EXPERIMENTS ON PETROLEUM GENERATION-CONSIDERATIONS AND OUTLOOK

ZOU Yan-Rong; SHUAI Yan-hua; KONG Feng; PENG Ping-an

doi:10.11781/sysydz200404375

Volume 26 Issue 4

Turn off MathJax

Article Contents

Article Navigation > PETROLEUM GEOLOGY & EXPERIMENT > 2004 > 26(4): 375-382

ZOU Yan-Rong, SHUAI Yan-hua, KONG Feng, PENG Ping-an. EXPERIMENTS ON PETROLEUM GENERATION-CONSIDERATIONS AND OUTLOOK[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2004, 26(4): 375-382. doi: 10.11781/sysydz200404375

Citation:

ZOU Yan-Rong, SHUAI Yan-hua, KONG Feng, PENG Ping-an. EXPERIMENTS ON PETROLEUM GENERATION-CONSIDERATIONS AND OUTLOOK[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2004, 26(4): 375-382. doi: 10.11781/sysydz200404375

Citation:

PDF( 3333 KB)

EXPERIMENTS ON PETROLEUM GENERATION-CONSIDERATIONS AND OUTLOOK

doi: 10.11781/sysydz200404375

State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, Guangdong 510640, China

Received Date: 2003-10-11
Rev Recd Date: 2004-05-29
Publish Date: 2004-07-25

Abstract

Abstract

The study of petroleum generation,based on pyrolysis experiments and by means of reaction kinetics,is a systematical method combined closely with geologic conditions.Based on the summarization of present works on pyrolysis and kinetics,the outlook and prospects were discussed in this paper,and some conclusions and aspects worthy to further studies were proposed:1) up to date,hydrous pyrolysis was one of the best technique for simulating oil formation,and the confined system pyrolysis was still an excellent experiment technique of oil and gas generation/cracking and can be used to carry out hydrous pyrolysis experiments;2) the pyrolysis equipment with the episodic expulsion of hydrocarbon remained to be deve-loped;3) it was sure that pressure affected organic matter maturation,hydrocarbon generation and oil cracking,but the effects were possibly different;4) the kinetic study based on the pyrolysis experiments at single heating rate would not be accepted in the future;5) the kinetic models with the effects of pressure,including hydrocarbon generation and stable isotopic modelling,were expected in further studies;6) most geologic catalysts,except water-soluble,had few influences on oil and gas formation,but they possibly affected petroleum cracking in reservoirs;7) natural gas components and isotopic composition were closely related to accumulation history,to which much attention was expected to pay;8) the study of inorganic matter and its hydrous pyrolysis and the kinetics of non-hydrocarbon gas generation and isotopic evolution were of potential values for scientific research.
- petroleum,
- natural gas,
- stable isotope,
- pyrolysis,
- kinetics

FullText(HTML)

References(57)

References

[1]	Moni C J,Connan J,Oudin J L,et al.Quantitative and qualitative experimental approach of oil and gas generation:application to the North Sea source rock[J].Org Geochem,1990,16:133～142.
[2]	Behar F,Kressmann S,Rudkiewicz J L,et al.Experimental simulation in a confined system and kinetics modelling of kerogen and oil cracking[J].Org Geochem,1992,19(1～3):173～189.
[3]	刘金钟,向同寿.少量/微量烃类气体的收集、定量分析及碳同位素分析方法[J].石油实验地质,2003,25(5):492～497.
[4]	卢家烂.干酪根成烃模拟实验及其应用[A].见:傅家谟,秦匡宗编.干酪根地球化学[M].广州:广东科技出版社,1995.471～519.
[5]	卢双舫,王子文,黄第藩等.煤岩显微组分的成烃动力学[J].中国科学(B),1995,25(1):101～107.
[6]	刘德汉,张惠之,戴金星等.煤岩显微组分的成烃实验研究与评价[J].科学通报,2000,45(4):346～352.
[7]	Pepper A P,Corvi P J.Simple kinetic models of petroleum formation,Part Ⅰ:oil and gas generation from kerogen[J].Marine and Petroleum Geology,1995a,12(3):291～319.
[8]	Pepper A P,Dodd T D.Simple kinetic models of petroleum formation,Part Ⅱ:Oil-gas cracking[J].Marine and Petroleum Geology,1995b,12(3):321～340.
[9]	Pepper A P,Corvi P J.Simple kinetic models of petroleum formation,Part Ⅲ:modeling an open system[J].Marine and Petroleum Geology,1995c,12(4):417～452.
[10]	Price L C,McNeil R.Thoughts on the birth,evolution,and current state of petroleum geochemistry[J].Journal of Petro-leum Geology,1997,20:118～123.
[11]	Price L C.Metamorphic free-for-all[J].Nature,1994,370:253～254.
[12]	卢家烂,傅家谟.气源岩矿物组成和岩性特征对天然气运移的影响[A].见:傅家谟,刘德汉编.天然气运移、储集和封盖条件[M].北京:科学出版社,1992.16～28.
[13]	Monthioux M,Landais P,Durand B.Comparison between extracts from nature and artificial maturation series of Mahakam Delta coals[J].Organic Geochemistry,1986,10:299～311.
[14]	Landais P,Michels R,Elie M.Are time and temperature the only constraints to the simulation of organic maturation? [J].Organic Geochemistry,1994,22:617～630.
[15]	Price L C,Wenger L M.The influence of pressure on petroleum generation and maturation as suggested by aqueous pyrolysis[J].Org Geochem,1992,19(1～3):141～159.
[16]	Braun A L,Burham A K.Mathematical model of oil generation,degradation and expulsion[J].Energy & Fuel,1990,4:132～146.
[17]	Bustin R M,Ross J V,Moffat I.Vitrinite anisotropy under differential stress and high confining pressure and temperature:preliminary observations[J].International Journal of Coal Geology,1986,6:343～351.
[18]	Mastalerz M,Wilks K R,Bustin R M,et al.The effect of temperature,pressure and strain on carbonization in high-volatile bituminous and anthracitic coals[J].Org Geochem,1993,20:315～325.
[19]	Dalla Torre M,Mahlman R F,Ernst W G.Experimental study on the pressure dependence of vitrinite maturation[J].Geochimica et Cosmochimica Acta,1997,61:2 921～2 928.
[20]	Sajo C,McEvoy J,Wolff G A,et al.Influence of temperature and pressure on maturation processes —(Ⅰ) preliminary report[J].Organic Geochemistry,1986,10:331～337.
[21]	Jackson K J,Burham A K,Braun R I,et al.Temperature and pressure dependence of n-hexadecane cracking[J].Organic Geochemistry,1995,23:941～953.
[22]	Schenk H J,Di Primio R,Horsfield B.The conversion of oil into gas in petroleum reservoirs,Part Ⅰ:comparative kinetic investigation of gas generation from crude oils of lacustrine,marine and fluviodeltaic origin by programmed-temperature closed-system pyrolysis[J].Organic Geochemistry,1997,26:467～481.
[23]	Pettngill H S.20世纪90年代世界巨型油气田发现综述[J].世界石油工业,2001,8(6):38～41.
[24]	Car A D.A vitrinite reflectance kinetics model incorporation overpressure retardation[J].Marine & Petroleum Geology,1999,16:355～377.
[25]	Zou Y R,Peng P.Overpressure retardation of organic-matter maturation:a kinetics model and its application[J].Marine and Petroleum Goelogy,2001,18:707～714.
[26]	Rooney M A,Claypool G E,Chung H M.Modeling thermogenic gas generation using carbon isotope ratios of natural gas hydrocarbons[J].Chem Geol,1995,126:219～232.
[27]	Cramer B,Faber E,Gerling P,et al.Reaction kinetics of stable carbon isotopes in natural gas-insights from dry,open system pyrolysis experiments[J].Energy & Fuels,2001,15:517～532.
[28]	Tang Y,Perry J K.Jenden P D,et al.Mathematical modeling of stable carbon isotope ratios in nature gases[J].Geochim Cosmochim Acta,2000,64:2 673～2 687.
[29]	高先志,张万选,张厚福.矿物质对热解影响的研究[J].石油实验地质,1990,12(3):201～206.
[30]	Evans R J,Felbeck G.High temperature simulation of petroleum formation—(Ⅰ) the pyrolysis of Green River Shale[J].Org Geochem,1983,4:135～144.
[31]	Evans R J,Felbeck G.High temperature simulation of petroleum formation—(Ⅱ) Effect of inorganic sedimentary constituents on hydrocarbon formation[J].Org Geochem,1983,4:145～152.
[32]	Tamnenbuam E,Kaplan I R.Role of minerals in the thermal alteration of organic matter-(Ⅰ) generationg of gases and condensates under dry condition[J].Geochim Cosmochim Acta,1985,49:2 589～2 604.
[33]	Tamnenbuam E,Huizinga B T,Kaplan I R.Role of minerals in the thermal alteration of organic matter—(Ⅱ) a material balance[J].AAPG Bull,1986,70:1 156～1 165.
[34]	Huizinga B T,Tamnenbuam E,Kaplan I R.Role of minerals in the thermal alteration of organic matter—(Ⅲ) generation of bitumen in Laboratory experiments[J].Organic Geochemistry,1987,11:591～604.
[35]	李术元,林世静,郭少辉等.矿物质对干酪根生烃过程的影响[J].石油大学学报(自然科学版),2002,26:69～74.
[36]	Mango F D.The light hydrocarbons in petroleum:a critical review[J].Org Geochem,1997,26:417～440.
[37]	Borgund A E,Barth T.Effects of base catalysis on the product distribution from pyrolysis of woody biomass in the presence of water[J].Org Geochem,1999,30:1 517～1 526.
[38]	李术元,郭少辉,刘宗玉.盐水介质中煤的早期热解烃特征和动力学[J].石油大学学报(自然科学版),1999,23:71～74.
[39]	邹艳荣,刘金钟,彭平安.压力对高硫干酪根轻烃产率的影响[J].地球化学,2000,29:431～434.
[40]	Lewan M D.Sulphur-radical control on petroleum formation rates[J].Nature,1998,391:164～166.
[41]	Lewan M D.Experiments on the role of water in petroleum formation[J].Geochimica et Cosmochimica Acta,1997,61:3 691～3 723.
[42]	Schimmelmann A,Lewan M D,Wintsch R P.D/H isotope ratios of kerogen,bitumen,oil,and water in hydrous pyrolysis of source rocks containing kerogen types Ⅰ,Ⅱ,and Ⅲ[J].Geochimica et Cosmochimica Acta,1999,63:3 751～3 766.
[43]	Schimmelmann A,Boudou J-P,Lewan M D,et al.Experimental controls on D/H and ¹³C/¹²C ratios of kerogen,bitumen and oil during hydrous pyrolysis[J].Org Geochem,2001,32:1 009～1 018.
[44]	Driesner T.The effect of pressure on deuterium-hydrogen fractionation in high-temperature water[J].Science,1997,277:791～794.
[45]	Harita J,Driesner T,Cole D R.Pressure effect on hydrogen isotope fractionation between Brucite and water at elevated temperatures[J].Science,1999,286:1 545～1 547.
[46]	Goldstein T P.Geocatalytic reaction in formation and maturation of petroleum[J].AAPG Bull,1983,41:152～159.
[47]	Brown M E,Galwey A K.The significance of "compensation effects" appearing in data published in "computational aspects of kinetic analysis":ICTAC project,2000[J].Thermochimica Acta,2002,387:173～183.
[48]	Burnham A K.Computational aspects of kinetic analysis,Part D:the ICTAC kinetics project —multi-thermal-history model-fitting methods and their relation to isoconversional methods[J].Thermochimica Acta,2000,355:165～170.
[49]	Burnham A K,Braun R L.Global kinetics analysis of complex materials[J].Energy & Fuel,1999,13:1～22.
[50]	把立强,李广友.模拟气碳同位素在线分析技术[J].石油实验地质,2003,25(增刊):607～609.
[51]	Berner U,Faber E,Stahl W.Mathematical simulation of the carbon isotopic fractionation between huminitic coals and related methane[J].Chem Geol,1992,94:315～319.
[52]	Cramer B,Krooss B,Littke R.Modeling isotope fractionation during primary cracking of natural gas:a reaction kinetics approach[J].Chem Geol,1998,149:235～250.
[53]	Shoell M.The hydrogen and carbon isotopic composition of methane from natural gases of various origins[J].Geochim Cosmochin Acta,1980,44(5):649～661.
[54]	Galinov E M.Sources and mechanisms of formation of gaseous hydrocarbons in sedimentary rock[J].Chem Geol,1988,71:77～96.
[55]	刘文汇,徐永昌.煤型气碳同位素演化二阶段分馏模式及机理[J].地球化学,1999,28(4):359～365.
[56]	徐永昌,沈平,刘文汇等.天然气成因理论及应用[M].北京:科学出版社,1994.195～210.
[57]	Lorant F,Prinzhofer A,Behar F,et al.Carbon isotope and molecular constraints on the formation and the expulsion of thermogenic hydrocarbon gases[J].Chem Geol,1998,147:249～264

Relative Articles

Supplements(0)

Cited By

Proportional views

Proportional views

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Citation

XML

PDF-CN

Article Metrics

Article views (671) PDF downloads(650)

EXPERIMENTS ON PETROLEUM GENERATION-CONSIDERATIONS AND OUTLOOK

doi: 10.11781/sysydz200404375

Abstract

References

Proportional views

Catalog

通讯作者: 陈斌, bchen63@163.com

Article Metrics

Proportional views

Related

EXPERIMENTS ON PETROLEUM GENERATION-CONSIDERATIONS AND OUTLOOK

doi: 10.11781/sysydz200404375

Abstract

References

Proportional views

Catalog

通讯作者: 陈斌, bchen63@163.com

Article Metrics

Proportional views

Related

Export File

Citation

Format

Content