A simultaneous determination method for diamondoids and thiadiamondoids in condensate oil and its geological significance: taking condensate oil from central Tarim Basin as an example

FANG Chenchen; ZHAI Jia; HU Guoyi; GONG Deyu

doi:10.11781/sysydz202105906

Volume 43 Issue 5

Sep. 2021

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Article Navigation > PETROLEUM GEOLOGY & EXPERIMENT > 2021 > 43(5): 906-914

FANG Chenchen, ZHAI Jia, HU Guoyi, GONG Deyu. A simultaneous determination method for diamondoids and thiadiamondoids in condensate oil and its geological significance: taking condensate oil from central Tarim Basin as an example[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2021, 43(5): 906-914. doi: 10.11781/sysydz202105906

Citation:

FANG Chenchen, ZHAI Jia, HU Guoyi, GONG Deyu. A simultaneous determination method for diamondoids and thiadiamondoids in condensate oil and its geological significance: taking condensate oil from central Tarim Basin as an example[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2021, 43(5): 906-914. doi: 10.11781/sysydz202105906

Citation:

FANG Chenchen, ZHAI Jia, HU Guoyi, GONG Deyu. A simultaneous determination method for diamondoids and thiadiamondoids in condensate oil and its geological significance: taking condensate oil from central Tarim Basin as an example[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2021, 43(5): 906-914. doi: 10.11781/sysydz202105906

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A simultaneous determination method for diamondoids and thiadiamondoids in condensate oil and its geological significance: taking condensate oil from central Tarim Basin as an example

doi: 10.11781/sysydz202105906

FANG Chenchen^1
,,
ZHAI Jia^{2, 3},
HU Guoyi^{1
,
,},
GONG Deyu¹

1.
Research Institute of Petroleum Exploration & Development, PetroChina, Beijing 100083, China
2.
State Key Laboratory of Coal Resources and Safe Mining, China University of Mining and Technology(Beijing), Beijing 100083, China
3.
College of Geoscience and Surveying Engineering, China University of Mining and Technology(Beijing), Beijing 100083, China

Received Date: 2021-07-12
Rev Recd Date: 2021-08-31
Publish Date: 2021-09-28

Abstract

Abstract

Diamondoids and thiadiamondoids in crude oil samples have the similar diamond-like cage structures, which can reflect the thermal cracking and thermochemical sulfate reduction(TSR) effect during geological processes. Therefore, the simultaneous monitoring of diamondoids and thiadiamondoids cannot only improve the efficiency of sample analysis and the accuracy of quantitative results of thiadiamondoids, but also provide more reliable and extensive geochemical interpretation for the samples. In this paper, a simultaneous quantitative detection method of diamondoids and thiadiamondoids was proposed by the means of gas chromatography-triple quadrupole mass spectrometer (GC-MS-MS). By determining the parameters of precursor and product ions, scanning time and collision energy of the target compound, a simultaneous quantitative detection method was established for diamondoids and thiadiamondoids in condensate from the central Tarim Basin. Results showed that despite the contents of diamondoids of oils from the central Tarim Basin were different, the maturity degree on the other hand, were comparable as over mature, and some samples have experienced TSR.
- diamondoids,
- thiadiamondoids,
- maturity,
- thermochemical sulfate reduction (TSR),
- central Tarim,
- Tarim Basin

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致谢: 感谢中国石油塔里木油田分公司肖中尧高级工程师和中国科学院广州地球化学研究所张文兵副研究员在野外取样和仪器使用过程中给予的大力支持和帮助。

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