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渤海湾盆地沾化凹陷BYP5导眼井古近系沙河街组三段下亚段岩心富氢气逸散气特征及其地质意义

李志明 刘惠民 刘鹏 钱门辉 曹婷婷 杜振京 李政 包友书 蒋启贵 徐二社 孙中良 刘雅慧

李志明, 刘惠民, 刘鹏, 钱门辉, 曹婷婷, 杜振京, 李政, 包友书, 蒋启贵, 徐二社, 孙中良, 刘雅慧. 渤海湾盆地沾化凹陷BYP5导眼井古近系沙河街组三段下亚段岩心富氢气逸散气特征及其地质意义[J]. 石油实验地质, 2024, 46(5): 979-988. doi: 10.11781/sysydz202405979
引用本文: 李志明, 刘惠民, 刘鹏, 钱门辉, 曹婷婷, 杜振京, 李政, 包友书, 蒋启贵, 徐二社, 孙中良, 刘雅慧. 渤海湾盆地沾化凹陷BYP5导眼井古近系沙河街组三段下亚段岩心富氢气逸散气特征及其地质意义[J]. 石油实验地质, 2024, 46(5): 979-988. doi: 10.11781/sysydz202405979
LI Zhiming, LIU Huimin, LIU Peng, QIAN Menhui, CAO Tingting, DU Zhenjing, LI Zheng, BAO Youshu, JIANG Qigui, XU Ershe, SUN Zhongliang, LIU Yahui. Characteristics and geological significance of escaping gas rich in natural hydrogen from pilot well BYP5 cores of lower sub-member of third member of Shahejie Formation in Zhanhua Sag, Bohai Bay Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2024, 46(5): 979-988. doi: 10.11781/sysydz202405979
Citation: LI Zhiming, LIU Huimin, LIU Peng, QIAN Menhui, CAO Tingting, DU Zhenjing, LI Zheng, BAO Youshu, JIANG Qigui, XU Ershe, SUN Zhongliang, LIU Yahui. Characteristics and geological significance of escaping gas rich in natural hydrogen from pilot well BYP5 cores of lower sub-member of third member of Shahejie Formation in Zhanhua Sag, Bohai Bay Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2024, 46(5): 979-988. doi: 10.11781/sysydz202405979

渤海湾盆地沾化凹陷BYP5导眼井古近系沙河街组三段下亚段岩心富氢气逸散气特征及其地质意义

doi: 10.11781/sysydz202405979
基金项目: 

国家自然科学基金项目 42090022

中国石化科技部项目 P23229

详细信息
    作者简介:

    李志明(1968—), 男, 博士, 研究员, 从事油气地球化学、页岩油气地质研究。E-mail: lizm.syky@sinopec.com

  • 中图分类号: TE122.1

Characteristics and geological significance of escaping gas rich in natural hydrogen from pilot well BYP5 cores of lower sub-member of third member of Shahejie Formation in Zhanhua Sag, Bohai Bay Basin

  • 摘要: BYP5导眼井是为探索渤海湾盆地沾化凹陷渤南深洼带较高热演化区古近系沙河街组三段下亚段(沙三下亚段)含油气性而部署的一口取心井,取心段深度介于4 267.0~4 338.1 m。为揭示取心段含油气性特征,开展了典型样品冷冻密闭碎样热解和岩心逸散气的收集定量与组分分析。研究结果认为:取心段总体是一套富有机质、富碳酸盐矿物的优质烃源岩,成熟度(Ro)约1.2%,热演化过程中应曾发生了高效生排烃作用,导致其现今游离烃(S1)和氢指数(IH)均较低;岩心逸散烃气含量总体不高,主要介于0.001~0.01 cm3/g,均值为0.005 cm3/g,逸散烃气相对高值段与热解游离烃(S1)相对高值段基本一致;逸散气组分主要由CH4、CO2、H2、C2H6组成,其中H2摩尔百分数介于1.08%~19.23%,平均7.09%,具有富氢气特征。H2与CO2具有明显正相关性,与CH4具有明显负相关性;逸散气应属原位滞留的气体,氢气的形成可能与有机质热解过程中异质键的裂解和去甲基化作用有关,建议加强有机质热裂解成因天然氢气的形成机制、地质勘查与评价研究,为该类型天然氢气的勘探部署决策提供依据。

     

  • 图  1  渤海湾盆地沾化凹陷(a)和BYP5导眼井(b)构造位置

    据参考文献[37]修改。

    Figure  1.  Tectonic location of Zhanhua Sag (a) and pilot well BYP5 (b), Bohai Bay Basin

    图  2  渤海湾盆地沾化凹陷BYP5导眼井沙三下亚段取心段综合柱状图

    Figure  2.  Comprehensive histogram of cored interval from pilot well BYP5 in lower sub-member of third member of Shahejie Formation, Zhanhua Sag, Bohai Bay Basin

    图  3  渤海湾盆地沾化凹陷BYP5导眼井沙三下亚段取心段总有机碳与游离烃含量关系

    Figure  3.  Relationship between total organic carbon (TOC) and free hydrocarbon (S1) contents in cored interval from pilot well BYP5 in lower sub-member of third member of Shahejie Formation, Zhanhua Sag, Bohai Bay Basin

    图  4  渤海湾盆地沾化凹陷BYP5导眼井沙三下亚段取心段有机质类型图版

    Figure  4.  Organic matter types of cored interval from pilot well BYP5 in lower sub-member of third member of Shahejie Formation, Zhanhua Sag, Bohai Bay Basin

    图  5  渤海湾盆地沾化凹陷BYP5导眼井沙三下亚段取心段逸散气组分间相关性

    Figure  5.  Correlation between components of escaping gas in cored interval from pilot well BYP5 in lower sub-member of third member of Shahejie Formation, Zhanhua Sag, Bohai Bay Basin

    图  6  富有机质泥页岩热演化过程中氢气形成的潜在机制

    据参考文献[27, 29]修改。

    Figure  6.  Potential mechanism of H2 formation during thermal evolution of organic-matter-rich mudstone and shale

    表  1  渤海湾盆地沾化凹陷BYP5导眼井沙三下亚段取心段逸散气组分特征

    Table  1.   Compositional characteristics of escaping gas in cored interval from pilot well BYP5 in lower sub-member of third member of Shahejie Formation, Zhanhua Sag, Bohai Bay Basin

    样品编号 岩性 井深/m 组分含量(摩尔百分数)/%
    H2 CO2 CH4 C2H6 C3H8
    byp5-1-1-1 层状泥质灰岩 4 273.65 1.54 16.67 75.90 5.13 0.77
    byp5-1-5-1 层状灰质泥岩 4 268.72 4.17 22.50 66.67 5.83 0.83
    byp5-2-1-1 层状泥质灰岩 4 278.07 1.08 13.36 76.90 7.58 1.08
    byp5-2-3-1 层状灰质泥岩 4 278.91 19.15 29.79 46.82 4.26 0.00
    byp5-3-2-1 层状泥质灰岩 4 286.31 3.08 15.42 74.89 5.73 0.88
    byp5-3-4-1 层状泥质灰岩 4 288.57 1.67 12.78 78.89 6.11 0.56
    byp5-4-1-1 层状泥质灰岩 4 296.12 3.37 23.60 67.41 4.49 1.12
    byp5-4-4-1 层状灰质泥岩 4 300.35 8.20 27.87 57.37 4.92 1.64
    byp5-5-1-1 层状灰质泥岩 4 309.50 19.23 34.61 42.30 3.85 0.00
    byp5-5-2-1 层状含泥灰岩 4 309.75 1.64 21.31 71.31 4.92 0.82
    byp5-5-4-1 层状灰质泥岩 4 312.61 17.50 22.50 57.51 2.50 0.00
    byp5-5-6-1 层状含泥灰岩 4 316.12 4.63 18.52 71.30 4.63 0.93
    byp5-5-7-1 层状灰质泥岩 4 317.79 13.33 46.65 26.66 6.66 6.69
    byp5-6-1-1 层状泥质灰岩 4 323.78 2.97 10.41 82.53 3.72 0.37
    byp5-6-2-1 层状灰质泥岩 4 325.30 8.96 23.88 61.19 4.48 1.49
    byp5-6-7-1 层状灰质泥岩 4 332.12 5.56 18.52 69.45 5.56 0.93
    byp5-6-9-1 层状灰质泥岩 4 335.26 4.46 14.29 75.00 5.36 0.89
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  • 收稿日期:  2024-05-14
  • 修回日期:  2024-07-06
  • 刊出日期:  2024-09-28

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