留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

川东北地区过成熟烃源岩催化加氢热解研究

岳长涛 李术元 凌瑞枫

岳长涛, 李术元, 凌瑞枫. 川东北地区过成熟烃源岩催化加氢热解研究[J]. 石油实验地质, 2011, 33(5): 540-545. doi: 10.11781/sysydz201105540
引用本文: 岳长涛, 李术元, 凌瑞枫. 川东北地区过成熟烃源岩催化加氢热解研究[J]. 石油实验地质, 2011, 33(5): 540-545. doi: 10.11781/sysydz201105540
Yue Changtao, Li Shuyuan, Ling Ruifeng. Catalytic hydropyrolysis of over-mature source rock in northeast Sichuan Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2011, 33(5): 540-545. doi: 10.11781/sysydz201105540
Citation: Yue Changtao, Li Shuyuan, Ling Ruifeng. Catalytic hydropyrolysis of over-mature source rock in northeast Sichuan Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2011, 33(5): 540-545. doi: 10.11781/sysydz201105540

川东北地区过成熟烃源岩催化加氢热解研究

doi: 10.11781/sysydz201105540
基金项目: 国家自然科学基金项目(40702019);油气资源与探测国家重点实验室开放课题(2009003)资助
详细信息
    作者简介:

    岳长涛(1977- ),男,博士,副教授,从事油气地球化学研究.E-mail:yuect@cup.edu.cn.

  • 中图分类号: TE122.1+13

Catalytic hydropyrolysis of over-mature source rock in northeast Sichuan Basin

  • 摘要: 针对川东北地区过成熟干酪根样品,采用固定床反应器进行催化加氢热解,利用GC-MS技术对产物进行检测并与源岩抽提产物进行对比,考察了饱和烃中甾烷、萜烷,芳烃中硫芴类和三芴类生物标志物的分布特征及地球化学信息,根据藿烷指数、姥鲛烷/植烷之比、伽马蜡烷指数、规则甾烷/17α(H)-藿烷、C27-C28-C29甾烷、重排甾烷/规则甾烷、硫芴系列化合物、三芴化合物等参数的结果,研究表明川东北烃源岩沉积的环境为缺氧的亚氧化、非超盐度、贫粘土的海相碳酸盐岩,沉积有机质来源于浮游生物。

     

  • [1] Love G D,Snape C E,Carr A D,et al.Release of covalentlybound alkane biomarkers in high yields from kerogen via catalytic hydropyrolysis[J]. Organic Geochemistry, 1995,23(10):981-986.
    [2] Bishop A N,Love G D,Mcaulay C E,et al.Release of kerogen-bound hopanoids by hydropyrolysis[J].Organic Geochemistry,1998,29(4):989-1001.
    [3] Murray I P,Love G D,Snape C E,et al.Comparison of covalently bound aliphatic biomarkers released via hydropyrolysis with their solvent-extractable counterparts for a suit of Krimmeridge clays[J].OrganicGeochemistry,1998,29(5-7):1487-1505.
    [4] Rocha J D,Brown S D,Love G D,et al.Hydropyrolysis:a versatile technique for solid fuel liquefaction,sulphur speciation and biomarker release[J].Journal of Analytical and Applied Pyrolysis,1997,40-41(1-2):91-103.
    [5] Love G D,Bowden S A,Jahnke L L,et al.A catalytic hydropyrolysis method for the rapid screening of microbial cultures for lipid biomarkers[J].Organic Geochemistry,2005,36(1):63-82.
    [6] Jochen J B,Love G D,Snape C E,et al.Release of bound aromatic hydrocarbons from late Archean and Mesoprotero zoic kerogens via hydropyrolysis[J].Geochimica et Cosmochimica Acta,2003,67(8):1521-1530.
    [7] Bowden S A,Farrimond P,Snape C E,et al.Compositional differences in biomarker constituents of the hydrocarbon,resin,asphaltene and kerogen fractions:An example from the Jet Rock (Yorkshire,UK)[J].Organic Geochemistry,2006,37(3):369-383.
    [8] Lockhart R S,Meredith W,Love G D,et al.Release of bound aliphatic biomarkers via hydropyrolysis from type Ⅱ kerogen at high maturity[J].Organic Geochemistry,2008,8(39):1119-1124.
    [9] 孙永革,Meredith W,Snape C E,等.加氧催化裂解技术用于高演化源岩有机质表征研究[J] ,石油与天然气地质,2008,29(2):276-282.
    [10] 周建伟,李术元,岳长涛,等.催化加氢热解反应催化剂前驱物四硫代钼酸铵的表征[J].化学试剂,2006,28(2):86-88.
    [11] 周建伟,李术元,岳长涛,等.HYPY/SE提取固体有机质中生物标志化合物的研究[J].化学通报,2006,15(5):337-341.
  • 加载中
计量
  • 文章访问数:  3024
  • HTML全文浏览量:  68
  • PDF下载量:  910
  • 被引次数: 0
出版历程
  • 收稿日期:  2010-12-31
  • 修回日期:  2011-08-31
  • 刊出日期:  2011-10-28

目录

    /

    返回文章
    返回