Advanced Search
Volume 45 Issue 5
Sep.  2023
Turn off MathJax
Article Contents
Article Navigation >  PETROLEUM GEOLOGY & EXPERIMENT  > 2023  >  45(5): 882-890
LIU Keyu, ZHANG Shulin, YANG Peng. Effect of low-temperature phase change on the re-equilibration of brine inclusions hosted in quartz minerals[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2023, 45(5): 882-890. doi: 10.11781/sysydz202305882
Citation: LIU Keyu, ZHANG Shulin, YANG Peng. Effect of low-temperature phase change on the re-equilibration of brine inclusions hosted in quartz minerals[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2023, 45(5): 882-890. doi: 10.11781/sysydz202305882
shu

Effect of low-temperature phase change on the re-equilibration of brine inclusions hosted in quartz minerals

doi: 10.11781/sysydz202305882
  • 1.

    School of Geosciences, China University of Petroleum (East China), Qingdao, Shandong 266580, China

  • 2.

    National Key Laboratory of Deep Oil and Gas, China University of Petroleum (East China), Qingdao, Shandong 266580, China

  • 3.

    The Laoshan Laboratory, Qingdao, Shandong 266071, China

  • Received Date: 2023-07-06
  • Rev Recd Date: 2023-09-12
  • Publish Date: 2023-09-28
    Abstract
  • Microthermometric measurement of fluid inclusions should follow the sequence of measuring homogenization temperature (Th) first, followed by the measurement of final freezing point temperature (Tm). However, in practice, this measurement sequence has not always been strictly followed. Many researchers may repeatedly measure the homogenization temperature of fluid inclusions even after the measurement of the final freezing point temperature. This may result in erroneous microthermometric data being obtained. In order to highlight this issue and to emphasize the importance of following the correct microthermometric measurement sequence, this study carried out repeated microthermometric measurements of brine inclusions and quantitatively compared the differences in the microthermomitric data obtained from different microthermomitric measurement sequences. The measurement exercise was aided by petrographic observation of brine inclusions and microscopic laser Raman analysis and fluid inclusion PVTx modelling. The results indicate that prior to the measurement of the final freezing point temperature, the homogenization temperature of brine inclusions can be repeatedly measured with the Th data showing no obvious deviation. During the measurement of the final freezing point temperature, the brine inclusion may undergo stretching or even leakage, and any subsequent Th measurements may yield elevated values, but Tm value remains largely unchanged. Therefore, low-temperature (freezing) phase-change measurement may cause resetting of the original PVTx information recorded. Compared to calcite minerals, brine inclusions hosted in quartz have stronger resistance to the influence of re-equilibration, and higher vapor filling degree and high salinity can offset the influence of brine inclusion re-equilibration to a certain extent. In the process of low-temperature phase change temperature measurement, due to the inflation caused by water freezing, it is common for brine inclusions to undergo stretching or even leakage, leading to a general increase in the homogenization temperature of brine inclusions.

     

    • All authors disclose no relevant conflict of interests.
    The study was designed by LIU Keyu and YANG Peng. The experimental analysis was completed by ZHANG Shulin. The manuscript was drafted and revised by all the authors. All the authors have read the last version of the paper and consented for submission.
    FullText(HTML)
  • loading
    • References(31)
  • [1]
    ROEDDER E. Fluid inclusions[M]//RIBBE P H. Reviews in mineralogy. Washington: Mineralogical Society of America, 1984.
    [2]
    GOLDSTEIN R H, REYNOLDS T J. Systematics of fluid inclusions in diagenetic minerals[M]. Tulsa: SEPM, 1994.
    [3]
    卢焕章, 范宏瑞, 倪培, 等. 流体包裹体[M]. 北京: 科学出版社, 2004.

    LU Huanzhang, FAN Hongrui, NI Pei, et al. Fluid inclusions[M]. Beijing: Science Press, 2004.
    [4]
    APLIN A C, MACLEOD G, LARTER S R, et al. Combined use of confocal laser scanning microscopyand PVT simulation for estimating the composition and physical properties of petroleum in fluid inclusions[J]. Marine and Petroleum Geology, 1999, 16(2): 97-110. doi: 10.1016/S0264-8172(98)00079-8
    [5]
    PIRONON J, CANALS M, DUBESSY J, et al. Volumetric reconstruction of individual oil inclusions by confocal scanning laser microscopy[J]. European Journal of Mineralogy, 1998, 10(6): 1143-1150. doi: 10.1127/ejm/10/6/1143
    [6]
    DUBESSY J, AUDEOUD D, WILKINS R, et al. The use of the Raman microprobe MOLE in the determination of the electrolytes dissolved in the aqueous phase of fluid inclusions[J]. Chemical Geology, 1982, 37(1/2): 137-150.
    [7]
    DUBESSY J, MOISSETTE A, BÄKKER R J, et al. High-temperature Raman spectroscopic study of H2O-CO2-CH4 mixtures in synthetic fluid inclusions: first insights on molecular interactions and analytical implications[J]. European Journal of Mineralogy, 1999, 11(1): 23-32. doi: 10.1127/ejm/11/1/0023
    [8]
    PIRONON J, BARRES O. Semi-quantitative FT-IR microanalysis limits: evidence from synthetic hydrocarbon fluid inclusions in sylvite[J]. Geochimica et Cosmochimica Acta, 1990, 54(3): 509-518. doi: 10.1016/0016-7037(90)90348-O
    [9]
    PIRONON J, THIÉRY R, AYT OUGOUGDAL M, et al. FT-IR measurements of petroleum fluid inclusions: methane, n-alkanes and carbon dioxide quantitative analysis[J]. Geofluids, 2001, 1(1): 2-10. doi: 10.1046/j.1468-8123.2001.11002.x
    [10]
    STASIUK L D, SNOWDON L R. Fluorescence micro-spectrometry of synthetic and natural hydrocarbon fluid inclusions: crude oil che-mistry, density and application to petroleum migration[J]. Applied Geochemistry, 1997, 12(3): 229-241. doi: 10.1016/S0883-2927(96)00047-9
    [11]
    RYDER A G. Quantitative analysis of crude oils by fluorescence lifetime and steady state measurements using 380 nm excitation[J]. Applied Spectroscopy, 2002, 56(1): 107-116. doi: 10.1366/0003702021954287
    [12]
    GUILLAUME D, TEINTURIER S, DUBESSY J, et al. Calibration of methane analysis by Raman spectroscopy in H2O-NaCl-CH4 fluid inclusions[J]. Chemical Geology, 2003, 194(1/3): 41-49.
    [13]
    APLIN A C, LARTER S R, BIGGE M A, et al. Confocal microscopy of fluid inclusions reveals fluid-pressure histories of sediments and an unexpected origin of gas condensate[J]. Geology, 2000, 28(11): 1047-1050. doi: 10.1130/0091-7613(2000)28<1047:CMOFIR>2.0.CO;2
    [14]
    APLIN A C, LARTER S R, BIGGE M A, et al. PVTX history of the North Sea's Judy oilfield[J]. Journal of Geochemical Exploration, 2000, 69-70: 641-644. doi: 10.1016/S0375-6742(00)00066-2
    [15]
    THIÉRY R, PIRONON J, WALGENWITZ F, et al. PIT (Petroleum Inclusion Thermodynamic): a new modeling tool for the characterization of hydrocarbon fluid inclusions from volumetric and microthermometric measurements[J]. Journal of Geoche-mical Exploration, 2000, 69-70: 701-704. doi: 10.1016/S0375-6742(00)00085-6
    [16]
    EADINGTON P J, LISK M, KRIEGER F W. Identifying oil well sites: US, 5543616[P]. 1996-08-06.
    [17]
    LISK M, O'BRIEN G W, EADINGTON P J. Quantitative evaluation of the oil-leg potential in the Oliver gas field, Timor Sea, Australia[J]. AAPG Bulletin, 2002, 86(9): 1531-1542.
    [18]
    LIU Keyu, EADINGTON P. Quantitative fluorescence techniques for detecting residual oils and reconstructing hydrocarbon charge history[J]. Organic Geochemistry, 2005, 36(7): 1023-1036. doi: 10.1016/j.orggeochem.2005.02.008
    [19]
    LIU Keyu, EADINGTON P, MIDDLETON H, et al. Applying quantitative fluorescence techniques to investigate petroleum charge history of sedimentary basins in Australia and Papuan New Guinea[J]. Journal of Petroleum Science and Engineering, 2007, 57(1/2): 139-151.
    [20]
    LIU Keyu, GEORGE S C, LU Xuesong, et al. Innovative fluorescence spectroscopic techniques for rapidly characterising oil inclusions[J]. Organic Geochemistry, 2014, 72: 34-45. doi: 10.1016/j.orggeochem.2014.04.010
    [21]
    GEORGE S C, KRIEGER F W, EADINGTON P J, et al. Geoche-mical comparison of oil-bearing fluid inclusions and produced oil from the Toro sandstone, Papua New Guinea[J]. Organic Geochemistry, 1997, 26(3/4): 155-173.
    [22]
    GEORGE S C, VOLK H, AHMED M. Oil-bearing fluid inclusions: geochemical analysis and geological applications[J]. Acta Petrologica Sinica, 2004, 20(6): 1319-1332. doi: 10.3321/j.issn:1000-0569.2004.06.002
    [23]
    GEORGE S C, VOLK H, AHMED M. Geochemical analysis techniques and geological applications of oil-bearing fluid inclusions, with some Australian case studies[J]. Journal of Petroleum Science and Engineering, 2007, 57(1/2): 119-138.
    [24]
    WATERMAN D, HORSFIELD B, HALL K, et al. Application of micro-scale sealed vessel thermal desorption-gas chromatography-mass spectrometry for the organic analysis of airborne particulate matter: linearity, reproducibility and quantification[J]. Journal of Chromatography A, 2001, 912(1): 143-150. doi: 10.1016/S0021-9673(01)00525-8
    [25]
    VOLK H, FUENTES D, FUERBACH A, et al. First on-line ana-lysis of petroleum from single inclusion using ultrafast laser ablation[J]. Organic Geochemistry, 2010, 41(2): 74-77. doi: 10.1016/j.orggeochem.2009.05.006
    [26]
    张鼐. 含油气盆地流体包裹体分析技术及应用[M]. 北京: 石油工业出版社, 2016.

    ZHANG Nai. Fluid inclusion analysis techniques and applications in oil and gas-bearing basins[M]. Beijing: Petroleum Industry Press, 2016.
    [27]
    THIÉRY R, PIRONON J, WALGENWITZ F, et al. Individual characterization of petroleum fluid inclusions (composition and P-T trapping conditions) by microthermometry and confocal laser scanning microscopy: inferences from applied thermodynamics of oils[J]. Marine and Petroleum Geology, 2002, 19(7): 847-859. doi: 10.1016/S0264-8172(02)00110-1
    [28]
    YANG Peng, LIU Keyu. Fluid inclusion re-equilibration in carbonate rock caused by freezing during microthermometric analysis[J]. Acta Geologica Sinica, 2020, 94(1): 580-582.
    [29]
    BODNAR R J. Revised equation and table for determining the freezing point depression of H2O-NaCl solutions[J]. Geochimica et Cosmochimica Acta, 1993, 57(3): 683-684. doi: 10.1016/0016-7037(93)90378-A
    [30]
    BAKKER R J. Package FLUIDS 1. Computer programs for analysis of fluid inclusion data and for modelling bulk fluid properties[J]. Chemical Geology, 2003, 194(1/3): 3-23.
    [31]
    BODNAR R J, VITYK M O. Interpretation of microterhrmometric data for H2O-NaCl fluid inclusions[C]//Fluid inclusions in minerals: methods and applications. Pontignano: Siena, 1994.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(8)  / Tables(1)

    Citation
    XML
    PDF-CN

    Article Metrics

    Article views (253) PDF downloads(41) Cited by()
    Proportional views
    Related

    Website Copyright © Wuxi Research Institute of Petroleum Geology, SINOPEC 苏ICP备15009037号 苏公网安备32021102000780号

    Address：No. 2060, Lihu Avenue, Wuxi, Jiangsu   (214126) Tel：0510-68787204，68787203 Fax：0510-68787113 Email：sysydz.syky@sinopec.com

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return