089-2102.
    [38] Shah N,Panjala D,Huffman G P.Hydrogen production by catalytic decomposition of methane[J].Energy and Fuels,2001,15(6):1528-1534.
    [39] 马素萍,贺建桥,汤渭,等.高压釜对加水模拟实验中氢产物的影响[J].沉积学报,2003,21(4):713-716. Ma Suping,He Jianqiao,Tang Wei,et al.The effect of high-pressure reaction-kettle to hydrogen-bearing product during pyrolysis experiment[J].ActaSedimentologica Sinica,2003,21(4):713-716.
    [40] 秦建中.中国烃源岩[M].北京:科学出版社,2005:337-340. Qin Jianzhong.Chinese source rock[M].Beijing:Science Press,2005:337-340.
    [41] 徐永昌.天然气成因理论及应用[M].北京:科学出版社,1994:236-255. Xu Yongchang.Theory and application of natural gas genesis[M].Beijing:Science Press,1994:236-255.
    [42] 金之钧,胡文瑄,张刘平,等.深部流体活动及其油气成藏效应[M].北京:科学出版社,2007:133-142. Jin Zhijun,Hu Wenxuan,Zhang Liuping,et al.Deep-derived fluid and its effect on hydrocarbon accumulation[M].Beijing:Science Press,2007:133-142.
    [43] Lin L H,Hall J,Lippmann-Pipke J,et al.Radiolytic H2 in continental crust:Nuclear power for deep subsurface microbial communities[J].Geochemistry Geophysics Geosystems,2005,6(7):Q07003.doi: 10.1029/2004GC000907.
  • 加载中
计量
  • 文章访问数:  939
  • HTML全文浏览量:  47
  • PDF下载量:  606
  • 被引次数: 0
出版历程
  • 收稿日期:  2013-07-30
  • 修回日期:  2014-09-18
  • 刊出日期:  2014-11-28

目录

    /

    返回文章
    返回