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碳酸盐团簇同位素在海相盆地热史研究中的进展

邱楠生 刘鑫 熊昱杰 刘雨晨 徐秋晨 常青

邱楠生, 刘鑫, 熊昱杰, 刘雨晨, 徐秋晨, 常青. 碳酸盐团簇同位素在海相盆地热史研究中的进展[J]. 石油实验地质, 2023, 45(5): 891-903. doi: 10.11781/sysydz202305891
引用本文: 邱楠生, 刘鑫, 熊昱杰, 刘雨晨, 徐秋晨, 常青. 碳酸盐团簇同位素在海相盆地热史研究中的进展[J]. 石油实验地质, 2023, 45(5): 891-903. doi: 10.11781/sysydz202305891
QIU Nansheng, LIU Xin, XIONG Yujie, LIU Yuchen, XU Qiuchen, CHANG Qing. Progress in the study of carbonate clumped isotope in the thermal history of marine basins[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2023, 45(5): 891-903. doi: 10.11781/sysydz202305891
Citation: QIU Nansheng, LIU Xin, XIONG Yujie, LIU Yuchen, XU Qiuchen, CHANG Qing. Progress in the study of carbonate clumped isotope in the thermal history of marine basins[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2023, 45(5): 891-903. doi: 10.11781/sysydz202305891

碳酸盐团簇同位素在海相盆地热史研究中的进展

doi: 10.11781/sysydz202305891
基金项目: 

国家自然科学基金项目 41830424

国家自然科学基金项目 U19B6003

详细信息
    作者简介:

    邱楠生(1968-), 男, 博士, 教授, 从事盆地构造-热演化研究工作。E-mail: qiunsh@cup.edu.cn

  • 中图分类号: TE135

Progress in the study of carbonate clumped isotope in the thermal history of marine basins

  • 摘要: 沉积盆地热史研究对于油气成藏分析至关重要,在油气勘探以及油气资源评价领域有着举足轻重的影响,而海相盆地碳酸盐岩层系由于缺乏有效古温标导致很难对其热史进行恢复。碳酸盐团簇同位素是能够指示碳酸盐岩形成温度的指标,它将温度信息记录在13C—18O配对的化学键中,并通过其丰度变化将温度信息反映出来,即碳酸盐团簇同位素的丰度(Δ47)与地层温度演化密切相关。从碳酸盐团簇同位素测温以及热史恢复的基本原理、方法出发,结合近年来其在国内外海相盆地热史恢复的研究实例,综述了碳酸盐团簇同位素古温标的应用情况,并探讨了其存在的问题和未来的发展方向。碳酸盐团簇同位素作为一种新兴的古温标,在碳酸盐岩地层热历史恢复中展现出了巨大的潜力。团簇同位素热史研究实例表明,美国箭峡Bird Spring组经历的最高古温度约为175 ℃,四川盆地二叠系茅口组最高埋藏温度在213~225 ℃,塔里木盆地奥陶系受二叠纪岩浆活动影响存在160 ℃以上的异常高温。团簇同位素由于受热演化模式不成熟,重结晶作用以及沉积埋藏温度变化的影响,使得其在热史恢复方面仍存在不足,并建议精确恢复碳酸盐岩地层热史的下一步发展方向是将碳酸盐团簇同位素和U-Pb定年以及其他古温标相联合。

     

  • 图  1  碳酸盐团簇同位素示意[12]

    Figure  1.  Schematic diagram of carbonate clumped isotope

    图  2  一阶近似模型预测的T47)—埋藏温度图[31]

    Figure  2.  Schematic diagram of T47)-burial T trajectories predicted by first-order approximation model

    图  3  热史路径和最高古温度对碳酸盐中13C—18O键重排和T47)值的影响示意[41]

    Figure  3.  Impact of thermal history path and maximum paleotemperature on 13C-18O bond reordering and T47) in carbonate

    图  4  美国内华达州箭峡Bird Spring组腕足化石团簇同位素热史恢复结果

    图 4a, 4b据文献[31], 4c据文献[24]。

    Figure  4.  Thermal history reconstructed by clumped isotope of brachiopod fossil from Bird Spring Formation in Arrow Canyon, Nevada, USA

    图  5  美国特拉华盆地不同地温梯度最佳拟合路径模拟[25]

    a图为埋藏史; b图为不同地温梯度下T47)演化曲线,黑带表示95%可信度。

    Figure  5.  Best fitting path of different geothermal gradients in Delaware Basin, USA

    图  6  塔中北部斜坡构造带TZ35井碳酸盐团簇同位素温度模拟[52]

    Figure  6.  Modeling results of carbonate clumped isotope temperature in well TZ35 on the northern slope of Tazhong Uplift

    图  7  利用交换/扩散模型模拟的塔里木盆地顺托果勒地区团簇同位素温度热模拟结果[27]

    Figure  7.  Thermal modeling results of clumped isotope temperature in Shuntuoguole area, Tarim Basin using exchange-diffusion model

    图  8  川东二叠系茅口组钻井样品团簇同位素对地层温度的热模拟结果

    Figure  8.  Thermal modeling results of clumped isotope of drilling sample from Permian Maokou Formation in eastern Sichuan Basin on strata temperature

    图  9  四川盆地普光气田白云岩团簇同位素温度演化过程[55]

    D83、D89和D99分别代表白云石样品的T47)及其误差。

    Figure  9.  Evolution of clumped isotope temperature of dolostone from Puguang Gas Field, Sichuan Basin

    图  10  基于包裹体宿主矿物年龄、团簇同位素温度约束的川中古隆起震旦系灯影组温度演化[57]

    Figure  10.  Temperature evolution of Sinian Dengying Formation in paleo-uplift in central Sichuan Basin based on the constraints of the age of the host mineral of the inclusion and the clumped isotope temperature

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  • 收稿日期:  2023-06-06
  • 修回日期:  2023-08-12
  • 刊出日期:  2023-09-28

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