原油中咔唑类参数运移示踪效应的驱替模拟实验

赵守钰; 徐耀辉; 严刚; 韩欣; 刘保磊; 钟鸣; 李姗姗

doi:10.11781/sysydz202402402

原油中咔唑类参数运移示踪效应的驱替模拟实验

doi: 10.11781/sysydz202402402

赵守钰^1,,
徐耀辉^1, ,,
严刚¹,
韩欣²,
刘保磊³,
钟鸣⁴,
李姗姗¹

1.
长江大学资源与环境学院油气地球化学与环境湖北省重点实验室, 武汉 430100
2.
中国石油长庆油田分公司长庆实业集团有限公司, 西安 710018
3.
长江大学油气钻采工程湖北省重点实验室, 武汉 430100
4.
中国地质大学(北京) 能源学院, 北京 100089

基金项目:

国家自然科学基金项目 41972122

详细信息

作者简介:
赵守钰(1998—)，男，硕士生，有机地球化学专业。E-mail: 2315326996@qq.com

通讯作者:
徐耀辉(1972—)，男，教授，博士生导师，从事有机地球化学和油气成藏研究。E-mail: yaohuixu@126.com

中图分类号: TE135
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- 文章访问数: 63
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- 被引次数: 0
出版历程
- 收稿日期: 2023-06-09
- 修回日期: 2024-02-01
- 刊出日期: 2024-03-28

Displacement simulation experiments of migration effect on carbazole parameters of crude oil

1.
Hubei Key Laboratory of Oil and Gas Geochemistry and Environment, College of Resources and Environment, Yangtze University, Wuhan, Hubei 430100, China
2.
Changqing Industrial Group Co., Ltd., PetroChina Changqing Oilfield Company, Xi'an, Shaanxi 710018, China
3.
Hubei Key Laboratory of Oil and Gas Drilling and Production Engineering, Yangtze University, Wuhan, Hubei 430100, China
4.
College of Energy and Resources, China University of Geosciences(Beijing), Beijing 100089, China

摘要

摘要: 油气运移研究对油气勘探与开发至关重要，受原油黏度、复杂化学组成及潜在的多种地质因素影响，原油运移方向与路径的确定难度较大。分子地球化学参数是研究油气运移规律的有效方法之一，实际成藏过程中的这些参数受其形成、相对组成以及演化程度等因素的影响。在实验室条件下可实现单一因素控制下的分子参数效应，采用室内驱替模拟实验的方法，在填砂管上进行油驱水实验，利用C₁₈固相萃取柱分离与富集不同运移距离吸附油中的咔唑类化合物，考察原油中咔唑类化合物的运移示踪规律。结果表明，咔唑类参数1-/4-MCA、1, 8-/1, 7-DMCA、1, 8-/2, 4-DMCA、1, 8-/2, 5-DMCA、1, 8-/2, 7-DMCA比值均随着运移距离的增加而显著增大，特别是全屏蔽型与全裸露型异构体比值1, 8-/2, 4-DMCA和1, 8-/2, 5-DMCA的增长幅度可达63.97%和35.50%，这些参数具备作为良好的运移示踪参数的潜质；而参数苯并[a]/[c]咔唑所表现出的运移示踪规律与前人部分实际油藏运移研究不符，可能是苯并咔唑类化合物的运移受其本身构型和其他地质条件的影响，建议该参数在应用到油气运移示踪研究时须谨慎使用。实验结果可为原油运移示踪参数研究提供有效的方法借鉴，但在实际地质应用时仍需结合分子动力学等手段对相关参数进行验证与优选。
- 咔唑类化合物 /
- 驱替模拟 /
- 地质色层分馏效应 /
- 原油运移
Abstract: The investigation of oil and gas migration plays a vital role in the field of oil and gas exploration and development. Determining the direction and path of crude oil migration is challenging due to factors such as crude oil viscosity, complex chemical composition, and geological influences. Molecular geochemical parameters are a valuable tool for studying petroleum migration, although they can be affected by factors like compound formation, distribution, and maturation. One approach involves simulating these parameters under controlled laboratory conditions to isolate their individual effects. This study establishes a sandy-packed system to simulate oil-driven experiments and uses a C₁₈ solid-phase extraction column to analyze carbazole compound fractions at different migration distances. The findings indicate that certain carbazole parameters, such as 1-/4-MCA, 1, 8-/1, 7-DMCA, 1, 8-/2, 4-DMCA, 1, 8-/2, 5-DMCA, and 1, 8-/2, 7-DMCA, increase significantly with transport distances. Notably, fully shielded and fully exposed isomers like 1, 8-/2, 4-DMCA and 1, 8-/2, 5-DMCA show enrichment levels of up to 63.97% and 35.50%, making them potential indicators of oil migration. However, parameters related to benzo [a]/[c] carbazole show inconsistencies with previous findings, likely due to intrinsic configurations and varying geological conditions that must be taken into account. The experimental results presented in this study offer insights for assessing specific reservoirs, with a recommendation to also consider molecular kinetics when selecting molecular parameters.
- carbazole compound /
- displacement simulation /
- geochromatographic effect /
- crude oil migration
注释:

1) 利益冲突声明/Conflict of Interests

1) 所有作者声明不存在利益冲突。

2) 赵守钰、徐耀辉、严刚参与论文框架设计及撰写工作；刘保磊、钟鸣参与实验设计；严刚完成实验操作；韩欣、李珊珊负责稿件校对。所有作者均阅读并同意最终稿件的提交。

2) 作者贡献/Authors’Contributions

HTML全文

图 1 原油驱替模拟装置示意

Figure 1. Schematic diagram of crude oil displacement simulator

下载: 全尺寸图片幻灯片

图 2 咔唑、苯并[a]咔唑和二苯并咔唑的分子结构

Figure 2. Molecular structure of carbazole, benzo [a] carbazole and dibenzocarbazole

下载: 全尺寸图片幻灯片

图 3 原油驱替装置入口端吸附油中咔唑类化合物的质量色谱

图中峰号表示的化合物名称见表 1。

Figure 3. Mass chromatograms of carbazole compounds in adsorbed oil at inlet end of crude oil displacement simulator

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图 4 不同运移距离咔唑类化合物质量色谱

Figure 4. Mass chromatograms of carbazole compounds with different migration distances

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图 5 咔唑类运移参数随着距离的变化特征

Figure 5. Characteristics of variation of carbazole migration parameters with distance

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表 1 吸附油中咔唑化合物鉴定结果

Table 1. Identification results of carbazole compounds in adsorbed oil

峰号	分子式	化合物名称	英文名称(简写)	类型
1	C₁₂H₉N	咔唑	Carbazole(CA)	全裸露
2	C₁₃H₁₁N	1-甲基咔唑	1-Methylcarbazole(4-MCA)	半屏蔽
3	C₁₃H₁₁N	3-甲基咔唑	2-Methylcarbazole(2-MCA)	全裸露
4	C₁₃H₁₁N	2-甲基咔唑	3-Methylcarbazole(3-MCA)	全裸露
5	C₁₃H₁₁N	4-甲基咔唑	4-Methylcarbazole(4-MCA)	全裸露
6	C₁₄H₁₃N	1, 8-二甲基咔唑	1, 8-Dimethylcarbazole(1, 8-DMCA)	全屏蔽
7	C₁₄H₁₃N	1-乙基咔唑	1-Eethylcarbazole(1-ECA)	半屏蔽
8	C₁₄H₁₃N	1, 3-二甲基咔唑	1, 3-Dimethylcarbazole(1, 3-DMCA)	半屏蔽
9	C₁₄H₁₃N	1, 6-二甲基咔唑	1, 6-Dimethylcarbazole(1, 6-DMCA)	半屏蔽
10	C₁₄H₁₃N	1, 7-二甲基咔唑	1, 7-Dimethylcarbazole(1, 7-DMCA)	半屏蔽
11	C₁₄H₁₃N	1, 4-二甲基咔唑	1, 4-Dimethylcarbazole(1, 4-DMCA)	半屏蔽
11’	C₁₄H₁₃N	4-乙基咔唑	4-Eethylcarbazole(4-ECA)	全裸露
12	C₁₄H₁₃N	1, 5-二甲基咔唑	1, 5-Dimethylcarbazole(1, 5-DMCA)	半屏蔽
12’	C₁₄H₁₃N	3-乙基咔唑	3-Eethylcarbazole(3-ECA)	全裸露
13	C₁₄H₁₃N	2, 6-二甲基咔唑	2, 6-Dimethylcarbazole(2, 6-DMCA	全裸露
14	C₁₄H₁₃N	2, 7-二甲基咔唑	2, 7-Dimethylcarbazole(2, 7-DMCA)	全裸露
15	C₁₄H₁₃N	1, 2-二甲基咔唑	1, 2-Dimethylcarbazole(1, 2-DMCA)	半屏蔽
16	C₁₄H₁₃N	2, 4-二甲基咔唑	2, 4-Dimethylcarbazole(2, 4-DMCA)	全裸露
17	C₁₄H₁₃N	2, 5-二甲基咔唑	2, 5-Dimethylcarbazole(2, 5-DMCA)	全裸露
18	C₁₄H₁₃N	2, 3-二甲基咔唑	2, 3-Dimethylcarbazole(2, 3-DMCA)	全裸露
19	C₁₄H₁₃N	3, 4-二甲基咔唑	3, 4-Dimethylcarbazole(3, 4-DMCA)	全裸露
20	C₁₆H₁₁N	苯并[a]咔唑	Benzo[a]carbazole(BC[a])	未定
21	C₁₆H₁₁N	苯并[b]咔唑	Benzo[b]carbazole(BC[b])	未定
22	C₁₆H₁₁N	苯并[c]咔唑	Benzo[c]carbazole(BC[c])	未定
注：全裸露型指1和8号碳位上氢原子均未被烷基取代；半屏蔽型指1和8号碳位上只有一个氢原子被烷基取代；全屏蔽型指1和8号碳位上氢原子均被烷基取代。

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表 2 不同运移距离石英砂吸附油咔唑类化合物运移参数

Table 2. Migration parameters of carbazole compounds of quartz sand adsorbed oil at different migration distances

参数	运移距离
参数	0 cm	30 cm	60 cm	90 cm	120 cm
1-/4-MCA	1.32	1.60	1.68	1.61	1.74
1, 8-/1, 7-DMCA	11.35	11.92	13.00	13.75	13.77
1, 8-/2, 4-DMCA	8.27	8.44	9.19	12.13	13.56
1, 8-/2, 5-DMCA	12.28	14.30	15.09	15.73	16.64
1, 8-/2, 7-DMCA	3.23	3.07	3.47	3.49	3.85
[a]/[c]	0.54	0.57	0.61	0.59	0.64

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