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鄂尔多斯盆地吴起-高桥地区延长组重排类藿烷分布特征及成因探讨

董君妍 陈世加 邹贤利 姚泾利 李勇 苏凯明

董君妍, 陈世加, 邹贤利, 姚泾利, 李勇, 苏凯明. 鄂尔多斯盆地吴起-高桥地区延长组重排类藿烷分布特征及成因探讨[J]. 石油实验地质, 2017, 39(6): 834-841. doi: 10.11781/sysydz201706834
引用本文: 董君妍, 陈世加, 邹贤利, 姚泾利, 李勇, 苏凯明. 鄂尔多斯盆地吴起-高桥地区延长组重排类藿烷分布特征及成因探讨[J]. 石油实验地质, 2017, 39(6): 834-841. doi: 10.11781/sysydz201706834
Dong Junyan, Chen Shijia, Zou Xianli, Yao Jingli, Li Yong, Su Kaiming. Distribution and origin of rearranged hopanes in Yanchang Formation, Wuqi-Gaoqiao area, Ordos Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2017, 39(6): 834-841. doi: 10.11781/sysydz201706834
Citation: Dong Junyan, Chen Shijia, Zou Xianli, Yao Jingli, Li Yong, Su Kaiming. Distribution and origin of rearranged hopanes in Yanchang Formation, Wuqi-Gaoqiao area, Ordos Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2017, 39(6): 834-841. doi: 10.11781/sysydz201706834

鄂尔多斯盆地吴起-高桥地区延长组重排类藿烷分布特征及成因探讨

doi: 10.11781/sysydz201706834
基金项目: 国家自然科学基金(41502146)、中国石油科技创新基金(2015D-5006-0101)、国家重大科技专项(2017ZX05001002-002)和西南石油大学青年科技创新团队资助计划(2015CXTD02)资助。
详细信息
    作者简介:

    董君妍(1992-),女,硕士,从事油气地球化学和油气勘探研究。E-mail:genki_coco@sina.cn。

    通讯作者:

    陈世加(1964-),男,教授,从事油气地球化学和油气成藏研究。E-mail:939543599@qq.com。

  • 中图分类号: TE122.1+1

Distribution and origin of rearranged hopanes in Yanchang Formation, Wuqi-Gaoqiao area, Ordos Basin

  • 摘要: 鄂尔多斯盆地吴起-高桥地区三叠系延长组长7-长9段烃源岩中检测出异常高丰度的重排类藿烷化合物。通过对不同层段烃源岩生物标志化合物特征的对比和探讨,对研究区烃源岩进行了分类并对其成因机制进行了分析。GC-MS分析结果表明:研究区源岩中含17α(H)-重排藿烷、早洗脱重排藿烷以及18α(H)-新藿烷(Ts和C29Ts)这3个系列重排藿烷类化合物。根据重排藿烷相对丰度存在的差异,可以将烃源岩划为以17α(H)-C30藿烷(C30H)为主峰,以17α(H)-C30重排藿烷(C30*)为主峰和以18α(H)-C27新藿烷(Ts)为主峰的3种类型。此外,早洗脱重排藿烷常与高丰度的17α(H)-重排藿烷以及18α(H)-新藿烷相伴出现,且这3类重排藿烷富集的烃源岩中同时富含重排甾烷和重排补身烷,说明重排类化合物的形成可能受控于相似的机制。各项地球化学参数的对比分析表明,高黏土含量、氧化性淡水沉积环境和以陆源植物为主的母质来源更利于烃源岩中高丰度重排类藿烷化合物的形成,较高的热成熟度促进藿烷重排反应的发生,但要考虑高成熟度下化合物裂解速率不同而造成的含量差异。

     

  • [1] Moldowan J M,Fago F J,Carlson R M K,et al.Rearranged hopanes in sediments and petroleum[J].Geochimica et Cosmochimica Acta,1991,55(11):3333-3353.
    [2] Telnaes N,Isaksen G H,Farrimond P.Unusual triterpane distributions in lacustrine oils[J].Organic Geochemistry,1992,18(6):785-789.
    [3] Nytoft H P,Lutnæs B F,Johansen J E.28-Nor-spergulanes,a novel series of rearranged hopanes[J].Organic Geochemistry,2006,37(7):772-786.
    [4] Farrimond P,Telnæs N.Three series of rearranged hopanes in Toarcian sediments (northern Italy)[J].Organic Geochemistry,1996,25(3/4):165-177.
    [5] 朱扬明,钟荣春,蔡勋育,等.川中侏罗系原油重排藿烷类化合物的组成及成因探讨[J].地球化学,2007,36(3):253-260. Zhu Yangming,Zhong Rongchun,Cai Xunyu, et al.Composition and origin approach of rearranged hopanes in Jurassic oils of central Sichuan Basin[J].Geochimica,2007,36(3):253-260.
    [6] Peters K E,Walters C C,Moldowan J M.The biomarker guide[M].London:Prentice-Hall,1993.
    [7] 王春江,傅家谟,盛国英,等.18α(H)-新藿烷及17α(H)-重排藿烷类化合物的地球化学属性与应用[J].科学通报,2000,45(13):1366-1372. Wang Chunjiang,Fu Jiamo,Sheng Guoying,et al.Geochemical characteristics and applications of 18α(H)-neohopanes and 17α(H)-diahopanes[J].Chinese Science Bulletin,2000,45(19):1742-1748.
    [8] 张文正,杨华,候林慧,等.鄂尔多斯盆地延长组不同烃源岩17α(H)-重排藿烷的分布及其地质意义[J].中国科学(D辑地球科学),2009,39(10):1438-1445. Zhang Wenzheng,Yang Hua,Hou Linhui,et al.Distribution and geological significance of 17α(H)-diahopanes from different hydrocarbon source rocks of Yanchang Formation in Ordos Basin[J].Science in China(Series D Earth Sciences),2009,52(7):965-974.
    [9] 程熊,陈小慧,张敏.鄂尔多斯盆地东北部上古生界煤系烃源岩17α(H)-重排藿烷类的分布及成因探讨[J].沉积学报,2014,32(4):790-796. Cheng Xiong,Chen Xiaohui,Zhang Min.Origin of 17α(H)-rearranged hopanes in upper Palaeozoic coal bearing source rocks in northeast Ordos Basin[J].Acta Sedimentologica Sinica,2014,32(4):790-796.
    [10] 肖中尧,黄光辉,卢玉红,等.库车坳陷却勒1井原油的重排藿烷系列及油源对比[J].石油勘探与开发,2004,31(2):35-37. Xiao Zhongyao,Huang Guanghui,Lu Yuhong,et al.Rearranged hopanes in oils from the Quele 1 well,Tarim Basin, and the significance for oil correlation[J].Petroleum Exploration and Development,2004,31(2):35-37.
    [11] Zhu Yangming,Hao Fang,Zou Huayao,et al.Jurassic oils in the central Sichuan Basin, southwest China:Unusual biomarker distribution and possible origin[J].Organic Geochemistry,2007,38(11):1884-1896.
    [12] 张水昌,张宝民,边立曾,等.8亿多年前由红藻堆积而成的下马岭组油页岩[J].中国科学(D辑地球科学),2007,37(5):636-643. Zhang Shuichang,Zhang Baomin, Bian Lizeng,et al.The Xiamaling oil shale generated through Rhodophyta over 800 Ma ago[J].Science in China(Series D Earth Sciences),2007,50(4):527-535.
    [13] 曹剑,边立曾,胡凯,等.柴达木盆地北缘侏罗系烃源岩中发现底栖宏观红藻类生烃母质[J].中国科学(D辑地球科学),2009,39(4):474-480. Cao Jian,Bian Lizeng,Hu Kai,et al.Benthic macro red alga:A new possible bio-precursor of Jurassic mudstone source rocks in the northern Qaidam Basin,northwestern China[J].Science in China(Series D Earth Sciences),2009,52(5):647-654.
    [14] Liu Haiyu,Zhang Min,Li Xing.Genesis study of high abundant 17α(H)-diahopanes in Lower Cretaceous lacustrine source rocks of the Lishu Fault Depression,Songliao Basin,Northeast China[J].Chinese Journal of Geochemistry,2014,33(2):201-206.
    [15] 柳广弟,杨伟伟,冯渊,等.鄂尔多斯盆地陇东地区延长组原油地球化学特征及成因类型划分[J].地学前缘,2013,20(2):108-115. Liu Guangdi,Yang Weiwei,Feng Yuan,et al.Geochemical characteristics and genetic types of crude oil from Yanchang Formation in Longdong area,Ordos Basin[J].Earth Science Frontiers,2013,20(2):108-115.
    [16] 张文正,杨华,李善鹏.鄂尔多斯盆地长91湖相优质烃源岩成藏意义[J].石油勘探与开发,2008,35(5):557-562. Zhang Wenzheng,Yang Hua,Li Shanpeng.Hydrocarbon accumulation significance of Chang91 high-quality lacustrine source rocks of Yanchang Formation,Ordos Basin[J].Petroleum Exploration and Development,2008,35(5):557-562.
    [17] 姚泾利,高岗,庞锦莲,等.鄂尔多斯盆地陇东地区延长组非主力有效烃源岩发育特征[J].地学前缘,2013,20(2):116-124. Yao Jingli,Gao Gang,Pang Jinlian,et al.Development characteristics of non-main effective source rocks of the Yanchang Formation in eastern Gansu Province of Ordos Basin[J]. Earth Science Frontiers,2013,20(2):116-124.
    [18] 杨华,张文正,蔺宏斌,等.鄂尔多斯盆地陕北地区长10油源及成藏条件分析[J].地球化学,2010,39(3):274-279. Yang Hua,Zhang Wenzheng,Lin Hongbin,et al.Origin of Chang 10 oil reservoir in northern Shaanxi region of Ordos Basin[J].Geochimica,2010,39(3):274-279.
    [19] 王香增,贺永红,张立宽,等.鄂尔多斯盆地吴起-志丹地区长10烃源岩特征与生烃潜力[J].天然气地球科学,2013,24(3):461-469. Wang Xiangzeng,He Yonghong,Zhang Likuan,et al.Geochemical characteristics and hydrocarbon generation potentials of Chang 10 source rock in Wuqi-Zhidan area,Ordos Basin[J].Natural Gas Geoscience,2013,24(3):461-469.
    [20] 曹红霞.鄂尔多斯盆地晚三叠世沉积中心迁移演化规律研究[D].西安:西北大学,2008. Cao Hongxia.Research on the rule of depocenter migration and evolution of Late Triassic in the Ordos Basin[D].Xi'an:Northwest University,2008.
    [21] 李红磊,张敏,姜连,等.利用芳烃参数研究煤系烃源岩中重排藿烷成因[J].沉积学报,2016,34(1):191-199. Li Honglei,Zhang Min,Jiang Lian,et al.Application of aroma-tics on genesis of rearranged hopanes in coal-bearing source rocks[J].Acta Sedimentologica Sinica,2016,34(1):191-199.
    [22] Kolaczkowska E,Slougui N E,Watt D S,et al.Thermodynamic stability of various alkylated,dealkylated and rearranged 17α-and 17β-hopane isomers using molecular mechanics calculations[J].Organic Geochemistry,1990,16(4/6):1033-1038.
    [23] 孙丽娜,张中宁,吴远东,等.生物标志化合物热成熟度参数演化规律及意义:以Ⅲ型烃源岩HTHP生排烃热模拟液态烃产物为例[J].石油与天然气地质,2015,36(4):573-580. Sun Lina,Zhang Zhongning,Wu Yuandong,et al.Evolution patterns and their significances of biomarker maturity parameters:A case study on liquid hydrocarbons from type Ⅲ source rock under HTHP hydrous pyrolysis[J].Oil & Gas Geology,2015,36(4):573-580.
    [24] de Leeuw J W,Cox H C,van Graas G,et al.Limited double bond isomerisation and selective hydrogenation of sterenes during early diagenesis[J].Geochimica et Cosmochimica Acta,1989,53(4):903-909.
    [25] Moldowan J M,Fago F J.Structure and significance of a novel rearranged monoaromatic steroid hydrocarbon in petroleum[J].Geochimica et Cosmochimica Acta,1986,50(3):343-351.
    [26] 朱扬明,张春明,张敏,等.沉积环境的氧化还原性对重排甾烷形成的作用[J].沉积学报,1997,15(4):103-108. Zhu Yangming,Zhang Chunming,Zhang Min,et al.The effect of oxidation-reduction nature of depositional environments on the formation of diasteranes[J].Acta Sedimentologica Sinica,1997,15(4):103-108.
    [27] 吉利明,梁晓飞,贺聪,等.鄂尔多斯盆地西峰地区延长组烃源岩两环烷烃分布特征及其生源[J].地球科学与环境学报,2015,37(1):76-84. Ji Liming,Liang Xiaofei,He Cong, et al.Distribution of bicyclic alkanes of source rocks of Yanchang Formation in Xifeng area of Ordos Basin and their biological sources[J].Journal of Earth Sciences and Environment,2015,37(1):76-84.
    [28] 邓南涛, 张枝焕, 王付斌, 等. 鄂尔多斯盆地南部镇泾地区中生界原油地球化学特征及油源分析[J].天然气地球科学,2013,24(3):604-611. Deng Nantao,Zhang Zhihuan,Wang Fubin, et al.Geochemical characteristics and oil-source correlation of crude oils in the Zhenjing area,southern Ordos Basin[J].Natural Gas Geoscience,2013,24(3):604-611.
    [29] Luo Binjie,Wang Youxiao,Meng Qianxiang,el al.Geochemistry of bicyclic alkanes in sediments, coal and crude oils[J].Science in China Series B-Chemistry,Life Sciences & Earth Sciences,1991,34(3):363-376.
    [30] Gordadze G N,Okunova T V,Giruts M V,el al.Petroleum C15 polyalkyl substituted bicyclo[4.4.0] decanes (sesquiterpanes) as oil maturity indicators (illustrated by the example of Jurassic and Cretaceous oils of Kalmykia)[J].Petroleum Chemistry,2011,51(2):117-122.
    [31] 陈中红,查明,金强.典型断陷湖盆C27三降藿烷参数演化及其控制因素:以东营凹陷古近系为例[J].沉积学报,2010,28(3):635-642. Chen Zhonghong,Zha Ming, Jin Qiang. The evolution and its control on maturation parameters relative to C27 trisnorhopane in the representative faulted lake-basin:A case study from Paleogene system in Dongying Sag[J].Acta Sedimentologica Sinica,2010,28(3):635-642.
    [32] Philp R P,Gilbert T D.Biomarker distributions in Australian oils predominantly derived from terrigenous source material[J].Organic Geochemistry,1986,10(1/3):73-84.
    [33] Rabbani A R,Kotarba M J,Baniasad A R,et al.Geochemical characteristics and genetic types of the crude oils from the Iranian sector of the Persian Gulf[J].Organic Geochemistry, 2014,70:29-43.
    [34] Duan Yi,Ma Lanhua.Lipid geochemistry in a sediment core from Ruoergai Marsh deposit (Eastern Qinghai-Tibet plateau,China)[J].Organic Geochemistry,2001,32(12):1429-1442.
    [35] 陈菊林,张敏.烃源岩热模拟实验中重排藿烷类化合物变化特征及其意义[J].石油实验地质,2016,38(5):672-678. Chen Julin,Zhang Min.Features and significance of rearranged hopanes in pyrolyzates of hydrocarbon source rocks[J].Petro-leum Geology & Experiment,2016,38(5):672-678.
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  • 收稿日期:  2017-05-22
  • 修回日期:  2017-09-25
  • 刊出日期:  2017-11-28

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