Chen Jinyang, Zhang Hong, Zheng Haifei, Zeng Yishan. IN SITU VISUALIZATION OF PYROLYSIS OF ORGANIC MATTER IN HIGH-TEMPERATURE AND HIGH-PRESSURE WATER—TAKING KEROGEN AND ASPHALT AS AN EXAMPLE[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2006, 28(1): 73-77. doi: 10.11781/sysydz200601073
Citation: Chen Jinyang, Zhang Hong, Zheng Haifei, Zeng Yishan. IN SITU VISUALIZATION OF PYROLYSIS OF ORGANIC MATTER IN HIGH-TEMPERATURE AND HIGH-PRESSURE WATER—TAKING KEROGEN AND ASPHALT AS AN EXAMPLE[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2006, 28(1): 73-77. doi: 10.11781/sysydz200601073

IN SITU VISUALIZATION OF PYROLYSIS OF ORGANIC MATTER IN HIGH-TEMPERATURE AND HIGH-PRESSURE WATER—TAKING KEROGEN AND ASPHALT AS AN EXAMPLE

doi: 10.11781/sysydz200601073
  • Received Date: 2005-03-13
  • Rev Recd Date: 2006-01-20
  • Publish Date: 2006-01-28
  • The in situ visualization of pyrolysis of kerogen and asphalt in high-temperature and high-pressure water studied by hydrothermal anvil cell.The phenomena of these two matter present great different.Kerogen pyrolyzes to liquid and gas phase hydrocarbon compounds in an inhomogeneous form at high temperature and high-pressure.These hydrocarbon compounds dissolve in water at high temperature and high-pressure and separate out during the decrease of temperature to the ambient temperature.Asphalt dissolves in water at high temperature and high pressure firstly,with increasing temperature further,it finally reactions with water to form graphite-soot matter.

     

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  • [1]
    Ahrens T J.Water storage in mantle[J].Nature,1989,342:122~123.
    [2]
    Bell D R,Rossman G R.Water in earth's mantle:the role of nominally anhydrous minerals[J].Science,1992,255:1 391~1 397.
    [3]
    Bai Q,Kohlstedt D L.Substantial hydrogen solubility in olivine and implications for water storage in the mantle[J].Nature,1992,357:672~674.
    [4]
    Langmuir C H.Water and the solid earth[J].Nature,1994,369:704~705.
    [5]
    Pawley A R,Holloway J R.Water sources for subduction zone volcanism:new experimental constraints[J].Science,1993,260:664~667.
    [6]
    Thompson A B.Water in the earth's upper mantle[J].Nature,1992,358:295~302.
    [7]
    邵济安,臧启家,韩庆军等.橄榄石流体包裹体中分子水的发现[J].岩石学报,2000,16(1):127~133.
    [8]
    翟庆龙.火山热液活动对烃源岩生排烃的作用—以东营凹陷西部沙三段为例[J].油气地质与采收率,2003,10(3):11~13.
    [9]
    Hartog N,Van Bergen P F,De Leeuw J W,et al.Reactivity of organic matter in aquifer sediments:geological and geochemical controls[J].Geochim et cosmochim Acta,2004,68 (6):1 281~1 292.
    [10]
    Lewan M D,Ruble T E.Comparison of petroleum generation kinetics by isothermal hydrous and nonisothermal open-system pyrolysis[J].Org Geochem,2002,33:1 457~1 475.
    [11]
    Mccoolom T M,Seewald J S,Simoneit B R T.Reactivity of monocyclic aromatic compounds under hydrothermal conditions[J].Geochim et Cosmochim Acta,2001,65(3):455~468.
    [12]
    Andresen B,Throndsen T,Raheim A,et al.A comparison of pyrolysis products with models for natural gas generation[J].Chem Geol,1995,126:261~280.
    [13]
    朱华银,周娟,万玉金等.多孔介质中气水渗流的微观机理研究[J].石油实验地质,2004,26(6):571~573.
    [14]
    Lewan M D.Experiments on the role of water in petroleum formation[J].Geochim et Cosmochim Acta,1997,61 (17):3 691~3 723.
    [15]
    Seewald J S,Benttez-Nelson B C,Whelan J K.Laboratory and theoretical constraints on the generation and composition of natural gas[J].Geochim et Cosmochim Acta,1998,62(9):1 599~1 617.
    [16]
    邹艳荣,帅燕华,孔枫等.油气生成过程实验研究的思考与展望[J].石油实验地质,2004,26(4):375~382.
    [17]
    Siskin M,Katritzky A R.Reactivity of organic compounds in hot water:geochemical and technological implications[J].Science,1991,254:231~237.
    [18]
    秦建中,刘井旺,刘宝泉等.加温时间、加水量对模拟实验油气产率及地化参数的影响[J].石油实验地质,2002,24(2):152~157.
    [19]
    高岗,王延斌,韩德馨等.煤的加水热模拟气特征对比[J].地质地球化学,2003,31(1):92~95.
    [20]
    史继扬,向明菊,屈定创.未熟-低熟烃源岩中脂肪酸的热模拟实验及演化[J].科学通报,2001,46(18):1 567~1 572.
    [21]
    Goto M,Obuchi R,Hirose T,et al.Hydrothermal conversion of municipal organic waste into resources[J].Bioresource Technology,2004,93:279~284.
    [22]
    Shanableh A.Production of useful organic matter from sludge using hydrothermal treatment[J].Water Research,2000,34(3):945~951.
    [23]
    Watanabe M,Hirakoso H,Sawamoto S,et al.Polyethylene conversion in supercritical water[J].Journal of Supercritical Fluids,1998,13:247~252.
    [24]
    龙中柱,高勇.超临界反应技术在废旧塑料回收再生利用方面的应用[J].化工进展,2001,(5):15~20.
    [25]
    孟令辉,白水平,冯立群等.超临界流体的应用研究—PET的分解、原料回收[J].材料科学与工艺,1999,7(2):96~99.
    [26]
    邱挺,马沛生,王军等.超临界水中废塑料的化学回收[J].高分子材料科学与工程,2001,17(6):10~14.
    [27]
    金辉,赵亚平,王大璞.纤维素超临界水解反应技术[J].现代化工,2001,21(12):56~59.
    [28]
    Yoshida T,Oshima Y,Matsumura Y.Gasification of biomass model compounds and real biomass in supercritical water[J].Biomass and Bioenergy,2004,26:71~78.
    [29]
    Xu X,Antal Jr M J.Gasification of sewage sludge and other biomass for hydrogen productioin in supercritical water[J].Environment Progress,1998,17(4):215~220.
    [30]
    Wei F,Hedzer J van der Kooi.Phase equilibria for biomass conversion processes in subcritical and supercritical water[J].Chem Engeering J,2004,98:105~113.
    [31]
    张义纲.油气地球化学的若干展望[J].石油实验地质,2005,27(5):484~489.
    [32]
    秦建中,钱志浩,曹寅等.油气地球化学新技术新方法[J].石油实验地质,2005,27(5):519~528.
    [33]
    Jinyang C,Haifei Z,Wansheng X,et al.high-temperaure and high-pressure cubic zirconia cell for raman spectroscopy[J].Applied Spectroscopy,2003,57(10):1 295~1 299.
    [34]
    汪洋,胡凯.应用激光喇曼光谱特征参数反映有机碳质的成熟度[J].矿物岩石,2002,22(3):57~60.
    [35]
    Shen A H,Basett W A,Chou I M.Hydrothermal studies in a DAC:pressure determination using the equation of state of H2O[A].In:High-pressure research:application to earth and planetary sciences[M].Tokyo:Terra Scientific Publishing Company,1992.61~68.
    [36]
    Escribano R,Sloan J J,Siddique N,et al.Raman spectroscopy of carbon-containing particles[J].Vibrational Spectroscopy,2001,26:179~186
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