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高含量氢气赋存的地质背景及勘探前景

孟庆强 金之钧 孙冬胜 刘全有 朱东亚 刘佳宜 黄晓伟 王璐

孟庆强, 金之钧, 孙冬胜, 刘全有, 朱东亚, 刘佳宜, 黄晓伟, 王璐. 高含量氢气赋存的地质背景及勘探前景[J]. 石油实验地质, 2021, 43(2): 208-216. doi: 10.11781/sysydz202102208
引用本文: 孟庆强, 金之钧, 孙冬胜, 刘全有, 朱东亚, 刘佳宜, 黄晓伟, 王璐. 高含量氢气赋存的地质背景及勘探前景[J]. 石油实验地质, 2021, 43(2): 208-216. doi: 10.11781/sysydz202102208
MENG Qingqiang, JIN Zhijun, SUN Dongsheng, LIU Quanyou, ZHU Dongya, LIU Jiayi, HUANG Xiaowei, WANG Lu. Geological background and exploration prospects for the occurrence of high-content hydrogen[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2021, 43(2): 208-216. doi: 10.11781/sysydz202102208
Citation: MENG Qingqiang, JIN Zhijun, SUN Dongsheng, LIU Quanyou, ZHU Dongya, LIU Jiayi, HUANG Xiaowei, WANG Lu. Geological background and exploration prospects for the occurrence of high-content hydrogen[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2021, 43(2): 208-216. doi: 10.11781/sysydz202102208

高含量氢气赋存的地质背景及勘探前景

doi: 10.11781/sysydz202102208
基金项目: 

国家重点研发计划项目 2017YFC0603102

国家自然科学基金项目 41872164

国家自然科学基金项目 41102075

国家自然科学基金项目 41541019

详细信息
    作者简介:

    孟庆强(1978—), 男, 博士, 高级工程师, 从事油气地球化学与氢能研究。E-mail: mengqq.syky@sinopec.com

  • 中图分类号: TE02

Geological background and exploration prospects for the occurrence of high-content hydrogen

  • 摘要: 氢气作为一种可燃气体,是一种重要的清洁能源。随着过度依赖化石能源带来的环境问题日益加剧,从自然界中获得氢气的研究得到了越来越多的重视。但是,地质条件下能否形成高含量氢气,它们的成因及分布规律如何,目前研究较少。针对上述问题,通过对比不同地质条件下氢气的形成及富集规律,发现在裂谷系统以及板块俯冲带前缘均可能发育高含量氢气气藏。通过进一步总结氢气在不同大地构造位置的分布特征,认为控制我国含油气盆地分布的板块碰撞带和俯冲带及其周缘,具备高含量氢气发育的地质条件,而且,这些构造位置上发育的含油气盆地具备较好的天然气保存条件,有利于高含量氢气的保存。

     

  • 图  1  中国工业氢气需求量与产量变化

    修改自文献[5]。

    Figure  1.  China's industrial hydrogen demand and production trends

    图  2  人工制氢原料来源分布与对比

    数据来自文献[6]。

    Figure  2.  Distribution and comparison of sources of raw materials for artificial hydrogen production

    图  3  北美Kansas盆地富氢气井构造地质及剖面

    修改自文献[38]。

    Figure  3.  Geological map and profile of hydrogen-rich wells in Kansas Basin, North America

    图  4  北美Kansas盆地富氢气藏形成过程示意

    修改自文献[39]。

    Figure  4.  Accumulation process of hydrogen gas pools in Kansas Basin, North America

    图  5  板块俯冲带分布的气藏类型及其划分标准

    图中为摩尔分数,修改自文献[44]。

    Figure  5.  Types of gas reservoirs distributed in plate subduction zones and relative classification criteria

    图  6  板块俯冲带不同位置气藏成因机理示意

    修改自文献[44]。

    Figure  6.  Genetic mechanism of gas reservoirs at different locations in plate subduction zones

    图  7  板块俯冲带不同位置气藏类型分布示意

    修改自文献[44]。

    Figure  7.  Distribution mode of various types of gas reservoirs at different locations in a plate subduction zone

    表  1  北美Kansas盆地Scott和Heins富氢天然气井中气体组分分析

    Table  1.   Gas components of hydrogen-rich natural gas wells of Scott and Heins in Kansas Basin, North America

    井号 取样日期 数据来源 摩尔分数/%
    He H2 O2 N2 CO2 CH4 Ar ∑C1-5
    Scott 1982-08-12 文献[36] - 36.62 1.88 61.03 - - - 0.47
    Scott 1982-08-26 文献[36] - 23.27 10.61 66.08 - - - 0.04
    Scott 1982-08-26 文献[36] - 40.65 1.78 57.51 - - - 0.06
    Scott 1982-09-20 文献[36] 痕量 44.61 21.36 33.72 0.31 - 痕量 -
    Scott 1982-09-20 文献[36] - 57.20 - 41.88 0.92 - 痕量 -
    Scott 1983-08-27 文献[36] - 33.80 1.01 65.19 - - - -
    Scott 1983-08-27 文献[36] <0.10 39.40 0.50 60.10 - - - -
    Scott 1984-06-10 文献[36] - 1.42 0.01 97.45 - - 1.12 -
    Scott 1985-07-14 文献[36] - 4.50 1.00 92.88 0.50 - 1.10 0.01
    Scott 2008-07-08 文献[36] 0.08 17.32 - 71.36 0.02 5.39 - 5.91
    Heins 1983-09-07 文献[44] 0.82 22.08 7.85 69.25 - 0.82 - 0.82
    Heins 1983-09-07 文献[36] 0.75 33.86 3.60 61.81 - 0.74 - 0.74
    Heins 1984-06-12 文献[38] - 31.21 1.48 67.28 0.03 - - -
    Heins 1985-06-14 文献[38] 0.06 35.03 4.49 59.38 0.30 0.10 0.70 0.10
    Heins 2008-07-08 文献[44] 0.14 16.44 - 19.73 0.09 31.65 - 32.09
    Heins 2012-03-12 文献[39] - 25.06 0.46 59.95 0.01 7.24 7.28
    注:本表对原始文献中的数据进行了归一化处理。
    下载: 导出CSV
  • [1] 罗佐县, 曹勇. 氢能产业发展前景及其在中国的发展路径研究[J]. 中外能源, 2020, 25(2): 9-15. https://www.cnki.com.cn/Article/CJFDTOTAL-SYZW202002003.htm

    LUO Zuoxian, CAO Yong. Development prospect of hydrogen energy industry and its development path in China[J]. Sino-Global Energy, 2020, 25(2): 9-15. https://www.cnki.com.cn/Article/CJFDTOTAL-SYZW202002003.htm
    [2] Hydrogen Council. Hydrogen scaling up: a sustainable pathway for the global energy transition[EB/OL]. (2017-11-13). http://hydrogencouncil.com/wp-content/uploads/2017/11/Hydrogen-Scaling-up_Hydrogen-Council_2017.compressed.pdf.
    [3] 孟庆强, 金之钧, 刘文汇, 等. 天然气中伴生氢气的资源意义及其分布[J]. 石油实验地质, 2014, 36(6): 712-717. doi: 10.11781/sysydz201406712

    MENG Qingqiang, JIN Zhijun, LIU Wenhui, et al. Distribution and genesis of hydrogen gas in natural gas[J]. Petroleum Geology & Experiment, 2014, 36(6): 712-717. doi: 10.11781/sysydz201406712
    [4] MENG Qingqiang, SUN Yuhua, TONG Jianyu, et al. Distribution and geochemical characteristics of hydrogen in natural gas from the Jiyang Depression, Eastern China[J]. Acta Geologica Sinica (English Edition), 2015, 89(5): 1616-1624. doi: 10.1111/1755-6724.12568
    [5] 邹才能, 张福东, 郑德温, 等. 人工制氢及氢工业在我国"能源自主"中的战略地位[J]. 天然气工业, 2019, 39(1): 1-10. https://www.cnki.com.cn/Article/CJFDTOTAL-TRQG201901001.htm

    ZOU Caineng, ZHANG Fudong, ZHENG Dewen, et al. Strategic role of the synthetic hydrogen production and industry in Energy Independence of China[J]. Natural Gas Industry, 2019, 39(1): 1-10. https://www.cnki.com.cn/Article/CJFDTOTAL-TRQG201901001.htm
    [6] 符冠云. 氢能在我国能源转型中的地位和作用[J]. 中国煤炭, 2019, 45(10): 15-21. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGME201910004.htm

    FU Guanyun. The status and role of hydrogen energy in China's energy transformation[J]. China Coal, 2019, 45(10): 15-21. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGME201910004.htm
    [7] PETERSEN H C. Does natural hydrogen exist?[J]. International Journal of Hydrogen Energy, 1990, 15(1): 55. doi: 10.1016/0360-3199(90)90130-Q
    [8] WOOLNOUGH W G. Natural gas in Australia and new guinea[J]. AAPG Bulletin, 1934, 18(2): 226-242.
    [9] BOHDANOWIC C. Natural gas occurrences in Russia (U.S.S.R. )[J]. AAPG Bulletin, 1934, 18(6): 746-759.
    [10] MEINCKE W. Zur herkunft des wasserstoffs in tiefenproben[J]. Zeitschrift fur Angewandte Geologie, 1967, 13(7): 346-347.
    [11] NEWCOMBE R B. Natural gas fields of Michigan[C]//LEY H A. Geology of Natural Gas. Tulsa: AAPG, 1935: 787-812.
    [12] NEWELL K D, DOVETON J H, MERRIAM D F, et al. H2-rich and hydrocarbon gas recovered in a deep Precambrian well in northeastern Kansas[J]. Natural Resources Research, 2007, 16(3): 277-292. doi: 10.1007/s11053-007-9052-7
    [13] 郭占谦. 从全球油气田分布看我国东南沿海火山岩覆盖区的含油气前景[J]. 石油实验地质, 2001, 23(2): 122-132. doi: 10.11781/sysydz200102122

    GUO Zhanqian. Hydrocarbon-bearing prospects of volcanic rock covered regions in the southeastern coastal waters of China judged by the distribution of global oil and gas fields[J]. Petroleum Geology & Experiment, 2001, 23(2): 122-132. doi: 10.11781/sysydz200102122
    [14] HAWKES H E. Geothermal hydrogen[J]. Mining Engineering, 1980, 1(6): 671-675.
    [15] THAYER T P. Serpentinization considered as a constant-volume metasomatic process[J]. American Mineralogist, 1966, 51(5/6): 685-710.
    [16] ABRAJANO T A, STURCHIO N C, BOHLKE J K, et al. Methane-hydrogen gas seeps, Zambales ophiolite, Philippines: deep or shallow origin?[J]. Chemical Geology, 1988, 71(1/3): 211-222.
    [17] NEAL C, STANGER G. Hydrogen generation from mantle source rocks in Oman[J]. Earth and Planetary Science Letters, 1983, 66: 315-320.
    [18] SANO Y, URABE A, WAKITA H, et al. Origin of hydrogen-nitrogen gas seeps, Oman[J]. Applied Geochemistry, 1993, 8(1): 1-8.
    [19] LYON G L, HULSTON J R. Carbon and hydrogen isotopic compositions of New Zealand geothermal gases[J]. Geochimica et Cosmochimica Acta, 1984, 48(6): 1161-1171.
    [20] JEFFREY A W A, KAPLAN I R. Hydrocarbons and inorganic gases in the Gravberg-1 well, Siljan Ring, Sweden[J]. Chemical Geology, 1988, 71(1/3): 237-255.
    [21] 戴金星. 云南省腾冲县硫磺塘天然气的碳同位素组成特征和成因[J]. 科学通报, 1988, 33(15): 1168-1170. https://www.cnki.com.cn/Article/CJFDTOTAL-KXTB198815014.htm

    DAI Jinxing. Composition characteristics and origin of carbon isotope of Liuhuangtang natural gas in Tengchong county, Yunnan province[J]. Chinese Science Bulletin, 1989, 34(12): 1027-1030. https://www.cnki.com.cn/Article/CJFDTOTAL-KXTB198815014.htm
    [22] 戴金星, 戴春森, 宋岩, 等. 中国一些地区温泉中天然气的地球化学特征及碳、氦同位素组成[J]. 中国科学(B辑), 1994, 24(4): 426-433. https://www.cnki.com.cn/Article/CJFDTOTAL-JBXK199404013.htm

    DAI Jinxing, DAI Chunsen, SONG Yan, et al. Geochemical characters, carbon and helium isotopic compositions of natural gas from hot springs of some areas in China[J]. Science in China (Series B), 1994, 37(6): 758-768. https://www.cnki.com.cn/Article/CJFDTOTAL-JBXK199404013.htm
    [23] 王先彬, 徐胜, 陈践发, 等. 腾冲火山区温泉气体组分和氦同位素组成特征[J]. 科学通报, 1993, 38(9): 814-817. https://www.cnki.com.cn/Article/CJFDTOTAL-KXTB199309014.htm

    WANG Xianbin, XU Sheng, CHEN Jianfa, et al. Composition and helium isotopic characters of natural gas in Tengchong volcanic hot spring[J]. Chinese Science Bulletin, 1993, 38(9): 814-817. https://www.cnki.com.cn/Article/CJFDTOTAL-KXTB199309014.htm
    [24] 上官志冠, 白春华, 孙明良. 腾冲热海地区现代幔源岩浆气体释放特征[J]. 中国科学(D辑), 2000, 30(4): 407-414. https://www.cnki.com.cn/Article/CJFDTOTAL-JDXK200004009.htm

    SHANGGUAN Zhiguan, BAI Chunhua, SUN Mingliang. Mantle-derived magmatic gas releasing features at the Rehai area, Tengchong county, Yunnan province, China[J]. Science in China (Series D: Earth Sciences), 2000, 43(4): 132-140. https://www.cnki.com.cn/Article/CJFDTOTAL-JDXK200004009.htm
    [25] 上官志冠, 霍卫国. 腾冲热海地热区逸出H2δD值及其成因[J]. 科学通报, 2001, 46(15): 1316-1320. https://www.cnki.com.cn/Article/CJFDTOTAL-KXTB200115020.htm

    SHANGGUAN Zhiguan, HUO Weiguo. δD values of escaped H2 from hot springs at the Tengchong Rehai geothermal area and its origin[J]. Chinese Science Bulletin, 2002, 47(2): 148. https://www.cnki.com.cn/Article/CJFDTOTAL-KXTB200115020.htm
    [26] SHANGGUAN Zhiguan, HUO Weiguo. δD values of escaped H2 from hot springs at the Tengchong Rehai geothermal area and its origin[J]. Chinese Science Bulletin, 2002, 47(2): 146-149.
    [27] 高清武. 长白山天池火山水热活动及气体释放特征[J]. 地球学报, 2004, 25(3): 345-350. https://www.cnki.com.cn/Article/CJFDTOTAL-DQXB200403012.htm

    GAO Qingwu. Volcanic hydrothermal activities and gas-releasing characteristics of the Tianchi Lake region, Changbai mountains[J]. Acta Geoscientica Sinica, 2004, 25(3): 345-350. https://www.cnki.com.cn/Article/CJFDTOTAL-DQXB200403012.htm
    [28] 高清武, 李霓. 腾冲和五大连池火山区流体地球化学特征及成因探讨[J]. 地质论评, 1999, 45(4): 345-351. https://www.cnki.com.cn/Article/CJFDTOTAL-DZLP199904002.htm

    GAO Qingwu, LI Ni. A discussion on fluid geochemistry and origin of the Tengchong and Wudalianchi volcanic areas[J]. Geological Review, 1999, 45(4): 345-351. https://www.cnki.com.cn/Article/CJFDTOTAL-DZLP199904002.htm
    [29] 杨晓勇, 刘德良, 陶士振. 中国东部典型地幔岩中包裹体成分研究及意义[J]. 石油学报, 1999, 20(1): 19-23. https://www.cnki.com.cn/Article/CJFDTOTAL-SYXB901.003.htm

    YANG Xiaoyong, LIU Deliang, TAO Shizhen. Compositions and implications of inclusions in the typical mantle rocks from East China[J]. Acta Petrolei Sinica, 1999, 20(1): 19-23. https://www.cnki.com.cn/Article/CJFDTOTAL-SYXB901.003.htm
    [30] 张铭杰, 王先彬, 李立武, 等. 幔源矿物中H2赋存状态的初步研究[J]. 地质学报, 2002, 76(1): 39-44. https://www.cnki.com.cn/Article/CJFDTOTAL-DZXE200201005.htm

    ZHANG Mingjie, WANG Xianbin, LI Liwu, et al. Mode of occurrence of H2 in mantle-derived minerals[J]. Acta Geologica Sinica, 2002, 76(1): 39-44. https://www.cnki.com.cn/Article/CJFDTOTAL-DZXE200201005.htm
    [31] ZHANG Mingjie, HU P Q, WANG Xianbin, et al. The fluid compositions of lherzolite xenoliths in Eastern China and Western American[J]. Geochimica et Cosmochimica Acta, 2005, 69: 146.
    [32] 陶明信, 徐永昌, 史宝光, 等. 中国不同类型断裂带的地幔脱气与深部地质构造特征[J]. 中国科学(D辑地球科学), 2005, 35(5): 441-451. https://www.cnki.com.cn/Article/CJFDTOTAL-JDXK200505007.htm

    TAO Mingxin, XU Yongchang, SHI Baoguang, et al. Mantle degassing and deep structure characters of different kinds of fracture, China[J]. Science in China(Series D Earth Sciences), 2005, 35(5): 441-451. https://www.cnki.com.cn/Article/CJFDTOTAL-JDXK200505007.htm
    [33] 胡沛青. 中国东部上地幔不同类型流体组成及其性质[D]. 兰州: 兰州大学, 2006.

    HU Peiqing. The chemical and isotopic compositions and their origin of upper mantle volatiles in Eastern China[D]. Lanzhou: Lanzhou University, 2006.
    [34] 曹学伟, 胡文瑄, 金之钧, 等. 临盘油田夏38井区辉绿岩热效应对成烃作用的影响[J]. 石油与天然气地质, 2005, 26(3): 317-322. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT200503011.htm

    CAO Xuewei, HU Wenxuan, JIN Zhijun, et al. Influences of thermal effect of diabase intrusion on hydrocarbon generation in Xia 38 wellblock, Linpan oilfield[J]. Oil & Gas Geology, 2005, 26(3): 317-322. https://www.cnki.com.cn/Article/CJFDTOTAL-SYYT200503011.htm
    [35] GOEBEL E D, COVENEY JR R M, ANGINO E E, et al. Naturally occurring hydrogen gas from a borehole on the western flank of Nemaha anticline in Kansas: abstract[J]. AAPG Bulletin, 1983, 67(8): 1324.
    [36] GOEBEL E, COVENEY R, ANGINO E, et al. Geology, composition, isotopes of naturally occurring H2/N2 rich gas from wells near Junction City, Kansas[J]. Oil & Gas Journal, 1984, 82(19): 215-222.
    [37] ANGINO E E, COVENEY R M. Hydrogen and nitrogen-origin, distribution, and abundance[J]. Oil & Gas Journal, 1984, 82(3): 142-146.
    [38] COVENEY JR R M, GOEBEL E D, ZELLER E J, et al. Serpentinization and the origin of hydrogen gas in Kansas[J]. AAPG Bulletin, 1987, 71(1): 39-48.
    [39] GUÉLARD J, BEAUMONT V, ROUCHON V, et al. Natural H2 in Kansas: deep or shallow origin?[J]. Geochemistry, Geophysics, Geosystems, 2017, 18(5): 1841-1865.
    [40] MARTY B, GUNNLAUGSSON E, JAMBON A, et al. Gas geochemistry of geothermal fluids, the Hengill area, southwest rift zone of Iceland[J]. Chemical Geology, 1991, 91(3): 207-225.
    [41] 吴振明, 刘和甫, 汤良杰, 等. 中国东部中、新生代主要裂谷盆地的演化及评论[J]. 石油实验地质, 1985, 7(1): 60-69. doi: 10.11781/sysydz198501060

    WU Zhenming, LIU Hefu, TANG Liangjie, et al. Evaluation and evolution of the major rift valley of Meso-Cenozoic in eastern China[J]. Petroleum Geology & Experiment, 1985, 7(1): 60-69. doi: 10.11781/sysydz198501060
    [42] KITA I, MATSUO S, WAKITA H, et al. D/H ratios of H2 in soil gases as an indicator of fault movements[J]. Geochemical Journal, 1980, 14: 317-320.
    [43] SUGISAKI R, IDO M, TAKEDA H, et al. Origin of hydrogen and carbon dioxide in fault gases and its relation to fault activity[J]. The Journal of Geology, 1983, 91(3): 239-258.
    [44] VACQUAND C, DEVILLE E, BEAUMONT V, et al. Reduced gas seepages in ophiolitic complexes: evidences for multiple origins of the H2-CH4-N2 gas mixtures[J]. Geochimica et Cosmochimica Acta, 2018, 223: 437-461.
    [45] KLEIN F, BACH W, JÖNS N, et al. Iron partitioning and hydrogen generation during serpentinization of abyssal peridotites from 15°N on the Mid-Atlantic Ridge[J]. Geochimica et Cosmochi-mica Acta, 2009, 73(22): 6868-6893.
    [46] MAYTHEW L E, ELLISON E T, MCCOLLOM T M, et al. Hydrogen generation from low-temperature water-rock reactions[J]. Nature Geoscience, 2013, 6(6): 478-484, doi: 10.1038/NGEO1825.
    [47] OKLAND I, HUANG S, THORSETH I H, et al. Formation of H2, CH4 and N-species during low-temperature experimental alteration of ultramafic rocks[J]. Chemical Geology, 2014, 387: 22-34.
    [48] NEUBECK A, DUC N T, BASTVIKEN D, et al. Formation of H2 and CH4 by weathering of olivine at temperatures between 30 and 70℃[J]. Geochemical Transactions, 2011, 12(1): 6, doi: 10.1186/1467-4866-12-6.
    [49] ETIOPE G, SCHOELL M, HOSGÖRMEZ H. Abiotic methane flux from the Chimaera seep and Tekirova ophiolites (Turkey): understanding gas exhalation from low temperature serpentinization and implications for Mars[J]. Earth and Planetary Science Letters, 2011, 310(1/2): 96-104.
    [50] 刘训, 游国庆. 中国的板块构造区划[J]. 中国地质, 2015, 42(1): 1-17. https://www.cnki.com.cn/Article/CJFDTOTAL-DIZI201501001.htm

    LIU Xun, YOU Guoqing. Tectonic regional subdivision of China in the light of plate theory[J]. Geology in China, 2015, 42(1): 1-17. https://www.cnki.com.cn/Article/CJFDTOTAL-DIZI201501001.htm
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