Liu Quanyou, Liu Wenhui, Wang Xiaofeng, Wang Wanchun. COMPARISONS OF GEOCHEMICAL METHODS FOR ASSESSMENT OF HYDROCARBON-GENERATING POTENTIAL[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2007, 29(1): 88-94. doi: 10.11781/sysydz200701088
Citation: Liu Quanyou, Liu Wenhui, Wang Xiaofeng, Wang Wanchun. COMPARISONS OF GEOCHEMICAL METHODS FOR ASSESSMENT OF HYDROCARBON-GENERATING POTENTIAL[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2007, 29(1): 88-94. doi: 10.11781/sysydz200701088

COMPARISONS OF GEOCHEMICAL METHODS FOR ASSESSMENT OF HYDROCARBON-GENERATING POTENTIAL

doi: 10.11781/sysydz200701088
  • Received Date: 2006-03-19
  • Rev Recd Date: 2006-12-06
  • Publish Date: 2007-01-28
  • In this context,on the basis of comparison of three geochemical methods for assessment of source rocks,Rock-Eval pyrolysis,H/C ratio and hydrous pyrolysis,the hydrocarbon-generating potential of the low-mature coal in the Manjiaer sag,Tarim Basin,was determined.The compared results show that the potential of hydrocarbon-generating obtained by H/C ratio is similar with that by hydrous pyrolysis.The yields of hydrocarbon-generation based on the methods of H/C ratio and hydrous pyrolysis are 9.62 and 9.72 mg/g,respectively.In contrast,the yield of hydrocarbon formation is 32.75 mg/g by using method of Rock-Eval pyrolysis,higher than those obtained by the other two methods.It is provided the maximum yield of hydrocarbon generation for Rock-Eval pyrolysis,whereas the effective expelling of hydrocarbons will be obtained by H/C ratios and hydrous pyrolysis.Therefore,it would be necessary for hydrocarbon source assessment to use the geochemical method based on the special regions and aims.

     

  • loading
  • [1]
    Baskin D K.Atomic H/C ratio of kerogen as an estimate of thermal maturity and organic matter conversion[J].AAPG Bulletin,1997,81(9):1437~1450
    [2]
    Larter S R.Intergrated kerogen typing in the recognition and quantitative assessment of petroleum source rocks[A].In:Thomas B M,Dore A G,Eggen S S,eds.Petroleum geochemistry in exploration of the Norwegian shelf[M].London:Graham and Trotman.1985.269~286
    [3]
    Schmoker J W.Volumetric calculations of hydrocarbons generation[M].Colorado:Geology Survey,1986.323~326
    [4]
    Espitalie J,Madec J,Tissot B.Role of mineral matter in kerogen pyrolysis:influence on petroleum genration and migration[J].AAPG Bulletin,1980,64(1):59~66
    [5]
    Espitalie J,Laporte J,Madec M,et al.Rapid method for characterizing the petroleum potential and degree of evolution of source rock[J].Evue de I'institute Francais du petrole,1977,1:23~42
    [6]
    Jones R W.Organic facies[A].In:brooks J,Wehe D,eds.Problems of petroleum geochemistry[M].New York:Academic,1987.1~90
    [7]
    程克明,王兆云.高成熟和过成熟海相碳酸盐岩生烃条件评价研究[J].中国科学D辑,1996,26(6):537~543
    [8]
    曾凡刚,程克明.下古生界海相碳酸盐烃源岩地球化学的研究现状[J].地质地球化学,1998,26(3):1~8
    [9]
    Demaison G J,Holck A J J,Jones R W,et al.Predictive source bed stratigraphy:a guide to regional petroleum occurrence[A].In:World Petroleum Congress,ed.Proceedings of 11th World Petroleum Congress[C] ,London:World Petroleum Congress,1983.17~30
    [10]
    Wenger L M,Baker D R.Variations in organic geochemistry of anoxic-oxic black shale-carbonate sequences in the Pennsylvanian of the Midcontient,USA[J].Organic Geochemistry,1986,10:85~95
    [11]
    Peters K E,Moldowan J M.Interpreting molecular fossils in petroleum and ancient sediments[M].New Jersy:Prentice Hall Inc,1993.236
    [12]
    Dow W G.Application of oil correlation and source rock data to exploration in the williston basin[J].AAPG Bulletin,1977,58:1253~1262
    [13]
    Saxby J D,Bennett A J R,Coreoran J F,et al.Petroleum generation-simulation of six years of hydrocarbon formation from torbanite and brown coal in a subsiding basin[J].Organie Geochemistry,1986,9:69~81
    [14]
    Behar F,Vandenbroucke M.Chemical modeling of kerogen[J].Organic Geochemistry,1987,11:15~24
    [15]
    Daly A R,Edman J D.Loss of organic carbon from source rocks during thermal maturation[J].AAPG Bulletin,1987,71:546
    [16]
    Raiswell R.Berner R A.Organic carbon loss during burial and thermal maturity of normal marine shales[J].Geology,1987,15:853~856
    [17]
    Larter S R.Some pragmatic perspectives in source rock geochemistry[J].Marine and Petroleum Geology,1988,5:194~204
    [18]
    Hunt J M.Petroleum geochemistry and geology[M].San Francisco:W H Freeman & Co Ltd,1995.1~743
    [19]
    Waples D.Organic geochemistry for exploration geologists[M].Minneapolis:Burgess Publication,1981.151
    [20]
    Tissot B T,Durand B,Espitalie J,et al.Influence of nature and diagenesis of orgainc matter in formation of petroleum[J].AAPG Bulletin,1974,58:499~506
    [21]
    Jones R W,Edison T A.Microscopic observations of kerogen related to geochemical parameters with emphasis on thermal maturation[A].In:Oltz D F,ed.Low temperature metamorphism of kerogen and clay minerals[C] ,Los Angeles:SEPM Pacific Section,1978.1~12
    [22]
    Jones R W,Demaison J G.Organic facies:a stratigraphic contept and exploration tool[A].In:ASEAN,ed.Proceedings of the second ASCOPE conference and exhibition[C] ,Manila:ASEAN,1981.51~68
    [23]
    Peters K E,Moldowan J M,McCaffrey M A,et al.Selective biodegradation of extended hopanes to 25-norhopanes in petroleum reservoirs,insights from molecular mechanics[J].Organic Geochemistry,1996,24(8-9):765~783
    [24]
    Orr W L.Comments on pyrolytic hydrocarbon yields in source rock evaluation[J].Organic Geochemistry,1981.3:775~787
    [25]
    Katz B J.Limitations of Rock-Eval pyrolysis for typing organic matter[J].Organic Geochemistry,1983,4:195~199
    [26]
    Crossey L J,Hagen E S,Surdam R C,et al.Correlation of organic parameters derived from elemental analysis and programmed pyrolysis of kerogen[A].In:Gautier D L,ed.Roles of organic matter in sediment diagenesis[C] ,Los Angeles:SEPM Special Publication,1986.35~46
    [27]
    Burwood R,Droad R J,Halpern H I,et al.Carbon isotope variations of kerogen pyrolyzates[J].Organic Geochemistry,1988,12:195~205
    [28]
    Horsfield B,Douglas A G.The influence of minerals on the pyrolysis of kerogens[J].Geochimica et Cosmochimica Acta,1980,44:1119~1131
    [29]
    Peters K E.Guidelines for evaluating petroleum source rocks using programmed pyrolysis[J].AAPG Bulletin,1986,70:31 8~329
    [30]
    Dung N G.Pyrolysis behavior of Australian oil shales in a fluidized bed reactor and in a material balance modified Fischer assay retort[J].Fuel,1989,68:1570~1579
    [31]
    Huizinga B J,Aizenshtat Z A A,Peters K E.Programmed pyrolysis-gas chromatography of artificially mature Green River keogen[J].Energy & Fuels,1988,2:74~81
    [32]
    Lewan M D.Evaluation of petroleum generation by hydrous pyrolysis experimentation[J].Philosophical Transactions of the Royal Society,1985,315:123~134
    [33]
    Peters K E,Moldowan J M,Sundaraman P.Effects of hydrous pyrolysis on biomarker thermal maturity parameters:Monterey Phosphatic and Silicenous Members[J].Organic Geochemistry,1990,15:249~265
    [34]
    Teerman S C,Hwang R J.Evaluation of the liquid hydrocarbon potential of coal by artifical maturation techniques[J].Organic Geochemistry,1991,17:749~764
    [35]
    刘全有,刘文汇,秦胜飞等.煤岩及其显微组分热模拟成气特征[J].石油实验地质,2002,24(2):49~53
    [36]
    刘全有,刘文汇,陈践发等.塔里木盆地煤系有机质热模拟实验中液态烃特征研究[J].天然气地球科学,2004,15(4):37~41
    [37]
    Peters K E.Cossa M R.Applied source rock geochemistry,AAPG Memoir 60[M].Tulsa:AAPG,1994.93~117
    [38]
    Lewan M D,Henty M E,Higley D K,et al.Material-balance assessment of the New Albany-Chesterian petroleum system of the Illinois basin[J].AAPG Bulletin,2002,86(5):745~777
    [39]
    Behar F,Vandenbroucke M,Tang Y,et al.Thermal cracking of kerogen in open and closed system:determination of kinetic parameters and stoichiometric coefficients for oil and gas generation[J].Organic Geochemistry,1997,26:321~339
    [40]
    Lewan M D.Experiments on the role of water in petroleum formation[J].Geochimica et Cosmochimica Acta,1997,61:3691~3723
    [41]
    Lewan M D,Comer J B,Hamilton-Smith T,et al.Feasibility study of material-balance assessment of petroleum from the New Albany Shale in the Illinsois basin[A].In:USGS,ed.U S Geological Survey Bulletin 2173[M].Denver:US Geological Survey,1995
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (927) PDF downloads(347) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return