Advanced Search
Volume 37 Issue 6
. 
Turn off MathJax
Article Contents
Article Navigation >  PETROLEUM GEOLOGY & EXPERIMENT  > 2015  >  37(6): 796-801
Zhang Wanfeng, Tong Ting, Li Donghao, Dai Wei, Guo Pengfei, He Sheng, Zhu Shukui. A novel method for the determination of diamondoids in crude oils[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2015, 37(6): 796-801. doi: 10.11781/sysydz201506796
Citation: Zhang Wanfeng, Tong Ting, Li Donghao, Dai Wei, Guo Pengfei, He Sheng, Zhu Shukui. A novel method for the determination of diamondoids in crude oils[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2015, 37(6): 796-801. doi: 10.11781/sysydz201506796
shu

A novel method for the determination of diamondoids in crude oils

doi: 10.11781/sysydz201506796
  • 1.

    Key Laboratory of Tectonics and Petroleum Resources of Ministry of Education, China University of Geosciences, Wuhan, Hubei 430074, China

  • 2. State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences, Wuhan, Hubei 430074, China

  • 3. State Key Laboratory of Isotope Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Geosciences, Guangzhou, Guangdong 510640, China

  • 4. Key Laboratory of Nature Resource of the Changbai Mountain and Functional Molecular of Ministry of Education, Yanbian University, Yanji, Jilin 133002, China

  • Received Date: 2014-10-08
  • Rev Recd Date: 2015-09-12
  • Publish Date: 2015-11-28
    Abstract
  • A novel device, termed as gas purge microsyringe extraction (GP-MSE), has been developed and applied to the preparation of different kinds of oil samples, including condensates, light and normal oils for the first time.Oils from the Pearl River Mouth Basin were firstly extracted by GP-MSE and then qualitatively and quantitatively analyzed by comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometry (GC×GC-TOFMS).The proposed method has many advantages over traditional column chromatography, such as simple and fast steps, satisfactory recoveries, and lower consumption of solvents and samples.The relative standard deviations (RSD%) of adamantane and diamantane are 1.57% and 2.63%, respectively.Crude oil samples are purified and enriched effectively. The relative deviation is less than 9%, and the correlation coefficient is over 0.997.

     

    • FullText(HTML)
  • loading
    • References(24)
  • [1]
    Huang B J,Xiao X M,Cai D S,et al.Oil families and their source rocks in the Weixinan Sub-basin,Beibuwan Basin,South China Sea[J].Organic Geochemistry,2011,42(2):134-145.
    [2]
    Wang Z D,Yang C,Hollebone B,et al.Forensic fingerprinting of diamondoids for correlation and differentiation of spilled oil and petroleum products[J].Environmental Science & Technology,2006,40(18):5636-5646.
    [3]
    Zhang S C,Huang H P,Xiao Z Y,et al.Geochemistry of Palaeozoic marine petroleum from the Tarim Basin,NW China.Part 2:Maturity assessment[J].Organic Geochemistry,2005,36(8):1215-1225.
    [4]
    崔景伟,王铁冠,胡健,等.塔里木盆地和田河气田轻质油成熟度判定及其油源意义[J].石油与天然气地质,2013,34(1):27-36. Cui Jingwei,Wang Tieguan,Hu Jian,et al.Maturity of light oil and its significance inindicating oil source in Hetianhe gas field,Tarim Basin[J].Oil & Gas Geology,2013,34(1):27-36.
    [5]
    Li J G,PhilpP,Cui M Z.Methyl diamantane index (MDI) as a maturity parameter for Lower Palaeozoic carbonate rocks at high maturity and overmaturity[J].Organic Geochemistry,2000,31(4):267-272.
    [6]
    Schulz L K,Wilhelms A,Rein E,et al.Application of diamondoids to distinguish source rock facies[J].Organic Geochemistry,2001,32(3):365-375.
    [7]
    Wei Z B,Moldowan J M,Zhang S C,et al.Diamondoid hydrocarbons as a molecular proxy for thermal maturity and oil cracking:Geochemical models from hydrous pyrolysis[J].Organic Geochemistry,2007,38(2):227-249.
    [8]
    Dahl J E,Liu S G,Carlson R M K.Isolation and structure of higher diamondoids,nanometer-sized diamond molecules[J].Science,2003,299(5603):96-99.
    [9]
    Dahl J E,Moldowan J M,Peters K E,et al.Diamondoid hydrocarbons as indicators of natural oil cracking[J].Nature,1999,399(6731):54-57.
    [10]
    Fang C C,Xiong Y Q,Liang Q Y,et al.Variation in abundance and distribution of diamondoids during oil cracking[J].Organic Geochemistry,2012,47:1-8.
    [11]
    Li S F,Hu S Z,Cao J,et al.Diamondoid characterization in condensate by comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometry:the Junggar basin of Northwest China[J].International Journal of Molecular Sciences,2012,13(9):11399-11410.
    [12]
    Liang Q Y,Xiong Y Q,Fang C C,et al.Quantitative analysis of diamondoids in crude oils using gas chromatography-triple quadrupole mass spectrometry[J].Organic Geochemistry,2012,43:83-91.
    [13]
    Wang G L,Shi S B,Wang P R,et al.Analysis of diamondoids in crude oils using comprehensive two-dimensional gas chromatog-raphy/time-of-flight mass spectrometry[J].Fuel,2013,107:706-714.
    [14]
    马安来,金之钧,朱翠山,等.塔河油田原油中金刚烷化合物绝对定量分析[J].石油学报,2009,30(2):214-218. Ma Anlai,Jin Zhijun,Zhu Cuishan,et al.Quantitative analysis on absolute concentration of diamondoids in oils from Tahe Oilfield[J].Acta Petrolei Sinica,2009,30(2):214-218.
    [15]
    Grice K,Alexander R,Kagi R I.Diamondoid hydrocarbon ratios as indicators of biodegradation in Australian crude oils[J].Organic Geochemistry,2000,31(1):67-73.
    [16]
    Chen J H,Fu J M,Sheng G Y,et al.Diamondoid hydrocarbon ratios:Novel maturity indices for highly mature crude oils[J].Organic Geochemistry,1996,25(3/4):179-190.
    [17]
    Silva R C,Silva R S F,de Castro E V R,et al.Extended diamondoid assessment in crude oil using comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry[J].Fuel,2013,112:125-133.
    [18]
    Wei Z B,Moldowan J M,Jarvie D M,et al.The fate of diamondoids in coals and sedimentary rocks[J].Geology,2006,34(12):1013-1016.
    [19]
    Bastow T P,Van Aarssen B G K,Lang D.Rapid small-scale separation of saturate,aromatic and polar components in petroleum[J].Organic Geochemistry,2007,38(8):1235-1250.
    [20]
    Qiu J X,Wu C M,Fang Y Y,et al.Derivatization and liquid chromatography-UV-tandem mass spectrometric analysis of perfluorinated carboxylic acids[J].Journal of Chromatography A,2012,1235:132-140.
    [21]
    Yang C,Piao X F,Qiu J X,et al.Gas purge microsyringe extraction for quantitative direct gas chromatographic-mass spectrometric analysis of volatile and semivolatile chemicals[J].Journal of Chromatography A,2011,1218(12):1549-1555.
    [22]
    Zhu S K,Zhang W F,Dai W,et al.A simple model for separation prediction of comprehensive two-dimensional gas chromatography and its applications in petroleum analysis[J].Analy-tical Methods,2014,6(8):2608-2620.
    [23]
    梁前勇,熊永强,房忱琛,等.两种测定原油中金刚烷类化合物方法的对比研究[J].地球化学,2012,41(5):433-441. Liang Qianyong,Xiong Yongqiang,Fang Chenchen,et al.Comparison of two methods for the determination of diamondoids in crude oils[J].Geochimica,2012,41(5):433-441.
    [24]
    Wingert W S.GC-MS analysis of diamondoid hydrocarbons in Smackover petroleums[J].Fuel,1992,71(1):37-43.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Citation
    XML
    PDF-CN

    Article Metrics

    Article views (874) PDF downloads(695) Cited by()
    Proportional views
    Related

    Website Copyright © Wuxi Research Institute of Petroleum Geology, SINOPEC 苏ICP备15009037号 苏公网安备32021102000780号

    Address：No. 2060, Lihu Avenue, Wuxi, Jiangsu   (214126) Tel：0510-68787204，68787203 Fax：0510-68787113 Email：sysydz.syky@sinopec.com

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return