Advanced Search
Volume 36 Issue 1
. 
Turn off MathJax
Article Contents
Article Navigation >  PETROLEUM GEOLOGY & EXPERIMENT  > 2014  >  36(1): 89-94
Liu Peng, Li Maowen, Sun Yongge, Jiang Qigui, Tao Guoliang, Cao Tingting. Molecular characterization of polar species in Canadian oil sand bitumens by electrospray ionization and high resolution mass spectrometry[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2014, 36(1): 89-94. doi: 10.11781/sysydz201401089
Citation: Liu Peng, Li Maowen, Sun Yongge, Jiang Qigui, Tao Guoliang, Cao Tingting. Molecular characterization of polar species in Canadian oil sand bitumens by electrospray ionization and high resolution mass spectrometry[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2014, 36(1): 89-94. doi: 10.11781/sysydz201401089
shu

Molecular characterization of polar species in Canadian oil sand bitumens by electrospray ionization and high resolution mass spectrometry

doi: 10.11781/sysydz201401089
  • 1.

    Department of Earth Science, Zhejiang University, Hangzhou, Zhejiang 310027, China

  • 2. SINOPEC Key Laboratory of Petroleum Accumulation Mechanisms, Wuxi, Jiangsu 214126, China

  • 3. Wuxi Research Institute of Petroleum Geology, SINOPEC, Wuxi, Jiangsu 214126, China

  • Received Date: 2013-02-22
  • Rev Recd Date: 2013-12-02
  • Publish Date: 2014-01-28
    Abstract
  • At present, biodegradation effect on saturated hydrocarbon biomarkers, aromatic biomarker parameters and low molecular weight nitrogen compounds and their parameters is mostly studied, with less attention paid to the research of high molecular weight polar compounds. Four genetically related Canadian oil sand bitumens with various biodegradation levels have been analyzed by negative-ion electrospray ionization (ESI) and Fourier transform-ion cyclotron resonance mass spectrometry (FT-ICR MS). The results show that the neutral nitrogen and acidic heteroatom compounds in the oil sand bitumens include N1,N1O1,N1O2,N1S,O1,O1S1,O2,O2S1,O3 and O4 heteroatom classes, among which the O2 class species are most abundant. With increasing biodegradation, the relative abundances of N1,N1O1 and O1 class species decrease slightly, while the relative abundances of O2 and O2S1 class species increase slightly. The advantage of high resolution mass spectrometry for analyzing high molecular weight polar compounds in crude oil indicates great potential for developing new petroleum geochemistry techniques.

     

    • FullText(HTML)
  • loading
    • References(19)
  • [1]
    王振齐, 卢鸿, 于赤灵, 等.济阳坳陷郑家—王庄油田生物降解稠油成熟度及油源研究[J].江汉石油学院学报, 2004, 26(2):1-6. Wang Zhenqi, Lu Hong, Yu Chiling, et al.Maturity and oil source of biodegradation viscous crude in Zhengjia-Wangzhuang oilfield of Jiyang depression[J].Journal of Jianghan Petroleum Institute, 2004, 26(2):1-6.
    [2]
    Larter S, Wilhelms A, Head I, et al.The controls on the composition of biodegraded oils in the deep subsurface:part 1:biodegradation rates in petroleum reservoirs[J].Organic Geochemistry, 2003, 34(4):601-613.
    [3]
    李秀鹏, 于洁.准噶尔盆地乌夏断裂带稠油类型及成因机理[J].断块油气田, 2012, 19(2):182-186. Li Xiupeng, Yu Jie.Classification and genetic mechanism of heavy oil in Wuerhe-Xiazijie fault belt, Junggar Basin[J].Fault-Block Oil and Gas Field, 2012, 19(2):182-186.
    [4]
    马安来, 张水昌, 张大江, 等.生物降解原油地球化学研究新进展[J].地球科学进展, 2005, 20(4):449-454. Ma Anlai, Zhang Shuichang, Zhang Dajiang, et al.The advances in the geochemistry of the biodegraded oil[J].Advance in Earth Sciences, 2005, 20(4):449-454.
    [5]
    彼得斯 K E, 沃尔特斯 C C, 莫尔多万 J M.生物标志化合物指南[M].2版.张水昌, 李振西, 等译.北京:石油工业出版社, 2011:189. Peters K E, Walters C C, Moldowan J M.The Biomarker Guide[M].2nd ed.Zhang Shuichang, Li Zhengxi, et al, eds.Beijing:Petroleum Industry Press, 2011:189.
    [6]
    Jenisch-Anton A, Adam P, Michaelis W, et al.Molecular evidence for biodegradation of geomacromolecules[J].Geochimica et Cosmochimica Acta, 2000, 64(20):3525-3537.
    [7]
    倪春华, 包建平, 顾忆.生物降解作用对芳烃生物标志物参数的影响研究[J].石油实验地质, 2008, 30(4):386-389. Ni Chunhua, Bao Jianping, Gu Yi.Study of biodegradation effect on aromatic biomarker parameters[J].Petroleum Geology & Experiment, 2008, 30(4):386-389.
    [8]
    史权, 赵锁奇, 徐春明, 等.傅立叶变换离子回旋共振质谱仪在石油组成分析中的应用[J].质谱学报, 2008, 29(6): 367-378. Shi Quan, Zhao Suoqi, Xu Chunming, et al.Fourier transform ion cyclotron resonance mass spectrometry and its application in petroleum analysis[J].Journal of Chinese Mass Spectrometry Society, 2008, 29(6):367-378.
    [9]
    Hughey C A, Rodgers R P, Marshall A G, et al.Acidic and neutral polar NSO compounds in Smackover oils of different thermal maturity revealed by electrospray high field Fourier transform ion cyclotron resonance mass spectrometry[J].Organic Geochemistry, 2004, 35(7):863-880.
    [10]
    Kim S, Stanford L A, Rodgers R P, et al.Microbial alteration of the acidic and neutral polar NSO compounds revealed by Fourier transform ion cyclotron resonance mass spectrometry[J].Organic Geochemistry, 2005, 36(8):1117-1134.
    [11]
    Liao Yuhong, Quan Shi, Hsu C S, et al.Distribution of acids and nitrogen-containing compounds in biodegraded oils of the Liaohe Basin by negative ion ESI FT-ICR MS[J].Organic Geochemistry, 2012, 47:51-65.
    [12]
    Li Maowen, Cheng Dingsheng, Pan Xiaohua, et al.Characterization of petroleum acids using combined FT-IR, FT-ICR-MS and GC-MS: Implications for the origin of high acidity oils in the Muglad Basin, Sudan[J].Organic Geochemistry, 2010, 41(9):959-965.
    [13]
    窦立荣, 黎茂稳.高酸值油藏的形成与分布[M].北京:地质出版社, 2010. Dou Lirong, Li Maowen.Origin and distribution of high acidity oils[M].Beijing:Geological Publishing House, 2010.
    [14]
    Kendrick E A.Mass Scale Based on CH2=14.0000 for High Resolution Mass Spectrometry of Organic Compounds[J].Analytical Chemistry, 1963, 35(13):2146-2154.
    [15]
    Hughey C A, Hendrickson C L, Rodgers R P, et al.Kendrick Mass Defect Spectrum:A Compact Visual Analysis for Ultrahigh-Resolution Broadband Mass Spectra[J].Analytical Chemistry, 2001, 73(19):4676-4681.
    [16]
    Liu P, Xu C, Shi Q, et al.Characterization of Sulfide Compounds in Petroleum:Selective Oxidation Followed by Positive-Ion Electrospray Fourier Transform Ion Cyclotron Resonance Mass Spectrometry[J].Analytical Chemistry, 2010, 82(15):6601-6606.
    [17]
    Shi Quan, Pan Na, Long Haiyan, et al.Characterization of Middle-Temperature Gasification Coal Tar.Part 3:Molecular Composition of Acidic Compounds[J].Energy Fuels 2013, 27(1):108-117.
    [18]
    Peters K E, Walters C C, Moldowan J M.The biomarker guide, biomarkers and isotopes in petroleum exploration and earth history[M].2nd ed.Cambridge University press, New York, 2005.
    [19]
    Huang Haiping, Bowler B F, Zhang Zhanwen. et al.Influence of biodegradation on carbazole and benzocarbazole distributions in oil columns from the Liaohe basin, NE China[J].Organic Geochemistry, 2003, 34(7):951-969.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Citation
    XML
    PDF-CN

    Article Metrics

    Article views (798) PDF downloads(1014) Cited by()
    Proportional views
    Related

    Website Copyright © Wuxi Research Institute of Petroleum Geology, SINOPEC 苏ICP备15009037号 苏公网安备32021102000780号

    Address：No. 2060, Lihu Avenue, Wuxi, Jiangsu   (214126) Tel：0510-68787204，68787203 Fax：0510-68787113 Email：sysydz.syky@sinopec.com

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return